Toners and developers containing BIS(ammonium) tetrahalocuprate salts as
charge-control agents
    1.
    发明授权
    Toners and developers containing BIS(ammonium) tetrahalocuprate salts as charge-control agents 失效
    含有四卤琥珀酸BIS(铵)作为电荷控制剂的调色剂和显影剂

    公开(公告)号:US5616444A

    公开(公告)日:1997-04-01

    申请号:US350604

    申请日:1994-12-07

    IPC分类号: G03G9/097

    CPC分类号: G03G9/09741 G03G9/09783

    摘要: New electrostatographic toners and developers are provided containing charge-control agents comprising bis(ammonium) tetrahalocuprate salts having the structure: ##STR1## wherein R, R.sup.1, R.sup.2 and R.sup.3 are the same or different and are independently selected from hydrogen; an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an unsubstituted aryl group having from 6 to 14 carbon atoms; a substituted aryl group having from 6 to 14 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy, acyloxy, amino-, nitro-, cyano-, keto- or halo-groups; or wherein any two or more of R, R.sup.1, R.sup.2, or R.sup.3 can be interconnected to one another to form a 5 to 14 membered saturated or unsaturated ring system, andX, which can be the same or different, is selected from fluorine, chlorine, bromine or iodine.

    摘要翻译: 提供了新的静电色调调色剂和显影剂,其含有电荷控制剂,其包含具有以下结构的双(铵)四卤代磷酸盐:其中R,R 1,R 2和R 3相同或不同并且独立地选自氢; 具有1至24个碳原子的未取代的烷基; 被一个或多个羟基,羧基,烷氧基,烷氧基,酰氧基,硝基,氰基,酮基或卤代基取代的碳原子数1〜24的取代烷基。 具有3至7个碳原子的环烷基; 具有6至14个碳原子的未取代的芳基; 被一个或多个羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基取代的具有6至14个碳原子的取代的芳基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子的芳烷基和在芳基中具有6至14个碳原子的芳烷基,其中芳基可以是未被取代的或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 ,酰氧基,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基; 或其中R,R 1,R 2或R 3中的任何两个或更多个可以彼此互连以形成5至14元饱和或不饱和的环系,并且可以相同或不同的X选自氟, 氯,溴或碘。

    Toners and developers containing bis(ammonium) tetrahalomanganate salts
as charge-control agents
    2.
    发明授权
    Toners and developers containing bis(ammonium) tetrahalomanganate salts as charge-control agents 失效
    含有双(铵)四卤代锰酸盐的调色剂和显影剂作为电荷控制剂

    公开(公告)号:US5582946A

    公开(公告)日:1996-12-10

    申请号:US350592

    申请日:1994-12-07

    IPC分类号: G03G9/097

    摘要: New electrostatographic toners and developers are provided containing charge-control agents comprising bis(ammonium) tetrahalomanganate salts having the structure: ##STR1## wherein R, R.sup.1, R.sup.2 and R.sup.3 are the same or different and are independently selected from hydrogen; an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto-, or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an unsubstituted aryl group having from 6 to 14 carbon atoms; a substituted aryl group having from 6 to 14 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto-, or halo-groups; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; or wherein any two or more of R, R.sup.1, R.sup.2, or R.sup.3 can be interconnected to one another to form a 5 to 14 membered saturated or unsaturated ring system, andX, which can be the same or different, is selected from fluorine, chlorine, Bromine or iodine.

    摘要翻译: 提供了新的静电色调剂和显影剂,其含有电荷控制剂,其包含具有以下结构的双(铵)四卤代高锰酸盐:其中R,R 1,R 2和R 3相同或不同并且独立地选自氢; 具有1至24个碳原子的未取代的烷基; 具有1至24个碳原子的取代的烷基被一个或多个羟基,羧基,烷氧基,烷氧基,酰氧基,硝基,氰基,酮基或卤代基取代; 具有3至7个碳原子的环烷基; 具有6至14个碳原子的未取代的芳基; 被一个或多个羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基取代的具有6至14个碳原子的取代芳基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子的芳烷基和在芳基中具有6至14个碳原子的芳烷基,其中芳基可以是未被取代的或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基团; 或其中R,R 1,R 2或R 3中的任何两个或更多个可以彼此互连以形成5至14元饱和或不饱和的环系,并且可以相同或不同的X选自氟, 氯,溴或碘。

    Bis(quaternary phosphonium) tetrahalomanganate salts as charge-control
agents
    3.
    发明授权
    Bis(quaternary phosphonium) tetrahalomanganate salts as charge-control agents 失效
    双(季鏻)四卤代马来酸盐作为电荷控制剂

