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公开(公告)号：US5364691A
公开(公告)日：1994-11-15
申请号：US490854
申请日：1990-03-09
摘要： This invention relates to radiation curable alk-1-enyloxy carbonate reaction products of a hydroxylated compound having the formula A-ROH and a dialk-1-enyloxy carbonate having the formula ##STR1## wherein R is a polymeric radical selected from the group of polyester, polyacetal, polyurethane, polyether, and polycarbonate, said polymers containing from about 10 to 50 repeating monomer units;A' is a terminating moiety and is hydrogen, lower alkyl or hydroxy;R' is hydrogen or lower alkyl;B is a linear, branched or cyclic divalent radicalhaving from 2 to 12 carbon atoms and is selected from the group of alkylene, mono or poly alkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, lower alkyl, cyano, nitro or alkoxy and m has a value of from 1 to 10. The products of this invention are defined by the formula: ##STR2## wherein A' is a terminating moiety and is hydrogen, lower alkyl or ##STR3##
摘要翻译： 本发明涉及具有式A-ROH的羟基化化合物和具有式“IMAGE”的二烷基-1-烯氧基碳酸酯的可辐射固化的烷-1-烯氧基碳酸酯反应产物，其中R是选自聚酯的聚合基 聚缩醛，聚氨酯，聚醚和聚碳酸酯，所述聚合物含有约10至50个重复单体单元; A'为终止部分，为氢，低级烷基或羟基; R'是氢或低级烷基; B是具有2至12个碳原子的直链，支链或环状二价基团，并且选自亚烷基，单或多烷氧基化亚烷基，亚烯基，亚炔基，亚芳基，亚烷基和亚芳基，其基团任选被卤素 ，低级烷基，氰基，硝基或烷氧基，m的值为1至10.本发明的产物由下式定义：其中A'为终止部分，为氢，低级烷基或 图像>
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公开(公告)号：US5106995A
公开(公告)日：1992-04-21
申请号：US347647
申请日：1989-05-05
申请人： Jeffrey S. Plotkin
发明人： Jeffrey S. Plotkin
IPC分类号： C07D307/33 , C07D307/93 , C07D309/30 , C07D315/00 , C07D319/12
CPC分类号： C07D307/33 , C07D307/93 , C07D315/00 , C07D319/12
摘要： A method for converting 1,4 and 1,5 aliphatic saturated diols to lactones is disclosed wherein the diol is reacted with a chemical oxidizing agent and a ruthenium containing catalyst at temperatures substantially less than 200.degree. C. The reaction proceeds quickly and produces high yields of the desired product.
摘要翻译： 公开了将1,4和1,5-脂肪族饱和二醇转化为内酯的方法，其中二醇在温度基本上低于200℃下与化学氧化剂和含钌催化剂反应。反应快速进行并产生高产率 的所需产品。
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公开(公告)号：US5095124A
公开(公告)日：1992-03-10
申请号：US582033
申请日：1990-09-10
IPC分类号： C07D317/36 , C09D4/00
CPC分类号： C07D317/36 , C09D4/00
摘要： The present invention relates to a two-stage liquid phase process wherein an alk-2-enyl glycidyl ether having the formula ##STR1## wherein R is hydrogen or lower alkyl; R' is C.sub.2 to C.sub.4 alkylene; n has a value of from 1 to 4 and n' has a value of from 0 to 4, is catalytically isomerized to the corresponding alk-1-enyl glycidyl ether in the first-stage of the reaction and the reaction mixture of the first-stage, containing the isomerization catalyst is then contacted with carbon dioxide in the presence of a phase transfer catalyst under a pressure ranging from atmospheric to about 400 psig in the second stage of the reaction.
