摘要:
New electrostatographic toners and developers are provided containing charge-control agents comprising bis(ammonium) tetrahalocuprate salts having the structure: ##STR1## wherein R, R.sup.1, R.sup.2 and R.sup.3 are the same or different and are independently selected from hydrogen; an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an unsubstituted aryl group having from 6 to 14 carbon atoms; a substituted aryl group having from 6 to 14 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy, acyloxy, amino-, nitro-, cyano-, keto- or halo-groups; or wherein any two or more of R, R.sup.1, R.sup.2, or R.sup.3 can be interconnected to one another to form a 5 to 14 membered saturated or unsaturated ring system, andX, which can be the same or different, is selected from fluorine, chlorine, bromine or iodine.
摘要:
New electrostatographic toners and developers are provided containing charge-control agents comprising bis(ammonium) tetrahalomanganate salts having the structure: ##STR1## wherein R, R.sup.1, R.sup.2 and R.sup.3 are the same or different and are independently selected from hydrogen; an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto-, or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an unsubstituted aryl group having from 6 to 14 carbon atoms; a substituted aryl group having from 6 to 14 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto-, or halo-groups; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; or wherein any two or more of R, R.sup.1, R.sup.2, or R.sup.3 can be interconnected to one another to form a 5 to 14 membered saturated or unsaturated ring system, andX, which can be the same or different, is selected from fluorine, chlorine, Bromine or iodine.
摘要:
New electrostatographic toners and developers are provided containing charge-control agents comprising bis(quaternary phosphonium) tetrahalomanganate salts having the structure: ##STR1## wherein R is selected from an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; phenyl or substituted phenyl;R.sup.1, R.sup.2 and R.sup.3, which can be the same or different, are independently selected from hydrogen; an alkyl group having from 1 to 24 carbon atoms; hydroxy-; carboxy-; alkoxy-; carboalkoxy-; acyloxy-; amino-; nitro-; cyano-; keto-; or halo-groups; andX, which can be the same or different, is independently selected from fluorine, chlorine, bromine or iodine.
摘要:
New electrostatographic toners and developers are provided containing charge-control agents comprising 3,5-di-tertiary-alkyl-4-hydroxybenzenesulfonate salts having the structure: ##STR1## The substituents are defined in the specification.
摘要:
New electrostatographic toners and developers are provided containing charge-control agents comprising ammonium tetrahaloferrate salts having the structure: ##STR1## wherein R, R.sup.1, R.sup.2 and R.sup.3 are the same or different and are independently selected from hydrogen; an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an unsubstituted aryl group having from 6 to 14 carbon atoms; a substituted aryl group having from 6 to 14 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; or wherein any two or more of R, R.sup.1, R.sup.2, or R.sup.3 can be interconnected to one another to form a 5 to 14 membered saturated or unsaturated ring system, andX, which can be the same or different, is selected from fluorine, chlorine, bromine or iodine.
摘要:
New electrostatographic toners and developers are provided containing charge-control agents comprising quaternary phosphonium tetrahaloferrate salts having the structure: ##STR1## wherein R is selected from an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; phenyl or substituted phenyl;R.sup.1, R.sup.2 and R.sup.3, which can be the same or different, are independently selected from hydrogen; an alkyl group having from 1 to 24 carbon atoms; hydroxy-; carboxy-; alkoxy-; carboalkoxy-; acyloxy-; amino-; nitro-; cyano-; keto-; or halo-groups; andX, which can be the same or different, is independently selected from fluorine, chlorine, bromine or iodine.
摘要:
A poly(vinylbenzyl quaternary phosphonium) salt having the following general structure: M represents Fe or Zn;X represents F, Cl, Br or I;p is 3 when M represents Zn and p is 4 when M represents Fe;ortho, meta and para isomers of the vinyl benzyl moiety are included;R.sup.1, R.sup.2 and R.sup.3 represent hydrogen; alkyl having from 1 to 24 carbon atoms; hydroxy-; carboxy-; alkoxy-; carboalkoxy; acyloxy-; amino-; nitro-; cyano-; keto-; or halo-; and R.sup.1, R.sup.2 and R.sup.3 may be independently substituted in the ortho, meta or para positions. R.sup.1, R.sup.2 and R.sup.3 may represent more than one substituent per ring;.brket open-st.Z.brket close-st. represents a copolymerized comonomer selected from the group consisting of acrylamides, acrylic acid, acrylonitrile, alkyl acrylates, alkyl methacrylates, alkyl vinyl ethers, styrenes, maleic anhydride, methacrylamides, methacrylic acid, methacrylonitrile, silyl methacrylates, vinyl esters, vinyl amides and vinyl halides andm and n together total 100 mole percent wherein m is 0.01 to 100.00 mole percent.
摘要:
An ultraviolet light absorbing polyester resin and toner particles incorporating such polymer are provided. The toner particles are particularly useful in photolithographic applications wherein ultraviolet light is used for making printing plates from color separation transparencies which contain imaged areas defined by the toner particles. The toner particles can be prepared, if desired, in finely divided form capable of forming high resolution electrographic images, and the toner particles can be used in dry or liquid developer formulation. The toner particles are heat fusible preferably at low temperatures, resist toner offset, and have good cohesivity.
摘要:
A toner composition and a xerographic process for making lithographic plates using the toner composition is provided. The toner composition can be prepared in the form of a dry powder, a polymeric limited coalescence composition, or an evaporative limited coalescence composition. The toner composition absorbs light in the frequency range of 300 to 450 nm and has a total transmission density of at least about 3 at a stack height of about 10 microns. Positive transparencies are produced with imaged areas formed from the toner composition using conventional photocomposing. The transparencies are then employed for contact exposing of positive-working lithographic plates with light, and the plates are then developed.
摘要:
New electrostatographic toners and developers are provided containing charge-control agents comprising quaternary phosphonium trihalozincate salts having the structure: ##STR1## wherein R is selected from an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group is unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; phenyl or substituted phenyl;R.sup.1, R.sup.2 and R.sup.3, which can be the same or different, are independently selected from hydrogen; an alkyl group having from 1 to 24 carbon atoms; hydroxy-; carboxy-; alkoxy-; carboalkoxy-; acyloxy-; amino-; nitro-; cyano-; keto-; or halo-groups; andX, which can be the same or different, is independently selected from fluorine, chlorine, bromine or iodine.