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公开(公告)号：US5264650A
公开(公告)日：1993-11-23
申请号：US991919
申请日：1992-12-17
申请人： Michael A. Better , Jonathan E. Child , Kenneth J. Del Rossi , Edward H. Edelson , Anagha A. Gupte , Rafi Jalkian , Tomas R. Melli , Sergei Yurchak
发明人： Michael A. Better , Jonathan E. Child , Kenneth J. Del Rossi , Edward H. Edelson , Anagha A. Gupte , Rafi Jalkian , Tomas R. Melli , Sergei Yurchak
CPC分类号： C01B7/195 , C07C2/62 , C07C2527/1206
摘要： The present invention provides a method for separating conjunct polymers which are formed as byproducts of acid catalyzed isoparaffin-olefin alkylation and sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid comprising the sequential steps of:(a) separating hydrofluoric acid from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid to provide a first intermediate stream containing less than about 30 percent hydrofluoric acid by weight;(b) mixing said intermediate stream with a nonpolar extraction solvent to provide a second intermediate stream; and(c) gravitationally separating said intermediate stream into a less dense extract stream enriched in conjunct polymers and a more dense liquid stream enriched in sulfolane.
摘要翻译： 本发明提供了一种从含有结合聚合物，环丁砜和氢氟酸的混合物中分离形成酸催化的异链烷烃 - 烯烃烷基化和环丁砜副产物的结合聚合物的方法，其包括以下步骤：（a）将氢氟酸与 含有结合聚合物，环丁砜和氢氟酸的混合物，以提供含有按重量计小于约30％氢氟酸的第一中间物流; （b）将所述中间物流与非极性萃取溶剂混合以提供第二中间物流; 和（c）将所述中间物流重力分离成富含结合聚合物的较不致密的提取物流和富含环丁砜的更致密的液体物流。
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2.发明授权Method for separating conjunct polymeric byproducts from mixture containing hydrofluoric acid and a sulfone 失效从包含氢氟酸和砜的混合物中分离结合的聚合副产物的方法
公开(公告)号：US5264652A
公开(公告)日：1993-11-23
申请号：US991921
申请日：1992-12-17
申请人： Jonathan E. Child , Edward H. Edelson , Anagha A. Gupte , Rafi Jalkian , Tomas R. Melli , Sergei Yurchak
发明人： Jonathan E. Child , Edward H. Edelson , Anagha A. Gupte , Rafi Jalkian , Tomas R. Melli , Sergei Yurchak
CPC分类号： C01B7/195 , C07C2/62 , C07C9/16 , C07C2527/1206
摘要： The present invention provides a method for separating conjunct polymers which are formed as byproducts of acid catalyzed isoparaffin-olefin alkylation and sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid comprising the sequential steps of:(a) separating hydrofluoric acid from said mixture to provide an intermediate stream containing less than about 30 percent hydrofluoric acid by weight;(b) gravitationally separating said intermediate stream into a more dense sulfolane-enriched stream and a less dense conjunct polymer-enriched stream;(c) distilling said more dense sulfolane-enriched stream of step (b) to provide an overhead stream containing a higher sulfolane concentration than said more dense sulfolane-enriched stream of step (b) and a bottom stream enriched in conjunct polymers.
