摘要:
Disclosed herein is a battery system including two or more kinds of cell lines having different charge and discharge characteristics, wherein each cell line includes one or more battery cells connected in series with each other. In the battery system according to the present invention, the battery cells of at least one cell line exhibit a high-rate charge characteristic, whereas the battery cells of at least another cell line exhibit a high-rate discharge characteristic. Consequently, the high-rate charge and discharge characteristics are improved, and the balance between the charge and discharge characteristics is maintained, whereby the battery system according to the present invention is used as a power source having a high power.
摘要:
Disclosed herein is a battery system including two or more kinds of cell lines having different charge and discharge characteristics, wherein each cell line includes one or more battery cells connected in series with each other. In the battery system according to the present invention, the battery cells of at least one cell line exhibit a high-rate charge characteristic, whereas the battery cells of at least another cell line exhibit a high-rate discharge characteristic. Consequently, the high-rate charge and discharge characteristics are improved, and the balance between the charge and discharge characteristics is maintained, whereby the battery system according to the present invention is used as a power source having a high power.
摘要:
Provided is a cathode active material containing a Ni-based lithium mixed transition metal oxide. More specifically, the cathode active material comprises the lithium mixed transition metal oxide having a composition represented by Formula I of LixMyO2 wherein M, x and y are as defined in the specification, which is prepared by a solid-state reaction of Li2CO3 with a mixed transition metal precursor under an oxygen-deficient atmosphere, and has a Li2CO3 content of less than 0.07% by weight of the cathode active material as determined by pH titration. The cathode active material in accordance with the present invention and substantially free of water-soluble bases such as lithium carbonates and lithium sulfates and therefore has excellent high-temperature and storage stabilities and a stable crystal structure. A secondary battery comprising such a cathode active material exhibits a high capacity and excellent characteristics, and can be produced by an environmentally friendly method with low production costs and high production efficiency.
摘要翻译:提供含有Ni基锂混合过渡金属氧化物的正极活性物质。 更具体地说,阴极活性材料包括具有由Li x Mn 2 O的式I表示的组成的锂混合过渡金属氧化物,其中M,x和y如说明书中所定义,其通过Li 2 CO 3与混合的固态反应 过氧化物金属前体,并且通过pH滴定测定,Li2CO3含量小于正极活性物质的0.07重量%。 根据本发明的阴极活性材料,基本上不含碳酸锂和硫酸锂等水溶性碱,因此具有优异的高温保存稳定性和稳定的晶体结构。 包含这种正极活性物质的二次电池显示出高容量和优异的特性,并且可以通过环保的方法生产,生产成本低,生产效率高。
摘要:
The present invention provides for a process of making a Ni-based lithium transition metal oxide cathode active materials used in lithium ion secondary batteries. The cathode active materials are substantially free of Li2CO3 impurity and soluble bases.
摘要翻译:本发明提供了制造用于锂离子二次电池的Ni基锂过渡金属氧化物正极活性物质的方法。 阴极活性材料基本上不含Li 2 CO 3杂质和可溶碱。
摘要:
The present invention provides for a process of making a Ni-based lithium transition metal oxide cathode active materials used in lithium ion secondary batteries. The cathode active materials are substantially free of Li2CO3 impurity and soluble bases.
摘要:
Provided is a method for preparing a lithium mixed transition metal oxide, comprising subjecting Li2CO3 and a mixed transition metal precursor to a solid-state reaction under an oxygen-deficient atmosphere with an oxygen concentration of 10 to 50% to thereby prepare a powdered lithium mixed transition metal oxide having a composition represented by Formula I of LixMyO2 wherein M, x and y are as defined in the specification. Therefore, since the high-Ni lithium mixed transition metal oxide having a given composition can be prepared by a simple solid-state reaction in air, using a raw material that is cheap and easy to handle, the present invention enables industrial-scale production of the lithium mixed transition metal oxide with significantly decreased production costs and high production efficiency. Further, the thus-produced lithium mixed transition metal oxide is substantially free of impurities, and therefore can exert a high capacity and excellent cycle stability, in conjunction with significantly improved storage stability and high-temperature stability.
