公开(公告)号：US08283477B2

公开(公告)日：2012-10-09

申请号：US12999420

申请日：2009-06-24

申请人： Jin-Eok Kim ,  Seung-il Kim ,  Han-Jin Kwag

发明人： Jin-Eok Kim ,  Seung-il Kim ,  Han-Jin Kwag

IPC分类号： A61K31/4015 ,  A61K31/402 ,  C07D207/40

CPC分类号： C07D207/448

摘要： The present invention relates to a method of preparing N-substituted maleimide in high purity and high yield, wherein, unlike a conventional method of preparing N-substituted maleimide after preparing N-substituted maleamic acid, an organic solvent, an acid catalyst, a dehydration co-catalyst and a stabilizer are added into a reactor without separately preparing N-substituted maleamic acid, and then a primary amine is added into the reactor to form an amine salt, maleic anhydride is added into the reactor, and the resulting mixture is subjected to a dehydration-cyclization reaction, wherein water produced during the reaction is azeotropically distilled with the organic solvent so as to effectively suppress formation of a maleimide polymer. Particularly, the invention simplifies the process, has high yield, minimizes side reactions, eliminates the introduction of expensive raw materials and the complicated treatment of the reaction solution and significantly shortens the time over which the raw materials and maleic anhydride are added.

摘要翻译： 本发明涉及以高纯度和高收率制备N-取代马来酰亚胺的方法，其中与制备N-取代马来酰胺酸，有机溶剂，酸催化剂，脱水剂的常规制备N-取代马来酰亚胺的方法不同 助催化剂和稳定剂加入到反应器中，而无需单独制备N-取代的马来酰胺酸，然后将伯胺加入到反应器中以形成胺盐，将马来酸酐加入到反应器中，并将所得混合物 进行脱水 - 环化反应，其中在反应期间产生的水与有机溶剂共沸蒸馏，以有效抑制马来酰亚胺聚合物的形成。 特别地，本发明简化了方法，具有高产率，最小化副反应，消除了昂贵原料的引入和复杂的反应溶液处理，并显着缩短了添加原料和马来酸酐的时间。

公开(公告)号：US20110124882A1

公开(公告)日：2011-05-26

申请号：US12999420

申请日：2009-06-24

申请人： Jin-Eok Kim ,  Seung-il Kim ,  Han-Jin Kwag

发明人： Jin-Eok Kim ,  Seung-il Kim ,  Han-Jin Kwag

IPC分类号： C07D207/448

CPC分类号： C07D207/448

摘要： The present invention relates to a method of preparing N-substituted maleimide in high purity and high yield, wherein, unlike a conventional method of preparing N-substituted maleimide after preparing N-substituted maleamic acid, an organic solvent, an acid catalyst, a dehydration co-catalyst and a stabilizer are added into a reactor without separately preparing N-substituted maleamic acid, and then a primary amine is added into the reactor to form an amine salt, maleic anhydride is added into the reactor, and the resulting mixture is subjected to a dehydration-cyclization reaction, wherein water produced during the reaction is azeotropically distilled with the organic solvent so as to effectively suppress formation of a maleimide polymer. Particularly, the invention simplifies the process, has high yield, minimizes side reactions, eliminates the introduction of expensive raw materials and the complicated treatment of the reaction solution and significantly shortens the time over which the raw materials and maleic anhydride are added.

摘要翻译： 本发明涉及以高纯度和高收率制备N-取代马来酰亚胺的方法，其中与制备N-取代马来酰胺酸，有机溶剂，酸催化剂，脱水剂的常规制备N-取代马来酰亚胺的方法不同 助催化剂和稳定剂加入到反应器中，而无需单独制备N-取代的马来酰胺酸，然后将伯胺加入到反应器中以形成胺盐，将马来酸酐加入到反应器中，并将所得混合物 进行脱水 - 环化反应，其中在反应期间产生的水与有机溶剂共沸蒸馏，以有效抑制马来酰亚胺聚合物的形成。 特别地，本发明简化了方法，具有高产率，最小化副反应，消除了昂贵原料的引入和复杂的反应溶液处理，并显着缩短了添加原料和马来酸酐的时间。

公开(公告)号：US07758995B2

公开(公告)日：2010-07-20

申请号：US12017290

申请日：2008-01-21

申请人： Tae-yong Kim ,  Zin Park ,  Seung-il Kim

发明人： Tae-yong Kim ,  Zin Park ,  Seung-il Kim

IPC分类号： H01M2/12

CPC分类号： H01M2/12 ,  H01M2/204 ,  H01M10/613 ,  H01M10/643 ,  H01M10/6562

摘要： A serial interface interposed between two serially connected unit cells provides mechanical strength to the serial connection and conductive coupling therebetween. The serial interface includes an inter-connector having a first vent hole formed therein configured for conductively coupling an anode outer wall of a first unit cell and a cathode terminal of a second unit cell to each other; and a spacer having a second vent hole formed therein and configured to be disposed between the inter-connector and an anode outer wall of the second unit cell to prevent a short-circuit due to the movement of the inter-connector.

摘要翻译： 插入在两个串联连接的单元电池之间的串行接口为串联连接提供机械强度并且在它们之间提供导电耦合。 串行接口包括一个连接器，其中形成有第一通气孔，其中构造成将第一单电池的阳极外壁和第二单元电池的阴极端子彼此导电耦合; 以及间隔件，其具有形成在其中的第二通气孔，并且被配置为设置在第二单元电池的连接器间和阳极外壁之间，以防止由于连接器的移动而引起的短路。

公开(公告)号：US20080182160A1

公开(公告)日：2008-07-31

申请号：US12017290

申请日：2008-01-21

申请人： Tae-yong Kim ,  Zin Park ,  Seung-il Kim

发明人： Tae-yong Kim ,  Zin Park ,  Seung-il Kim

IPC分类号： H01M2/12

CPC分类号： H01M2/12 ,  H01M2/204 ,  H01M10/613 ,  H01M10/643 ,  H01M10/6562

摘要： A serial interface interposed between two serially connected unit cells provides mechanical strength to the serial connection and conductive coupling therebetween. The serial interface includes an inter-connector having a first vent hole formed therein configured for conductively coupling an anode outer wall of a first unit cell and a cathode terminal of a second unit cell to each other; and a spacer having a second vent hole formed therein and configured to be disposed between the inter-connector and an anode outer wall of the second unit cell to prevent a short-circuit due to the movement of the inter-connector.

摘要翻译： 插入在两个串联连接的单元电池之间的串行接口为串联连接提供机械强度并且在它们之间提供导电耦合。 串行接口包括一个连接器，其中形成有第一通气孔，其中构造成将第一单电池的阳极外壁和第二单元电池的阴极端子彼此导电耦合; 以及间隔件，其具有形成在其中的第二通气孔，并且被配置为设置在第二单元电池的连接器间和阳极外壁之间，以防止由于连接器的移动而引起的短路。