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    Dendrimer solid acid and polymer electrolyte membrane including the same
    2.
    发明授权
    Dendrimer solid acid and polymer electrolyte membrane including the same 有权
    树枝状聚合物固体酸和聚合物电解质膜包括相同的

    公开(公告)号：US08049033B2

    公开(公告)日：2011-11-01

    申请号：US11546020

    申请日：2006-10-10

    申请人： Myung-sup Jung ,  Jin-gyu Lee ,  Sang-kook Mah ,  Jae-jun Lee

    发明人： Myung-sup Jung ,  Jin-gyu Lee ,  Sang-kook Mah ,  Jae-jun Lee

    IPC分类号： C07C309/32 ,  C07C309/42 ,  C07C309/33 ,  C07C309/44

    CPC分类号： C08J5/2256 ,  C08J5/2275 ,  C08J2300/00 ,  C08J2300/202 ,  C08J2379/08

    摘要： Provided are a dendrimer solid acid and a polymer electrolyte membrane using the same. The polymer electrolyte membrane includes a macromolecule of a dendrimer solid acid having ionically conductive terminal groups at the surface thereof and a minimum amount of ionically conductive terminal groups required for ionic conduction, thus suppressing swelling and allowing a uniform distribution of the dendrimer solid acid, thereby improving ionic conductivity. Since the number of ionically conductive terminal groups in the polymer electrolyte membrane is minimized and the polymer matrix in which swelling is suppressed is used, methanol crossover and difficulties of outflow due to a large volume may be reduced, and a macromolecule of the dendrimer solid acid having the ionically conductive terminal groups on the surface thereof is uniformly distributed. Accordingly, ionic conductivity is high and thus, the polymer electrolyte membrane shows good ionic conductivity even in non-humidified conditions.

    摘要翻译： 提供了树枝状聚合物固体酸和使用其的聚合物电解质膜。 聚合物电解质膜包括其表面具有离子导电性端基的树枝状聚合物固体酸的高分子和离子传导所需的离子导电性端基的最小量，因此抑制了树枝状聚合物固体酸的均匀分布，从而 提高离子电导率。 由于聚合物电解质膜中的离子导电性端基的数量被最小化，并且使用抑制了溶胀的聚合物基体，所以甲基交联和体积大的流出困难可能降低，并且树枝状聚合物固体酸的高分子 其表面上的离子导电性端基均匀分布。 因此，离子电导率高，因此即使在非加湿条件下，高分子电解质膜也具有良好的离子传导性。

    Dendrimer solid acid and polymer electrolyte membrane including the same
    5.
    发明授权
    Dendrimer solid acid and polymer electrolyte membrane including the same 有权
    树枝状聚合物固体酸和聚合物电解质膜包括相同的

    公开(公告)号：US08119833B2

    公开(公告)日：2012-02-21

    申请号：US13176699

    申请日：2011-07-05

    申请人： Myung-sup Jung ,  Jin-gyu Lee ,  Sang-kook Mah ,  Jae-jun Lee

    发明人： Myung-sup Jung ,  Jin-gyu Lee ,  Sang-kook Mah ,  Jae-jun Lee

    IPC分类号： C07C309/32 ,  C07C309/42 ,  C07C309/33 ,  C07C309/44 ,  H01M8/22

    CPC分类号： C08J5/2256 ,  C08J5/2275 ,  C08J2300/00 ,  C08J2300/202 ,  C08J2379/08

    摘要： Provided are a dendrimer solid acid and a polymer electrolyte membrane using the same. The polymer electrolyte membrane includes a macromolecule of a dendrimer solid acid having ionically conductive terminal groups at the surface thereof and a minimum amount of ionically conductive terminal groups required for ionic conduction, thus suppressing swelling and allowing a uniform distribution of the dendrimer solid acid, thereby improving ionic conductivity. Since the number of ionically conductive terminal groups in the polymer electrolyte membrane is minimized and the polymer matrix in which swelling is suppressed is used, methanol crossover and difficulties of outflow due to a large volume may be reduced, and a macromolecule of the dendrimer solid acid having the ionically conductive terminal groups on the surface thereof is uniformly distributed. Accordingly, ionic conductivity is high and thus, the polymer electrolyte membrane shows good ionic conductivity even in non-humidified conditions.

    摘要翻译： 提供了树枝状聚合物固体酸和使用其的聚合物电解质膜。 聚合物电解质膜包括其表面具有离子导电性端基的树枝状聚合物固体酸的高分子和离子传导所需的离子导电性端基的最小量，因此抑制了树枝状聚合物固体酸的均匀分布，从而 提高离子电导率。 由于聚合物电解质膜中的离子导电性端基的数量被最小化，并且使用抑制了溶胀的聚合物基体，所以甲基交联和体积大的流出困难可能降低，并且树枝状聚合物固体酸的高分子 其表面上的离子导电性端基均匀分布。 因此，离子电导率高，因此即使在非加湿条件下，高分子电解质膜也具有良好的离子传导性。