    公开(公告)号:US5512407A

    公开(公告)日:1996-04-30

    申请号:US350790

    申请日:1994-12-07

    IPC分类号: G03G9/097

    摘要: New electrostatographic toners and developers are provided containing charge-control agents comprising bis(quaternary phosphonium) tetrahalomanganate salts having the structure: ##STR1## wherein R is selected from an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; phenyl or substituted phenyl;R.sup.1, R.sup.2 and R.sup.3, which can be the same or different, are independently selected from hydrogen; an alkyl group having from 1 to 24 carbon atoms; hydroxy-; carboxy-; alkoxy-; carboalkoxy-; acyloxy-; amino-; nitro-; cyano-; keto-; or halo-groups; andX, which can be the same or different, is independently selected from fluorine, chlorine, bromine or iodine.

    摘要翻译: 提供了新的静电彩色调色剂和显影剂,其含有电荷控制剂,其包含具有以下结构的双(季鏻)四卤代高锰酸盐:其中R选自未取代的具有1至24个碳原子的烷基; 具有1至24个碳原子的取代的烷基被一个或多个羟基,羧基,烷氧基 - ,烷酰氧基 - ,酰氧基 - ,硝基 - ,氰基 - ,酮基或卤代基取代; 具有3至7个碳原子的环烷基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子的芳烷基和在芳基中具有6至14个碳原子的芳烷基,其中芳基可以是未被取代的或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基团; 苯基或取代的苯基; R 1,R 2和R 3可以相同或不同,独立地选自氢; 具有1至24个碳原子的烷基; 羟基 - 羧基 烷氧基 碳烷氧基 酰氧基 - 氨基 - 硝基 氰基 酮基 或卤代基团; 和X可以相同或不同,独立地选自氟,氯,溴或碘。

    Toners and developers containing ammonium tetrahaloferrate salts as
charge-control agents
    5.
    发明授权
    Toners and developers containing ammonium tetrahaloferrate salts as charge-control agents 失效
    含有四卤代钒酸盐作为电荷控制剂的调色剂和显影剂

    公开(公告)号:US5464719A

    公开(公告)日:1995-11-07

    申请号:US350598

    申请日:1994-12-07

    IPC分类号: G03G9/083 G03G9/097

    摘要: New electrostatographic toners and developers are provided containing charge-control agents comprising ammonium tetrahaloferrate salts having the structure: ##STR1## wherein R, R.sup.1, R.sup.2 and R.sup.3 are the same or different and are independently selected from hydrogen; an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an unsubstituted aryl group having from 6 to 14 carbon atoms; a substituted aryl group having from 6 to 14 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; or wherein any two or more of R, R.sup.1, R.sup.2, or R.sup.3 can be interconnected to one another to form a 5 to 14 membered saturated or unsaturated ring system, andX, which can be the same or different, is selected from fluorine, chlorine, bromine or iodine.

    摘要翻译: 提供了新的静电调色剂和显影剂,其含有电荷控制剂,其包含具有以下结构的四卤代钒酸盐:其中R,R 1,R 2和R 3相同或不同并且独立地选自氢; 具有1至24个碳原子的未取代的烷基; 被一个或多个羟基,羧基,烷氧基,烷氧基,酰氧基,硝基,氰基,酮基或卤代基取代的碳原子数1〜24的取代烷基。 具有3至7个碳原子的环烷基; 具有6至14个碳原子的未取代的芳基; 被一个或多个羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基取代的具有6至14个碳原子的取代的芳基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子的芳烷基和在芳基中具有6至14个碳原子的芳烷基,其中芳基可以是未被取代的或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基团; 或其中R,R 1,R 2或R 3中的任何两个或更多个可以彼此互连以形成5至14元饱和或不饱和的环系,并且可以相同或不同的X选自氟, 氯,溴或碘。

    Quaternary phosphonium tetrahaloferrate salts as charge-control agents
for toners
    6.
    发明授权
    Quaternary phosphonium tetrahaloferrate salts as charge-control agents for toners 失效
    四卤代四氢鏻盐作为调色剂的电荷控制剂

    公开(公告)号:US5459006A

    公开(公告)日:1995-10-17

    申请号:US350564

    申请日:1994-12-07

    IPC分类号: A62D101/24 G03G9/097

    CPC分类号: G03G9/09741 A62D2101/24

    摘要: New electrostatographic toners and developers are provided containing charge-control agents comprising quaternary phosphonium tetrahaloferrate salts having the structure: ##STR1## wherein R is selected from an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; phenyl or substituted phenyl;R.sup.1, R.sup.2 and R.sup.3, which can be the same or different, are independently selected from hydrogen; an alkyl group having from 1 to 24 carbon atoms; hydroxy-; carboxy-; alkoxy-; carboalkoxy-; acyloxy-; amino-; nitro-; cyano-; keto-; or halo-groups; andX, which can be the same or different, is independently selected from fluorine, chlorine, bromine or iodine.