摘要翻译： 本发明提供一种从含有结合聚合物，环丁砜和氢氟酸的混合物中分离出作为酸催化的异链烷烃 - 烯烃烷基化和环丁砜的副产物形成的结合聚合物的方法，包括以下顺序步骤：（a）将氢氟酸与所述 混合物以提供含有按重量计小于约30％氢氟酸的中间料流; （b）将所述中间物流重力分离成更稠密的富含环丁砜的物流和不太致密的结合聚合物富集料流; （c）蒸馏步骤（b）的所述更稠密的富含环丁砜的物流，以提供比步骤（b）的所述更致密的富含环丁砜的物流高的环丁砜浓度的塔顶物流和富含结合聚合物的塔底物流。
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公开(公告)号：US5304522A
公开(公告)日：1994-04-19
申请号：US069486
申请日：1993-06-01
申请人： Rafi Jalkian , Tomas R. Melli
发明人： Rafi Jalkian , Tomas R. Melli
CPC分类号： B01J31/4092 , B01J27/32 , B01J31/0222 , C01B7/197 , C07C2/62 , B01J2231/4205 , B01J27/12 , B01J31/06 , C07C2527/1206 , Y02P20/584
摘要： A process is disclosed for regenerating a spent liquid acid catalyst comprising the steps of:(a) providing a spent liquid acid catalyst comprising HF, sulfolane, and conjunct polymeric byproducts formed during the HF-catalyzed reaction of isoparaffin and olefin to form isoparafinnic alkylate;(b) providing a finely divided solid sorbent, wherein said solid sorbent preferentially and reversibly sorbs said conjunct polymeric byproducts from a mixture containing HF, sulfolane;(c) mixing said spent liquid acid catalyst of step (a) with said solid sorbent of step (b) by charging said spent liquid acid catalyst to the driving fluid inlet of an eductor and drawing a stream containing said solid sorbent into said eductor;(d) holding said mixture of step (c) in contact for time sufficient for said solid sorbent to preferentially sorb at least a portion of said conjunct polymeric byproducts from said spent liquid acid catalyst to produce a conjunct polymer-enriched sorbent and to regenerate said liquid acid catalyst; and(e) separating said conjunct polymer-enriched sorbent from said regenerated liquid acid catalyst;(f) soaking said conjunct polymer-enriched sorbent in a solvent to desorb said conjunct polymeric byproducts; and(g) recycling said solid sorbent to said mixing step (c).
摘要翻译： 公开了一种用于再生废液酸催化剂的方法，包括以下步骤：（a）提供废液体酸催化剂，其包含HF，环丁砜和在异链烷烃和烯烃的HF催化反应期间形成的结合的聚合副产物以形成异烷烃烷基化物; （b）提供细碎的固体吸附剂，其中所述固体吸附剂优先和可逆地从包含HF，环丁砜的混合物中吸收所述结合的聚合副产物; （c）将步骤（a）的所述废液体酸催化剂与步骤（b）的固体吸附剂混合，将所述废液酸催化剂装入喷射器的驱动流体入口并将含有所述固体吸附剂的料流抽吸到所述喷射器中; （d）将所述步骤（c）的混合物保持接触足以使所述固体吸附剂从所述废液酸催化剂中优先吸附所述结合的聚合副产物的至少一部分的时间，以产生富含凝结聚合物的吸附剂，并再生所述 液体酸催化剂; 和（e）从所述再生液体酸催化剂中分离出富含凝结物的富集吸附剂; （f）将富集的富含聚合物的吸附剂浸泡在溶剂中以解吸所述结合的聚合副产物; 和（g）将所述固体吸附剂再循环到所述混合步骤（c）。
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4.发明申请Method for determining asphaltenes contamination in used marine engine lubricants using UV-visible spectroscopy and chemometrics 有权使用紫外 - 可见光谱和化学计量学测定废旧船用发动机润滑油中沥青质污染的方法公开(公告)号：US20070231912A1
公开(公告)日：2007-10-04
申请号：US11809457
申请日：2007-06-01
申请人： Paul Reischman , Rafi Jalkian
发明人： Paul Reischman , Rafi Jalkian
IPC分类号： G01N33/28
CPC分类号： G01N21/88 , G01N21/33 , G01N33/2835 , G01N33/2888 , G01N2021/3155
摘要： A method for determining contamination in marine diesel lubricating oils. The method has been found to have particular utility in estimating asphaltenes contamination in marine diesel lubricating oils. The method includes the steps of: (a) obtaining spectral raw data over a frequency range substantially equivalent to that of ultraviolet-visible light for reference lubricating oil samples with known properties and concentrations of asphaltenes; (b) performing chemometric techniques to the spectral raw data obtained in step (a) to develop a calibration model and calibrate the spectral data with actual values for parameters reflecting the level of asphaltenes contamination of the reference samples, the actual values determined by means of conventional analytical methods; (c) obtaining spectra of samples of marine diesel lubricating oil of unknown concentration of asphaltenes over a frequency range substantially equivalent to that of ultraviolet-visible light; and (d) processing the obtained spectral raw data of step (c) and applying the developed calibration model to the processed data in order to determine the parameters reflecting the level of asphaltenes present in the marine diesel lubricating oil.