    DENDRIMER SOLID ACID AND POLYMER ELECTROLYTE MEMBRANE INCLUDING THE SAME
    6.
    发明申请
    DENDRIMER SOLID ACID AND POLYMER ELECTROLYTE MEMBRANE INCLUDING THE SAME 有权
    DENDRIMER固体酸和聚合物电解质膜包括它们

    公开(公告)号：US20110262833A1

    公开(公告)日：2011-10-27

    申请号：US13176699

    申请日：2011-07-05

    申请人： Myung-sup Jung ,  Jin-gyu Lee ,  Sang-kook Mah ,  Jae-jun Lee

    发明人： Myung-sup Jung ,  Jin-gyu Lee ,  Sang-kook Mah ,  Jae-jun Lee

    IPC分类号： H01M8/10

    CPC分类号： C08J5/2256 ,  C08J5/2275 ,  C08J2300/00 ,  C08J2300/202 ,  C08J2379/08

    摘要： Provided are a dendrimer solid acid and a polymer electrolyte membrane using the same. The polymer electrolyte membrane includes a macromolecule of a dendrimer solid acid having ionically conductive terminal groups at the surface thereof and a minimum amount of ionically conductive terminal groups required for ionic conduction, thus suppressing swelling and allowing a uniform distribution of the dendrimer solid acid, thereby improving ionic conductivity. Since the number of ionically conductive terminal groups in the polymer electrolyte membrane is minimized and the polymer matrix in which swelling is suppressed is used, methanol crossover and difficulties of outflow due to a large volume may be reduced, and a macromolecule of the dendrimer solid acid having the ionically conductive terminal groups on the surface thereof is uniformly distributed. Accordingly, ionic conductivity is high and thus, the polymer electrolyte membrane shows good ionic conductivity even in non-humidified conditions.

    摘要翻译： 提供了树枝状聚合物固体酸和使用其的聚合物电解质膜。 聚合物电解质膜包括其表面具有离子导电性端基的树枝状聚合物固体酸的高分子和离子传导所需的离子导电性端基的最小量，因此抑制了树枝状聚合物固体酸的均匀分布，从而 提高离子电导率。 由于聚合物电解质膜中的离子导电性端基的数量被最小化，并且使用抑制了溶胀的聚合物基体，所以甲基交联和体积大的流出困难可能降低，并且树枝状聚合物固体酸的高分子 其表面上的离子导电性端基均匀分布。 因此，离子电导率高，因此即使在非加湿条件下，高分子电解质膜也具有良好的离子传导性。

    Ion-conducting crosslinked copolymer and fuel cell comprising the same
    9.
    发明授权
    Ion-conducting crosslinked copolymer and fuel cell comprising the same 有权
    离子导电交联共聚物和包含其的燃料电池

    公开(公告)号：US07893117B2

    公开(公告)日：2011-02-22

    申请号：US11546779

    申请日：2006-10-11

    申请人： Jae-jun Lee ,  Jin-gyu Lee ,  Sang-kook Mah ,  Myung-sup Jung

    发明人： Jae-jun Lee ,  Jin-gyu Lee ,  Sang-kook Mah ,  Myung-sup Jung

    IPC分类号： C08J5/20 ,  C08G75/00 ,  C08L81/00 ,  H01M8/10

    CPC分类号： C08G65/4056 ,  C08J5/2256 ,  C08J2371/12 ,  H01B1/122 ,  H01M8/04186 ,  H01M8/1011 ,  H01M8/1246 ,  H01M2300/0082 ,  Y02E60/523 ,  Y02E60/525 ,  Y02P70/56

    摘要： An ion-conducting, sulfonated and crosslinked copolymer for use in a fuel cell is disclosed. The ion-conducting, sulfonated and crosslinked copolymer is made up of four monomers. The first monomer is an aromatic diol. The second monomer includes two groups, each group capable of reacting with the hydroxy groups of the first monomer, and each group independently selected from a nitro group and a halogen group. The third monomer is one of the first monomer or the second monomer, except that one of the hydrogen atoms attached to a benzene ring is substituted with —SO3Y, where Y is selected from hydrogen (H), lithium (Li), sodium (Na), potassium (K) and trialkyl ammonium of the form HNR3 where R is an alkyl group having from 1 to 5 carbon atoms. The fourth monomer includes at least three groups, each independently selected from a hydroxy group, a nitro group, and a halogen group.

    摘要翻译： 公开了一种用于燃料电池的离子导电磺化交联共聚物。 离子导电，磺化和交联的共聚物由四种单体组成。 第一单体是芳族二醇。 第二单体包括两个基团，每个基团能够与第一单体的羟基反应，每个基团独立地选自硝基和卤素基团。 第三单体是第一单体或第二单体之一，不同之处在于连接到苯环的一个氢原子被-SO 3 Y取代，其中Y选自氢（H），锂（Li），钠（Na ），钾（K）和HNR 3形式的三烷基铵，其中R是具有1至5个碳原子的烷基。 第四单体包括至少三个基团，各自独立地选自羟基，硝基和卤素基团。