    摘要翻译: 提供了新的静电调色剂和显影剂,其含有电荷控制剂,其包含具有以下结构的四卤代钒酸盐:其中R选自未取代的具有1至24个碳原子的烷基; 具有1至24个碳原子的取代的烷基被一个或多个羟基,羧基,烷氧基 - ,烷酰氧基 - ,酰氧基 - ,硝基 - ,氰基 - ,酮基或卤代基取代; 具有3至7个碳原子的环烷基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子的芳烷基和在芳基中具有6至14个碳原子的芳烷基,其中芳基可以是未被取代的或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基团; 苯基或取代的苯基; R 1,R 2和R 3可以相同或不同,独立地选自氢; 具有1至24个碳原子的烷基; 羟基 - 羧基 烷氧基 碳烷氧基 酰氧基 - 氨基 - 硝基 氰基 酮基 或卤代基团; 和X可以相同或不同,独立地选自氟,氯,溴或碘。

    Poly(vinylbenzyl quaternary phoshonium) salt charge control agents
    7.
    发明授权
    Poly(vinylbenzyl quaternary phoshonium) salt charge control agents 失效
    聚(乙烯基苄基季铵盐)盐电荷控制剂

    公开(公告)号:US6027847A

    公开(公告)日:2000-02-22

    申请号:US96109

    申请日:1998-06-11

    IPC分类号: G03G9/087 G03G9/097

    CPC分类号: G03G9/09741 G03G9/08791

    摘要: A poly(vinylbenzyl quaternary phosphonium) salt having the following general structure: M represents Fe or Zn;X represents F, Cl, Br or I;p is 3 when M represents Zn and p is 4 when M represents Fe;ortho, meta and para isomers of the vinyl benzyl moiety are included;R.sup.1, R.sup.2 and R.sup.3 represent hydrogen; alkyl having from 1 to 24 carbon atoms; hydroxy-; carboxy-; alkoxy-; carboalkoxy; acyloxy-; amino-; nitro-; cyano-; keto-; or halo-; and R.sup.1, R.sup.2 and R.sup.3 may be independently substituted in the ortho, meta or para positions. R.sup.1, R.sup.2 and R.sup.3 may represent more than one substituent per ring;.brket open-st.Z.brket close-st. represents a copolymerized comonomer selected from the group consisting of acrylamides, acrylic acid, acrylonitrile, alkyl acrylates, alkyl methacrylates, alkyl vinyl ethers, styrenes, maleic anhydride, methacrylamides, methacrylic acid, methacrylonitrile, silyl methacrylates, vinyl esters, vinyl amides and vinyl halides andm and n together total 100 mole percent wherein m is 0.01 to 100.00 mole percent.

    摘要翻译: 具有以下一般结构的聚(乙烯基苄基季鏻)盐:M代表Fe或Zn; X表示F,Cl,Br或I; 当M表示Zn时,p为3,当M表示Fe时p为4; 包括乙烯基苄基部分的邻位,间位和对位异构体; R1,R2和R3表示氢; 具有1至24个碳原子的烷基; 羟基 - 羧基 烷氧基 碳烷氧基 酰氧基 - 氨基 - 硝基 氰基 酮基 或卤素 并且R 1,R 2和R 3可以在邻位,间位或对位独立地被取代。 R 1,R 2和R 3可以表示每个环多于一个取代基; +547Z + 548表示选自丙烯酰胺,丙烯酸,丙烯腈,丙烯酸烷基酯,甲基丙烯酸烷基酯,烷基乙烯基醚,苯乙烯,马来酸酐,甲基丙烯酰胺,甲基丙烯酸,甲基丙烯腈,甲基丙烯酸甲硅烷酯,乙烯基酯等的共聚合共聚单体, 乙烯基酰胺和乙烯基卤化物,m和n共计为100摩尔%,其中m为0.01至100.00摩尔%。

    Polyesters and toners made therewith which absorb ultraviolet light
    8.
    发明授权
    Polyesters and toners made therewith which absorb ultraviolet light 失效
    由此制成的聚酯和调色剂吸收紫外线

    公开(公告)号:US5102762A

    公开(公告)日:1992-04-07

    申请号:US645529

    申请日:1991-01-24

    摘要: An ultraviolet light absorbing polyester resin and toner particles incorporating such polymer are provided. The toner particles are particularly useful in photolithographic applications wherein ultraviolet light is used for making printing plates from color separation transparencies which contain imaged areas defined by the toner particles. The toner particles can be prepared, if desired, in finely divided form capable of forming high resolution electrographic images, and the toner particles can be used in dry or liquid developer formulation. The toner particles are heat fusible preferably at low temperatures, resist toner offset, and have good cohesivity.

