摘要:
A method of treating mercury-contaminated material to obtain a treated product having reduced mercury leachability includes the steps of (a) admixing the mercury-contaminated material with a reagent system comprising calcium sulfide (CaS) and trisodium phosphate (TNaP), wherein the calcium sulfide and trisodium phosphate are preferably provided at a CaS:TNaP ratio of from 2:1 to 1:2, on a dry weight reagent basis, and the reagent system is preferably provided in an amount equal to 0.4% to 5% by weight of the contaminated material; and (b) adding water as needed to achieve a moisture content of at least 5% by weight of the contaminated material.
摘要:
Provided is a practically valuable and economically excellent insolubilizing material for a specific toxic substance: that is useful for insolubilizing treatment for a heavy metal or the like conducted by applying the insolubilizing material for a specific toxic substance to soil or on the surface of the soil; that is capable of effectively insolubilizing and immobilizing the heavy metal or the like; that is capable of making treated matter neutral so as to be reusable and environment-friendly; and moreover that is capable of imparting strength to the treated matter as necessary; and with which the heavy metal or the like is not re-eluted even when the treated matter is exposed to an environment under a neutral condition or an acidic condition. An insolubilizing material for a specific toxic substance to be used so that soil does not reach a strongly alkaline region of a pH of 11 or more, wherein the insolubilizing material for a specific toxic substance comprises an amorphous aluminum compound or a derivative thereof as a main component, or an insolubilizing material for a specific toxic substance to be used so that soil containing a heavy metal or the like does not reach a strongly alkaline region of a pH of 11 or more, the insolubilizing material for a specific toxic substance functioning also as a solidifying material, wherein the insolubilizing material for a specific toxic substance comprises gypsum obtained by adding and mixing, to the gypsum, the amorphous aluminum compound and the derivative thereof in a range of 0.5 to 60 mass parts relative to 100 mass parts of the gypsum, and a method for improving soil using the insolubilizing material for a specific toxic substance.
摘要:
It is an object of the present invention to provide a beneficial composition in order to detoxify the harmful compound containing arsenic etc. effectively and systematically and a method for detoxifying a harmful compound by using the composition. The composition for the alkylation according to the present invention is characterized in that the composition contains a cobalt complex. The method of detoxifying the harmful compound according to the present invention is characterized in that a harmful compound containing at least one element selected from the groups comprising arsenic, antimony and selenium is detoxified by the alkylation of the harmful compound, in the presence of the composition according to the present invention.
摘要:
The invention relates to a system and method for the substantially permanent biogeochemical stabilization of solids impacted with hexavalent chromium/Cr(VI), including chromite ore processing residue (“COPR”). The invention comprises a novel treatment method of adding amendment(s) to COPR or other chromate impacted solids for the purpose of (1) weathering COPR minerals (when present) to convert the minerals that control alkalinity of the COPR to non-alkaline forms and liberate incorporated hexavalent chromium (Cr(VI)) in the process; (2) providing a chemical reductant (ferrous iron) to rapidly and permanently reduce the available Cr(VI) to trivalent form (Cr(III)); and/or (3) supporting longer-term biogeochemical Cr(VI) reduction enhanced by recycling of the chemical reductant, ultimately rendering the material non-hazardous as measured by acceptable methods. Amendments include but are not limited to acids; sources of ferrous iron; fermentable organic carbon source(s); and/or a source of active anaerobic microbes.
摘要:
The invention provides an optimal method for stabilization of heavy metal bearing paint residue subject to acid and water leaching tests or leach conditions by addition of environment safe, worker safe, multi-media compatible, non-separating, non-embedding, stabilizing agent and optional complexing agent(s) to the blast media, thus allowing for pre-blending of stabilizer and blast media and field production of a uniform and steady state stabilizer within media for stabilization outside or within an OSHA containment building or collection device, such that leaching of heavy metals such as lead are inhibited to desired levels. The resultant stabilized paint residue and spent blast media mixture is suitable for on-site reuse, off-site reuse, or disposal as RCRA non-hazardous waste.
摘要:
This invention provides a method for the treatment of wastes and materials by addition of Amber Phosphoric Acid to reduce the PCB content and/or TCLP Pb content, thus allowing treated materials or waste to be classified as non-Toxic Substance Control Act (TSCA) waste and/or non-hazardous RCRA solid waste, or otherwise allowed to be reused or land filled at a cost lower than without such treatment.
摘要:
A method of disposing of two or more waste materials, including at least one hazardous waste material, which method includes the steps of: obtaining a waste byproduct; producing a reagent from the waste byproduct which reagent includes one or more contaminates; obtaining a waste material containing one or more hazardous heavy metals; treating the hazardous heavy metal containing waste material with the reagent from step b) to stabilize the hazardous heavy metal containing waste material; and disposing of the stabilized hazardous heavy metal containing waste material. According to one embodiment the waste byproduct is gypsum. The gypsum can be obtained from a flue gas desulfurization process. According to another embodiment the waste byproduct is a calcium carbonate containing byproduct which is reacted with acid tar to produce calcium sulfide. The calcium carbonate containing byproduct can come from a Solvay process.
摘要:
It is an object of the present invention to provide a method of detoxifying a methyl compound comprising arsenic etc., effectively and systematically. The method of detoxifying a methyl compound according to the present invention is characterized in that an organic halogenated compound is reacted with a methyl compound comprising at least one element selected from the groups comprising arsenic, antimony and selenium to convert the methyl compound into more harmless substances. Furthermore, in a preferred embodiment of the method of detoxifying a methyl compound according to the present invention, the method is characterized in that the element is arsenic.
摘要:
The invention is a method for stabilizing heavy metals of the fly ash, the bottom ash or the soil. The stabilization agents which belong to silicate materials, was added to fly ash bottom ash or soil by sprinkling or directly subjoining mix and so on. After this reaction, low soluble and stabilize Heavy metal-Silicate compounds which were formed and didn't re-leaching heavy metals easily (especially, Pb) in the nature environment, even leaching results could below the regulated values and fill the reuse regulations
摘要:
Methods to reduce hexavalent chromium (Cr(VI)) in chromite processing wastes include one or more of the following steps: contacting the chromite processing wastes with an oxygen scavenger or chemical reducer; permitting the chromite processing wastes to react with the oxygen scavenger or chemical reducer; contacting the chromite processing wastes with ferrous ion; contacting the chromite processing wastes with sulfide ion; and, contacting the chromite processing wastes with ferrous sulfide.