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1.发明授权Self-assembled photosynthesis-inspired light harvesting material and solar cells containing the same 失效自组装光合作用的光收集材料和含有相同的光电池公开(公告)号：US07633007B2
公开(公告)日：2009-12-15
申请号：US11782288
申请日：2007-07-24
IPC分类号： H01L31/00
CPC分类号： B82Y10/00 , B82Y20/00 , H01L51/0077 , H01L51/0093 , H01L51/4226 , Y02E10/549
摘要： A solar cell is described that comprises: (a) a semiconductor charge separation material; (b) at least one electrode connected to the charge separation material; and (c) a light-harvesting film on the charge separation material, the light-harvesting film comprising non-covalently coupled, self-assembled units of porphyrinic macrocycles. The porphyrinic macrocycles preferably comprise: (i) an intramolecularly coordinated metal; (ii) a first coordinating substituent; and (iii) a second coordinating substituent opposite the first coordinating substituent. The porphyrinic macrocycles can be assembled by repeating intermolecular coordination complexes of the metal, the first coordinating substituent and the second coordinating substituent.
摘要翻译： 描述了一种太阳能电池，其包括：（a）半导体电荷分离材料; （b）连接到电荷分离材料的至少一个电极; 和（c）电荷分离材料上的光收集膜，所述光收集膜包含非共价偶联的自组装的卟啉大环化合物单元。 卟啉大环优选包括：（i）分子内配位的金属; （ii）第一配位取代基; 和（iii）与第一配位取代基相对的第二配位取代基。 可以通过重复金属，第一配位取代基和第二配位取代基的分子间配位络合物来组装卟啉大环。
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2.发明申请SELF-ASSEMBLED PHOTOSYNTHESIS-INSPIRED LIGHT HARVESTING MATERIAL AND SOLAR CELLS CONTAINING THE SAME 失效自组装光电子激发光收集材料和含有它的太阳能电池公开(公告)号：US20080029155A1
公开(公告)日：2008-02-07
申请号：US11782288
申请日：2007-07-24
IPC分类号： H01L31/0216
CPC分类号： B82Y10/00 , B82Y20/00 , H01L51/0077 , H01L51/0093 , H01L51/4226 , Y02E10/549
摘要： A solar cell is described that comprises: (a) a semiconductor charge separation material; (b) at least one electrode connected to the charge separation material; and (c) a light-harvesting film on the charge separation material, the light-harvesting film comprising non-covalently coupled, self-assembled units of porphyrinic macrocycles. The porphyrinic macrocycles preferably comprise: (i) an intramolecularly coordinated metal; (ii) a first coordinating substituent; and (iii) a second coordinating substituent opposite the first coordinating substituent. The porphyrinic macrocycles can be assembled by repeating intermolecular coordination complexes of the metal, the first coordinating substituent and the second coordinating substituent.
摘要翻译： 描述了一种太阳能电池，其包括：（a）半导体电荷分离材料; （b）连接到电荷分离材料的至少一个电极; 和（c）电荷分离材料上的光收集膜，所述光收集膜包含非共价偶联的自组装的卟啉大环化合物单元。 卟啉大环优选包含：（i）分子内配位的金属; （ii）第一配位取代基; 和（iii）与第一配位取代基相对的第二配位取代基。 可以通过重复金属，第一配位取代基和第二配位取代基的分子间配位络合物来组装卟啉大环。
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公开(公告)号：US08013149B2
公开(公告)日：2011-09-06
申请号：US12494711
申请日：2009-06-30
IPC分类号： C07B47/00 , C07D487/22
CPC分类号： C07D487/22 , C07D403/04
摘要： A method of making a porphyrin (I) is carried out by condensing (i) a bis(imino)dipyrromethane of Formula II: with (ii) a dipyrromethaneto produce a reaction product; then (b) optionally oxidizing said reaction product with an oxidizing agent; and then (c) optionally demetallating said reaction product to produce the porphyrin. Methods of making compounds of Formula II are also described.
