摘要:
A solid oxide fuel cell device incorporates a sealing material resistant to hydrogen gas permeation at a sealing temperature in the intermediate temperature range of 600° C.-900° C., the seal having a CTE in the 100×10−7/° C. to 120×10−7/° C., wherein the sealing material comprises in weight %, of: (i) a 80 wt % to 100 wt % glass frit, the glass frit itself having a composition comprising in mole percent of: SiO2 15-65; Li2O 0-5; Na2O 0-5; K2O 0-10; MgO 0-5; CaO 0-32; Al2O3 0-10; B2O3 0-50; SrO 0 to 25, wherein the total amount of alkalis is less than 10 mole %; and (ii) zirconia or leucite addition 0 wt % to 30 wt.
摘要翻译:固体氧化物燃料电池装置包括在600℃-900℃的中间温度范围内的密封温度下耐氢气渗透的密封材料,所述密封件具有在100×10 -7〜 其中密封材料的重量百分比为:(i)80重量%至100重量%的玻璃料,玻璃料 本身具有以摩尔%计含有:SiO 2 15-65的组成; Li 2 O 0-5; Na 2 O 0-5; K 2 O 0-10; MgO 0-5; CaO 0-32; Al 2 O 3 O 10; B u> O 0-50; SrO 0〜25,其中碱的总量小于10摩尔%。 和(ii)添加0重量%至30重量%的氧化锆或白云母
摘要:
A solid oxide fuel cell device incorporates a sealing material resistant to hydrogen gas permeation at a sealing temperature in the intermediate temperature range of 600° C.-800° C., the seal having a CTE in the 100×10−7/° C. to 120×10−7/° C., wherein the sealing material comprises in weight %, of: (i) a 80 to 95 wt % of glass frit, the glass frit itself having a composition in mole percent of: SiO2 70-85%; Al2O3 0-5%; Na2O3 0-8%; K2O 10-25%; ZnO 0-10%; ZrO2 0-6%; MgO 0-7%; TiO2 0-2%; and (ii) and 5 wt % to 25 wt % of addition comprising at least one of: alumina, zirconia or leucite.
摘要翻译:固体氧化物燃料电池装置包括在600℃-800℃的中间温度范围内的密封温度下耐氢气渗透的密封材料,该密封件具有在100×10 -7〜 其中密封材料的重量百分比为:(i)80至95重量%的玻璃料,玻璃料本身 具有摩尔百分数:SiO 2%70-85%的组成; Al 2 O 3 0-5%; Na 2 O 3 0-8%; K 2 O 10-25%; ZnO 0-10%; ZrO 2 0-6%; MgO 0-7%; TiO 2 2-2%; 和(ii)和5重量%至25重量%的包含氧化铝,氧化锆或白云母中的至少一种的添加剂。
摘要:
A method and resulting device for metallic structures including interconnects and sealed frames for solid oxide fuel cells, particularly those with multi-cell electrolyte sheets, includes providing a high-temperature aluminum-containing surface-alumina-forming steel, forming an interconnect structure from the steel, removing any alumina layer from a surface portion of the interconnect where an electrical contact is to be formed, providing a structure having a surface portion with which electrical contact is to be made by the surface portion of the interconnect, and brazing the surface portion of the interconnect to the surface portion of the structure, and sealing fuel cell frames by brazing.