Triborohydride salts as hydrogen storage materials and preparation thereof
    1.
    发明授权
    Triborohydride salts as hydrogen storage materials and preparation thereof 失效
    三氢硼酸盐作为储氢材料及其制备

    公开(公告)号:US07214439B2

    公开(公告)日:2007-05-08

    申请号:US10741192

    申请日:2003-12-19

    摘要: The present invention relates to the use of triborohydride salts as hydrogen storage materials. The present invention also relates to a system of using triborohydride salts to generate hydrogen gas for use in a fuel cell or other hydrogen-consuming device. A novel method of preparing triborohydride salts is also disclosed, wherein gaseous diborane is reacted with a carbonate suspended in a non-aqueous solvent in a suitable vessel with agitation. The process is typically carried out utilizing sodium carbonate to form sodium triborohydride. Other triborohydride salts can then be formed by cationic exchange. Hydrogen generating fuels according to the present invention include aqueous or hydroalcoholic solutions or slurries of a triborohydride salt, which may additionally contain a borohydride salt to provide operation over a broader temperature range.

    摘要翻译: 本发明涉及使用三氢化铈盐作为储氢材料。 本发明还涉及一种使用三氢化烃盐产生用于燃料电池或其它耗氢装置的氢气的系统。 还公开了一种制备三氢化硼盐的新方法,其中将气态乙硼烷与悬浮在非水溶剂中的碳酸酯在合适的容器中与搅拌反应。 该方法通常使用碳酸钠进行以形成三氢化钠。 然后可以通过阳离子交换形成其它三氯化硼盐。 根据本发明的产生氢的燃料包括三氢化烃盐的水溶液或水醇溶液或浆料,其可以另外含有硼氢化物盐以在更宽的温度范围内提供操作。