摘要翻译： 本发明涉及两阶段液相方法，其中具有下式的烷基-2-烯基缩水甘油醚：其中R是氢或低级烷基; R'是C 2至C 4亚烷基; n的值为1至4，n'为0至4的值，在反应的第一阶段催化异构化为相应的烷-1-烯基缩水甘油醚，第一步的反应混合物， 然后在相转移催化剂的存在下，在反应的第二阶段，在大气压至约400psig的压力下，使异构化催化剂与二氧化碳接触。
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公开(公告)号：US5055357A
公开(公告)日：1991-10-08
申请号：US670649
申请日：1991-03-18
CPC分类号： C08G65/336 , C07F7/045 , C08F8/42 , C08G59/4085 , C09D4/00 , Y10T428/31511 , Y10T428/31855
摘要： This invention realtes to a radiation curable cross linkable composition containing (a) from about 0.1 to about 5 wt. % of an initiator containing at least 25% cationic initiator, (b) from about 0 to about 60 wt. % of a polymerizable vinyl ether, expoxide, vinyloxy alkyl urethane or acrylate and (c) from about 35 to about 99.9 wt. % of a polyfunctional alkenyl ether having the formulaA[(CH.sub.2 O).sub.m (Z).sub.r CH.dbd.CHR].sub.nwherein A is a carbon atom, --OCH.dbd.CHR or [C.sub.1 to C.sub.10 alkyl].sub.4-n ; R is C.sub.1 to C.sub.6 alkyl; Z is C.sub.2 to C.sub.8 alkyleneoxy; r has a value of from 0 to 6; m has a value of from 0 to 1 and at least one of r and m has a positive value; n has a value of from 1 to 4, with the proviso that m is 0 and n is one when A is --OCH.dbd.CHR, n has a value of 2 or 3 when A is [C.sub.1 to C.sub.10 alkyl].sub.4-n and n has a value of 4 when A is carbon. The invention also relates to the process of curing said composition and to a cured film on a substrate coated with the above composition.
摘要翻译： 本发明涉及可辐射固化的可交联组合物，其包含（a）约0.1至约5wt。 ％的引发剂含有至少25％的阳离子引发剂，（b）约0至约60wt。 ％的可聚合乙烯基醚，过氧化物，乙烯基氧基烷基氨基甲酸酯或丙烯酸酯和（c）约35-约99.9重量％ ％的具有式A [（CH 2 O）m（Z）r CH = CHR] n的多官能烯基醚其中A是碳原子，-OCH = CHR或[C1-C10烷基] 4-n; R为C1至C6烷基; Z为C2〜C8亚烷氧基; r的值为0到6; m具有0至1的值，并且r和m中的至少一个具有正值; n的值为1至4，条件是m为0且当A为-OCH = CHR时n为1，当A为[C 1至C 10烷基] 4-n时，n为2或3的值，n为 当A为碳时，n的值为4。 本发明还涉及在涂覆有上述组合物的基材上固化所述组合物和固化膜的方法。
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公开(公告)号：US5225606A
公开(公告)日：1993-07-06
申请号：US712766
申请日：1991-06-10
IPC分类号： C07C43/23
CPC分类号： C07C43/23
摘要： This invention relates to the alk-1-enyl ether reaction product of a hydroxylated compound and an alk-1-enyloxy oxirane containing from 0 to 95% alkyl epoxide.
摘要翻译： 本发明涉及羟基化合物和含有0至95％烷基环氧化物的烷-1-烯氧基环氧乙烷的烷-1-烯基醚反应产物。
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公开(公告)号：US5200437A
公开(公告)日：1993-04-06
申请号：US817218
申请日：1992-01-06
申请人： James A. Dougherty , Fulvio J. Vara , Jeffrey S. Plotkin , Paul D. Taylor , Kolazi S. Narayanan
发明人： James A. Dougherty , Fulvio J. Vara , Jeffrey S. Plotkin , Paul D. Taylor , Kolazi S. Narayanan
IPC分类号： C08F2/46 , C08F214/18 , C09D4/00
CPC分类号： C08F214/188 , C09D4/00
摘要： This invention relates to coating compositions containing the alk-1-enyl ether reaction product of a hydroxylated compound, an alk-1-enyloxy oxirane and from 0 to 95% of an alkyl epoxide.
摘要翻译： 本发明涉及包含羟基化化合物，烷-1-烯氧基环氧乙烷和0至95％烷基环氧化物的烷-1-烯基醚反应产物的涂料组合物。
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公开(公告)号：US5159098A
公开(公告)日：1992-10-27
申请号：US579511
申请日：1990-09-10
IPC分类号： C07C271/12 , C07C271/20
CPC分类号： C07C271/20 , C07C271/12
摘要： The invention relates to alk-1-enyloxy carbamates selected from the group having the formulae ##STR1## wherein R is a saturated or unsaturated, monovalent or divalent hydrocarbon radical having from 1 to 50 carbon atoms and is optionally substituted with halo, alkyleneoxy, hydroxy, or a combination of said radicals; Y is --O-- or --OCO--O--; X is hydrogen or methyl; R' and R" are each independently hydrogen, alkyl, aryl, aralkyl or alkaryl; m has a value of from 2 to 6 and n has a value of from 0 to 25. The invention also relates to the use of these alk-1-enyloxy carbamates as reactive diluents in cationically induced radiation curing of epoxy, vinyl ether, urethane monomers or oligomers and others.
