摘要:
An electrolyte for a lithium secondary battery includes lithium salts, a non-aqueous organic solvent, and additive compounds, which initiates decomposition at 4V to 5V and show a constant current maintenance plateau region of more than or equal to 0.5V at measurement of LSV (linear sweep voltammetry). The additive compounds added to the electrolyte of the present invention decompose earlier than the organic solvent to form a conductive polymer layer on the surface of a positive electrode by increased electrochemical energy and heat at overcharge. The conductive polymer layer prevents decomposition of the organic solvent. Accordingly, the electrolyte inhibits gas generation caused by decomposition of the organic solvent during high temperature storage, and also improves safety of the battery during overcharge.
摘要:
An electrolyte for a lithium secondary battery includes lithium salts, a non-aqueous organic solvent, and additive compounds. The additive compounds added to the electrolyte of the present invention decompose earlier than the organic solvent to form a conductive polymer layer on the surface of a positive electrode, and prevent decomposition of the organic solvent. Accordingly, the electrolyte inhibits gas generation caused by decomposition of the organic solvent at initial charging, and thus reduces an increase of internal pressure and swelling during high temperature storage, and also improves safety of the battery during overcharge.
摘要:
An electrolyte for a lithium secondary battery includes lithium salts, a non-aqueous organic solvent, and additive compounds, which initiates decomposition at 4V to 5V and show a constant current maintenance plateau region of more than or equal to 0.5V at measurement of LSV (linear sweep voltammetry). The additive compounds added to the electrolyte of the present invention decompose earlier than the organic solvent to form a conductive polymer layer on the surface of a positive electrode by increased electrochemical energy and heat at overcharge. The conductive polymer layer prevents decomposition of the organic solvent. Accordingly, the electrolyte inhibits gas generation caused by decomposition of the organic solvent during high temperature storage, and also improves safety of the battery during overcharge.
摘要:
An electrolyte for a lithium secondary battery includes lithium salts, a non-aqueous organic solvent, and additive compounds, which initiates decomposition at 4V to 5V and show a constant current maintenance plateau region of more than or equal to 0.5V at measurement of LSV (linear sweep voltammetry). The additive compounds added to the electrolyte of the present invention decompose earlier than the organic solvent to form a conductive polymer layer on the surface of a positive electrode by increased electrochemical energy and heat at overcharge. The conductive polymer layer prevents decomposition of the organic solvent. Accordingly, the electrolyte inhibits gas generation caused by decomposition of the organic solvent during high temperature storage, and also improves safety of the battery during overcharge.
摘要:
A non-aqueous electrolyte for a lithium secondary battery is provided. The electrolyte comprises a lithium salt, a non-aqueous solvent, and an organic compound selected from the group consisting of compounds represented by Formulae (1) to (6): wherein R1 to R12 are each independently selected from the group consisting of primary, secondary, and tertiary alkyl groups, alkenyl groups, and aryl groups; X is hydrogen or halogen; and n and m are numerical values ranging from 0 to 3.
摘要:
A non-aqueous electrolyte for a lithium secondary battery is provided. The electrolyte comprises a lithium salt, a non-aqueous solvent, and an organic compound selected from the group consisting of compounds represented by Formulae (1) to (6): wherein R1 to R12 are each independently selected from the group consisting of primary, secondary, and tertiary alkyl groups, alkenyl groups, and aryl groups; X is hydrogen or halogen; and n and m are numerical values ranging from 0 to 3.
摘要:
A non-aqueous electrolyte for a lithium secondary battery is provided. The electrolyte comprises a lithium salt, a non-aqueous solvent, and an organic compound selected from the group consisting of compounds represented by Formulae (1) to (6): wherein R1 to R12 are each independently selected from the group consisting of primary, secondary, and tertiary alkyl groups, alkenyl groups, and aryl groups; X is hydrogen or halogen; and n and m are numerical values ranging from 0 to 3.
摘要:
An electrolyte for a lithium secondary battery is provided. The electrolyte includes a lithium salt, a non-aqueous organic solvent, and a compound represented by Formula (1): wherein R1, R2, and R3 are each independently selected from the group consisting of hydrogen, primary, secondary, and tertiary alkyl groups, alkenyl groups, and aryl groups. The compound of the present invention is decomposed earlier than an electrolytic organic solvent, and an organic SEI film is formed on a negative electrode, thereby inhibiting the electrolytic organic solvent from decomposing.
摘要:
Disclosed is an electrolyte for a lithium secondary battery. The electrolyte includes a non-aqueous solvent and a sulfone based organic compound represented by the following Formulae (I), (II), or (III), or a mixture thereof: where R and R′ are independently selected from the group consisting of primary alkyl groups, secondary alkyl groups, tertiary alkyl groups, alkenyl groups, aryl groups; halogen substituted primary alkyl groups, halogen substituted secondary alkyl groups, halogen substituted tertiary alkyl groups, halogen substituted alkenyl groups, and halogen substituted aryl groups, and n is from 0 to 3.
摘要:
An electrolyte includes a lithium salt, a non-aqueous organic solvent, gamma-butyrolactone and halogenated toluene represented by the following formula 1: wherein X represents at least one element selected from the group consisting of F, Cl, Br and I, and n represents an integer of 1 to 5. The lithium ion secondary battery including the electrolyte provides improved safety under overcharge and high-temperature storage conditions.