摘要翻译： 一种确定船用柴油润滑油污染的方法。 已经发现该方法在估计船用柴油润滑油中沥青质污染方面具有特殊的用途。 该方法包括以下步骤：（a）在具有已知性质和沥青质浓度的参考润滑油样品的基础上获得与紫外 - 可见光基本相同的频率范围内的光谱原始数据; （b）对在步骤（a）中获得的光谱原始数据进行化学计量技术以开发校准模型并且校准具有反映参考样品的沥青质污染水平的参数的实际值的光谱数据，通过 常规分析方法; （c）在基本上等于紫外 - 可见光的频率范围内获得浓度未知浓度的沥青质的船用柴油润滑油样品的光谱; 和（d）处理所获得的步骤（c）的光谱原始数据并将开发的校准模型应用于经处理的数据，以便确定反映船用柴油润滑油中存在的沥青质水平的参数。
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5.发明授权Method for determining asphaltenes contamination in used marine engine lubricants using UV-visible spectroscopy and chemometrics 有权使用紫外 - 可见光谱和化学计量学测定废旧船用发动机润滑油中沥青质污染的方法公开(公告)号：US07407809B2
公开(公告)日：2008-08-05
申请号：US11809457
申请日：2007-06-01
CPC分类号： G01N21/88 , G01N21/33 , G01N33/2835 , G01N33/2888 , G01N2021/3155
摘要： A method for determining contamination in marine diesel lubricating oils. The method has been found to have particular utility in estimating asphaltenes contamination in marine diesel lubricating oils. The method includes the steps of: (a) obtaining spectral raw data over a frequency range substantially equivalent to that of ultraviolet-visible light for reference lubricating oil samples with known properties and concentrations of asphaltenes; (b) performing chemometric techniques to the spectral raw data obtained in step (a) to develop a calibration model and calibrate the spectral data with actual values for parameters reflecting the level of asphaltenes contamination of the reference samples, the actual values determined by means of conventional analytical methods; (c) obtaining spectra of samples of marine diesel lubricating oil of unknown concentration of asphaltenes over a frequency range substantially equivalent to that of ultraviolet-visible light; and (d) processing the obtained spectral raw data of step (c) and applying the developed calibration model to the processed data in order to determine the parameters reflecting the level of asphaltenes present in the marine diesel lubricating oil.
摘要翻译： 一种确定船用柴油润滑油污染的方法。 已经发现该方法在估计船用柴油润滑油中沥青质污染方面具有特殊的用途。 该方法包括以下步骤：（a）在具有已知性质和沥青质浓度的参考润滑油样品的基础上获得与紫外 - 可见光基本相同的频率范围内的光谱原始数据; （b）对在步骤（a）中获得的光谱原始数据进行化学计量技术以开发校准模型并且校准具有反映参考样品的沥青质污染水平的参数的实际值的光谱数据，通过 常规分析方法; （c）在基本上等于紫外 - 可见光的频率范围内获得浓度未知浓度的沥青质的船用柴油润滑油样品的光谱; 和（d）处理所获得的步骤（c）的光谱原始数据并将开发的校准模型应用于经处理的数据，以便确定反映船用柴油润滑油中存在的沥青质水平的参数。
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6.发明授权Method for determining residual fuel and insolubles contamination in used marine engine lubricants using UV-visible spectroscopy and chemometrics 有权使用紫外 - 可见光谱和化学计量学确定使用的船用发动机润滑剂中残留燃料和不溶物污染的方法公开(公告)号：US07241621B2
公开(公告)日：2007-07-10
申请号：US10274070
申请日：2002-10-18
CPC分类号： G01N21/88 , G01N21/33 , G01N33/2835 , G01N33/2888 , G01N2021/3155
摘要： A method for determining contamination in marine diesel lubricating oils. The method has been found to have particular utility in estimating residual fuel and insolubles contamination in marine diesel lubricating oils. The method includes the steps of: (a) obtaining spectral raw data over a frequency range substantially equivalent to that of ultraviolet-viable light for reference lubricating oil samples with known properties and concentrations of residual fuel and insolubles; (b) performing chemometric techniques to the spectral raw data obtained in step (a) to develop a calibration model and calibrate the spectral data with actual values for parameters reflecting the level of residual fuel and insolubles contamination of the reference samples, the actual values determined by means of conventional analytical methods; (c) obtaining spectra of samples of marine diesel lubricating oil of unknown concentration of residual fuel and insolubles over a frequency range substantially equivalent to that of ultraviolet-viable light; and (d) processing the obtained spectral raw data of step (c) and applying the developed calibration model to the processed data in order to determine the parameters reflecting the level of residual fuel contaminants and insolubles present in the marine diesel lubricating oil.