摘要翻译： 本发明涉及选自具有下式的基团的烯-1-烯氧基氨基甲酸酯：其中R是具有1至50个碳原子的饱和或不饱和的一价或二价烃基，并且是 任选地被卤素，亚烷氧基，羟基或所述基团的组合取代; Y是-O-或-OCO-O-; X是氢或甲基; R'和R“各自独立地为氢，烷基，芳基，芳烷基或烷芳基; m的值为2至6，n的值为0至25.本发明还涉及这些烷-1-烯氧基氨基甲酸酯作为反应性稀释剂在环氧树脂，乙烯基醚，氨基甲酸酯的阳离子诱导辐射固化中的用途 单体或低聚物等。
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公开(公告)号：US5140054A
公开(公告)日：1992-08-18
申请号：US756715
申请日：1991-09-09
申请人： Mark M. Miller , Jeffrey S. Plotkin
发明人： Mark M. Miller , Jeffrey S. Plotkin
IPC分类号： C07C271/20 , C07C271/28 , C08F2/50
CPC分类号： C07C271/20 , C07C271/28
摘要： This invention relates to a polypropenyl ether having the formula ##STR1## wherein m and s each independently have a value of from 1 to 6; R is alkyl or phenyl optionally substituted with lower alkyl or halogen; A is C.sub.2 to C.sub.12 alkylene or C.sub.6 to C.sub.22 aryl, both optionally substituted with lower alkyl, haloalkyl, halogen or phenyl.
摘要翻译： 本发明涉及具有式“IMAGE”的聚丙烯基醚，其中m和s各自独立地具有1至6的值; R是烷基或任选被低级烷基或卤素取代的苯基; A是C 2至C 12亚烷基或C 6至C 22芳基，两者均任选被低级烷基，卤代烷基，卤素或苯基取代。
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10.发明授权Radiation curable cross linkable compositions containing an aliphatic polyfunctional alkenyl ether 失效含有脂肪族多官能烯基醚的可辐射固化交联组合物
公开(公告)号：US5045572A
公开(公告)日：1991-09-03
申请号：US470487
申请日：1990-01-26
CPC分类号： C08G65/336 , C07F7/045 , C08F8/42 , C08G59/4085 , C09D4/00
摘要： This invention relates to a radiation curable crosslinkable composition containing (a) from about 0.1 to about 5 wt. % of an initiator containing at least 25% cationic initiator, (b) from about 0 to about 60 wt. % of a polymerizable vinyl ether, epoxide, vinyloxy alkyl urethane or acrylate and (c) from about 35 to about 99.9% wt. % of a polyfunctional alkenyl ether having the formulaA[(CH.sub.2 O).sub.m (Z).sub.r CH.dbd.CHR].sub.nwherein A is a carbon atom, --OCH.dbd.CHR or [C.sub.1 to C.sub.10 alkyl].sub.4-n ; R is C.sub.1 to C.sub.6 alkyl; Z is C.sub.2 to C.sub.8 alkyleneoxy; r has a value of from 0 to 6; m has a value of from 0 to 1 and at least one of r and m has a positive value; n has a value of from 1 to 4, with the proviso that m is 0 and n is one when A is --OCH.dbd.CHR, n has a value of 2 or 3 when A is [C.sub.1 to C.sub.10 alkyl].sub.4-n and n has a value of 4 when A is carbon. The invention also relates to the process of curing said composition and to a cured film on a substrate coated with the above composition.
摘要翻译： 本发明涉及可辐射固化的可交联组合物，其包含（a）约0.1至约5wt。 ％的引发剂含有至少25％的阳离子引发剂，（b）约0至约60wt。 ％的可聚合乙烯基醚，环氧化物，乙烯基氧基烷基氨基甲酸酯或丙烯酸酯和（c）约35-约99.9重量％ ％的具有式A [（CH 2 O）m（Z）r CH = CHR] n的多官能烯基醚其中A是碳原子，-OCH = CHR或[C1-C10烷基] 4-n; R为C1至C6烷基; Z为C2〜C8亚烷氧基; r的值为0到6; m具有0至1的值，并且r和m中的至少一个具有正值; n的值为1至4，条件是m为0且当A为-OCH = CHR时n为1，当A为[C 1至C 10烷基] 4-n时，n为2或3的值，n为 当A为碳时，n的值为4。 本发明还涉及在涂覆有上述组合物的基材上固化所述组合物和固化膜的方法。
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