摘要翻译： 制备卟啉（I）的方法是通过将（ⅰ）式Ⅱ的双（亚氨基）二吡咯烷与（ⅱ）二吡咯甲烷缩合制备反应产物而进行的; 然后（b）任选地用氧化剂氧化所述反应产物; 然后（c）任选地使所述反应产物脱金属以产生卟啉。 还描述了制备式II化合物的方法。
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公开(公告)号：US07951939B2
公开(公告)日：2011-05-31
申请号：US12361715
申请日：2009-01-29
IPC分类号： C07B47/00 , C07D487/22 , C07D207/00 , C07D295/00
CPC分类号： C07D403/04 , C07D487/22
摘要： A method of making a porphyrin is carried out by: (a) condensing (i) a 1,9-bis(N,N-)dialkylaminomethyl)dipyrromethane of Formula II: with (ii) a dipyrromethane to produce a reaction product; then (b) oxidizing the reaction product; and then (c) optionally demetallating said reaction product to produce the porphyrin. The reaction is particularly useful for making substituted porphyrins with a wide range of substituents at the A and/or B (the 5 and/or 15) positions.
摘要翻译： 通过以下方法进行卟啉的制备方法：（a）将（ⅰ）式Ⅱ的1,9-双（N，N-）二烷基氨基甲基）二吡咯烷与（ⅱ）二吡咯甲烷缩合生成反应产物; 然后（b）氧化反应产物; 然后（c）任选地使所述反应产物脱金属以产生卟啉。 该反应对于在A和/或B（5和/或15）位置制备具有宽范围取代基的取代卟啉是特别有用的。
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公开(公告)号：US08524892B2
公开(公告)日：2013-09-03
申请号：US13488658
申请日：2012-06-05
IPC分类号： C07B47/00
CPC分类号： C07D403/04 , C07D487/22
摘要： A method of making a porphyrin is carried out by: (a) condensing (i) a 1,9-bis(N,N-)dialkylaminomethyl)dipyrromethane of Formula II: with (ii) a dipyrromethane to produce a reaction product; then (b) oxidizing the reaction product; and then (c) optionally demetallating said reaction product to produce the porphyrin. The reaction is particularly useful for making substituted porphyrins with a wide range of substituents at the A and/or B (the 5 and/or 15) positions.
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公开(公告)号：US20120253052A1
公开(公告)日：2012-10-04
申请号：US13488658
申请日：2012-06-05
IPC分类号： C07D403/06
CPC分类号： C07D403/04 , C07D487/22
摘要： A method of making a porphyrin is carried out by: (a) condensing (i) a 1,9-bis(N,N-)dialkylaminomethyl)dipyrromethane of Formula II: with (ii) a dipyrromethane to produce a reaction product; then (b) oxidizing the reaction product; and then (c) optionally demetallating said reaction product to produce the porphyrin. The reaction is particularly useful for making substituted porphyrins with a wide range of substituents at the A and/or B (the 5 and/or 15) positions.
摘要翻译： 通过以下方法进行卟啉的制备方法：（a）将（ⅰ）式Ⅱ的1,9-双（N，N-）二烷基氨基甲基）二吡咯烷与（ⅱ）二吡咯甲烷缩合生成反应产物; 然后（b）氧化反应产物; 然后（c）任选地使所述反应产物脱金属以产生卟啉。 该反应对于在A和/或B（5和/或15）位置制备具有宽范围取代基的取代卟啉是特别有用的。
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公开(公告)号：US07501508B2
公开(公告)日：2009-03-10
申请号：US11192934
申请日：2005-07-29
IPC分类号： C07B47/00
CPC分类号： C07D403/04 , C07D487/22
摘要： A method of making a porphyrin is carried out by: (a) condensing (i) a 1,9-bis(N,N-)dialkylaminomethyl)dipyrromethane of Formula II: with (ii) a dipyrromethane to produce a reaction product; then (b) oxidizing the reaction product; and then (c) optionally demetallating said reaction product to produce the porphyrin. The reaction is particularly useful for making substituted porphyrins with a wide range of substituents at the A and/or B (the 5 and/or 15) positions.