摘要翻译： 一种确定船用柴油润滑油污染的方法。 已经发现该方法在估计船用柴油润滑油中的残余燃料和不溶物污染方面具有特别的用途。 该方法包括以下步骤：（a）在具有已知性质和残留燃料和不溶物浓度的参考润滑油样品的基础上获得与紫外线可见光基本相同的频率范围上的光谱原始数据; （b）对步骤（a）中获得的光谱原始数据进行化学计量技术，以开发校准模型，并用反映残留燃料水平和参考样品不溶物污染的参数的实际值校准光谱数据，确定实际值 通过传统的分析方法; （c）在基本上等于紫外线可见光的频率范围内获得未知浓度的残余燃料和不溶物的船用柴油润滑油样品的光谱; 和（d）处理所获得的步骤（c）的光谱原始数据，并将开发的校准模型应用于处理的数据，以便确定反映船用柴油润滑油中存在的残余燃料污染物和不溶物的水平的参数。
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公开(公告)号：US5407830A
公开(公告)日：1995-04-18
申请号：US160565
申请日：1993-12-01
申请人： Lawrence J. Altman , Rafi Jalkian
发明人： Lawrence J. Altman , Rafi Jalkian
CPC分类号： B01J19/0006 , C07C2/62 , G01N21/3577 , C07C2527/1206 , Y10T436/12 , Y10T436/21
摘要： A method and system for controlling an HF alkylation system comprising a reactor, a settler, an HF acid regenerator and a source of fresh HF acid wherein a stream of olefins and a stream of isobutanes are contacted in the reactor in the presence an HF acid catalyst. At least the reactor feed is sampled, and the sample is passed to an analyzer using an attenuated total reflectance cell. Signals are generated which are representative of infrared spectra of the samples in a range providing information on the amount of at least one of HF, water, ASO and sulfolane. These signals are simultaneously determined and generated because all absorb in the same spectral region. This aspect provides for viewing these distortions of the main HF absorption band to quantify these three components. The infrared spectra signals are compared with stored signals to generate control signals; and at least one of HF, water and sulfolane fed to the reactor feed is adjusted in response to the control signal.
摘要翻译： 用于控制HF烷基化系统的方法和系统包括反应器，沉降器，HF酸再生器和新鲜HF酸源，其中烯烃流和异丁烷流在反应器中在HF酸催化剂存在下接触 。 至少对反应器进料进行取样，并使用衰减的全反射率单元将样品送至分析仪。 产生代表在提供关于HF，水，ASO和环丁砜中的至少一种的量的信息范围内的样品的红外光谱的信号。 这些信号同时被确定和产生，因为所有这些信号都在相同的光谱区域中吸收。 该方面提供了观察主HF吸收带的这些失真以量化这三个分量。 将红外光谱信号与存储的信号进行比较以产生控制信号; 并且响应于控制信号调节进料到反应器进料中的HF，水和环丁砜中的至少一种。
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公开(公告)号：US5583049A
公开(公告)日：1996-12-10
申请号：US423336
申请日：1995-04-17
申请人： Lawrence J. Altman , Rafi Jalkian
发明人： Lawrence J. Altman , Rafi Jalkian
CPC分类号： B01J19/0006 , C07C2/62 , G01N21/3577 , C07C2527/1206 , Y10T436/12 , Y10T436/21
摘要： A method and system for controlling an HF alkylation system comprising a reactor, a settler, an HF acid regenerator and a source of fresh HF acid wherein a stream of olefins and a stream of isobutanes are contacted in the reactor in the presence an HF acid catalyst. At least the reactor feed is sampled, and the sample is passed to an analyzer using an attenuated total reflectance cell. Signals are generated which are representative of infrared spectra of the samples in a range providing information on the amount of at least one of HF, water, ASO and sulfolane. These signals are simultaneously determined and generated because all absorb in the same spectral region. This aspect provides for viewing these distortions of the main HF absorption band to quantify these three components. The infrared spectra signals are compared with stored signals to generate control signals; and at least one of HF, water and sulfolane fed to the reactor feed is adjusted in response to the control signal.
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