    摘要翻译: 提供紫外光吸收聚酯树脂和掺入这种聚合物的调色剂颗粒。 调色剂颗粒在光刻应用中特别有用,其中紫外光用于从包含由调色剂颗粒限定的成像区域的分色透明胶片制备印版。 如果需要,调色剂颗粒可以以能够形成高分辨率电摄影图像的细碎形式制备,并且调色剂颗粒可以用于干燥或液体显影剂制剂中。 调色剂颗粒优选在低温下易熔融,抵抗调色剂偏移并且具有良好的内聚力。

    Xerographic phototypesetting system and toner useful therein
    9.
    发明授权
    Xerographic phototypesetting system and toner useful therein 失效
    静电复印照相系统和有用的调色剂

    公开(公告)号:US5063132A

    公开(公告)日:1991-11-05

    申请号:US434379

    申请日:1989-11-13

    摘要: A toner composition and a xerographic process for making lithographic plates using the toner composition is provided. The toner composition can be prepared in the form of a dry powder, a polymeric limited coalescence composition, or an evaporative limited coalescence composition. The toner composition absorbs light in the frequency range of 300 to 450 nm and has a total transmission density of at least about 3 at a stack height of about 10 microns. Positive transparencies are produced with imaged areas formed from the toner composition using conventional photocomposing. The transparencies are then employed for contact exposing of positive-working lithographic plates with light, and the plates are then developed.

    摘要翻译: 提供了调色剂组合物和使用调色剂组合物制造平版印刷版的静电复印印刷方法。 调色剂组合物可以以干粉,聚合物有限聚结组合物或蒸发有限聚结组合物的形式制备。 调色剂组合物在300至450nm的频率范围内吸收光,并且在堆叠高度为约10微米时具有至少约3的总透射密度。 通过使用常规光聚合从调色剂组合物形成的成像区域产生正透明胶片。 然后使用透明胶片将正性工作平板印刷板与光接触曝光,然后显影板。

    Quaternary phosphonium trihalozincate salts as charge-control agents for
toners and developers
    10.
    发明授权
    Quaternary phosphonium trihalozincate salts as charge-control agents for toners and developers 失效
    季铵盐三卤代盐作为调色剂和显影剂的电荷控制剂

    公开(公告)号:US5561020A

    公开(公告)日:1996-10-01

    申请号:US350775

    申请日:1994-12-07

    IPC分类号: G03G9/097

    摘要: New electrostatographic toners and developers are provided containing charge-control agents comprising quaternary phosphonium trihalozincate salts having the structure: ##STR1## wherein R is selected from an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group is unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; phenyl or substituted phenyl;R.sup.1, R.sup.2 and R.sup.3, which can be the same or different, are independently selected from hydrogen; an alkyl group having from 1 to 24 carbon atoms; hydroxy-; carboxy-; alkoxy-; carboalkoxy-; acyloxy-; amino-; nitro-; cyano-; keto-; or halo-groups; andX, which can be the same or different, is independently selected from fluorine, chlorine, bromine or iodine.

    摘要翻译: 提供了新的静电调色剂和显影剂,其含有电荷控制剂,其包含具有以下结构的季铵鏻三卤代酸盐:其中R选自未取代的具有1至24个碳原子的烷基; 被一个或多个羟基,羧基,烷氧基,烷氧基,酰氧基,硝基,氰基,酮基或卤代基取代的碳原子数1〜24的取代烷基。 具有3至7个碳原子的环烷基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子且在芳基中具有6至14个碳原子的芳烷基,其中芳基未被取代或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基; 苯基或取代的苯基; R 1,R 2和R 3可以相同或不同,独立地选自氢; 具有1至24个碳原子的烷基; 羟基 - 羧基 烷氧基 碳烷氧基 酰氧基 - 氨基 - 硝基 氰基 酮基 或卤代基团; 和X可以相同或不同,独立地选自氟,氯,溴或碘。