摘要翻译:提供一种制备锂混合过渡金属氧化物的方法,包括在氧气浓度为10至50%的氧缺乏气氛下使Li 2 CO 3和混合过渡金属前体进行固态反应,从而制备混合的粉末状锂 具有由式I表示的组合物的过渡金属氧化物,其中M,x和y如说明书中所定义。 因此,由于具有给定组成的高Ni锂混合过渡金属氧化物可以通过在空气中简单的固态反应来制备,使用廉价且易于处理的原料,本发明使得能够工业规模生产 锂混合过渡金属氧化物的生产成本显着降低,生产效率高。 此外,这样制造的锂混合过渡金属氧化物基本上不含杂质,因此可以发挥高容量和优异的循环稳定性,同时显着提高储存稳定性和高温稳定性。
摘要:
The present invention provides a powdery composite precursor, which comprises a core of a lithium transition metal oxide, and an aluminum hydroxide-based precipitate layer coated on the surface of the core, and a process to prepare the composite precursor. The preparation process comprises the formation of a water based slurry by dispersing lithium transition metal oxide powder in water, and a precipitation reaction of an aluminum salt solution with a base solution where the lithium transition metal particles act as seed particles, whereby a mechanically stable precipitate layer of homogeneous thickness can be achieved. The composite precursor can be converted into aluminum-containing, e.g., aluminum-doped, lithium transition metal oxide suitable for a cathode active material of lithium rechargeable battery by heat treatment.
摘要:
Provided is a method for preparing a lithium mixed transition metal oxide, comprising subjecting Li2CO3 and a mixed transition metal precursor to a solid-state reaction under an oxygen-deficient atmosphere with an oxygen concentration of 10 to 50% to thereby prepare a powdered lithium mixed transition metal oxide having a composition represented by Formula I of LixMyO2 wherein M, x and y are as defined in the specification. Therefore, since the high-Ni lithium mixed transition metal oxide having a given composition can be prepared by a simple solid-state reaction in air, using a raw material that is cheap and easy to handle, the present invention enables industrial-scale production of the lithium mixed transition metal oxide with significantly decreased production costs and high production efficiency. Further, the thus-produced lithium mixed transition metal oxide is substantially free of impurities, and therefore can exert a high capacity and excellent cycle stability, in conjunction with significantly improved storage stability and high-temperature stability.
摘要翻译:提供一种制备锂混合过渡金属氧化物的方法,包括在氧气浓度为10至50%的氧缺乏气氛下使Li 2 CO 3和混合过渡金属前体进行固态反应,从而制备混合的粉末状锂 具有由式I表示的组合物的过渡金属氧化物,其中M,x和y如说明书中所定义。 因此,由于具有给定组成的高Ni锂混合过渡金属氧化物可以通过在空气中简单的固态反应来制备,使用廉价且易于处理的原料,本发明使得能够工业规模生产 锂混合过渡金属氧化物的生产成本显着降低,生产效率高。 此外,这样制造的锂混合过渡金属氧化物基本上不含杂质,因此可以发挥高容量和优异的循环稳定性,同时显着提高储存稳定性和高温稳定性。
摘要:
The present invention provides for lithium ion secondary batteries that use Ni-based lithium transition metal oxide cathode active materials. The cathode active materials are substantially free of Li2CO3 impurity and soluble bases.
摘要翻译:本发明提供使用Ni系锂过渡金属氧化物正极活性物质的锂离子二次电池。 阴极活性材料基本上不含Li 2 CO 3杂质和可溶碱。
摘要:
The present invention provides for Ni-based lithium transition metal oxide cathode active materials used in lithium ion secondary batteries. The cathode active materials are substantially free of Li2CO3 impurity and soluble bases.
摘要翻译:本发明提供了用于锂离子二次电池的Ni基锂过渡金属氧化物正极活性物质。 阴极活性材料基本上不含Li 2 CO 3杂质和可溶碱。