摘要翻译： 通过以下方法进行卟啉的制备方法：（a）将（ⅰ）式Ⅱ的1,9-双（N，N-）二烷基氨基甲基）二吡咯烷与（ⅱ）二吡咯甲烷缩合生成反应产物; 然后（b）氧化反应产物; 然后（c）任选地使所述反应产物脱金属以产生卟啉。 该反应对于在A和/或B（5和/或15）位置制备具有宽范围取代基的取代卟啉是特别有用的。
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公开(公告)号：US08212023B2
公开(公告)日：2012-07-03
申请号：US13014914
申请日：2011-01-27
IPC分类号： C07D487/22 , C07B47/00
CPC分类号： C07D403/04 , C07D487/22
摘要： A method of making a porphyrin is carried out by: (a) condensing (i) a 1,9-bis(N,N-)dialkylaminomethyl)dipyrromethane of Formula II: with (ii) a dipyrromethane to produce a reaction product; then (b) oxidizing the reaction product; and then (c) optionally demetallating said reaction product to produce the porphyrin. The reaction is particularly useful for making substituted porphyrins with a wide range of substituents at the A and/or B (the 5 and/or 15) positions.
摘要翻译： 通过以下方法进行卟啉的制备方法：（a）将（ⅰ）式Ⅱ的1,9-双（N，N-）二烷基氨基甲基）二吡咯烷与（ⅱ）二吡咯甲烷缩合生成反应产物; 然后（b）氧化反应产物; 然后（c）任选地使所述反应产物脱金属以产生卟啉。 该反应对于在A和/或B（5和/或15）位置制备具有宽范围取代基的取代卟啉是特别有用的。
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公开(公告)号：US20090270638A1
公开(公告)日：2009-10-29
申请号：US12494711
申请日：2009-06-30
IPC分类号： C07D403/06
CPC分类号： C07D487/22 , C07D403/04
摘要： A method of making a porphyrin (I) is carried out by condensing (i) a bis(imino)dipyrromethane of Formula II: with (ii) a dipyrromethaneto produce a reaction product; then (b) optionally oxidizing said reaction product with an oxidizing agent; and then (c) optionally demetallating said reaction product to produce the porphyrin. Methods of making compounds of Formula II are also described.
摘要翻译： 制备卟啉（I）的方法是通过将（ⅰ）式Ⅱ的双（亚氨基）二吡咯烷与（ⅱ）二吡咯甲烷缩合制备反应产物而进行的; 然后（b）任选地用氧化剂氧化所述反应产物; 然后（c）任选地使所述反应产物脱金属以产生卟啉。 还描述了制备式II化合物的方法。
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公开(公告)号：US20110144325A1
公开(公告)日：2011-06-16
申请号：US13014914
申请日：2011-01-27
IPC分类号： C07D487/22
CPC分类号： C07D403/04 , C07D487/22
摘要： A method of making a porphyrin is carried out by: (a) condensing (i) a 1,9-bis(N,N-)dialkylaminomethyl)dipyrromethane of Formula II: with (ii) a dipyrromethane to produce a reaction product; then (b) oxidizing the reaction product; and then (c) optionally demetallating said reaction product to produce the porphyrin. The reaction is particularly useful for making substituted porphyrins with a wide range of substituents at the A and/or B (the 5 and/or 15) positions.
摘要翻译： 通过以下方法进行卟啉的制备方法：（a）将（ⅰ）式Ⅱ的1,9-双（N，N-）二烷基氨基甲基）二吡咯烷与（ⅱ）二吡咯甲烷缩合生成反应产物; 然后（b）氧化反应产物; 然后（c）任选地使所述反应产物脱金属以产生卟啉。 该反应对于在A和/或B（5和/或15）位置制备具有宽范围取代基的取代卟啉是特别有用的。
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