公开(公告)号：US07812154B2

公开(公告)日：2010-10-12

申请号：US10574797

申请日：2004-10-07

申请人： Jong Ho Kwon ,  Ki Suck Jung ,  Woo Ho Son ,  Seong Soo Park ,  Jin Phil Ko ,  Hyun Suk Jung

发明人： Jong Ho Kwon ,  Ki Suck Jung ,  Woo Ho Son ,  Seong Soo Park ,  Jin Phil Ko ,  Hyun Suk Jung

IPC分类号： C09B47/08 ,  C07D47/00

CPC分类号： C09B67/0026 ,  C07D487/22 ,  G03G5/051 ,  G03G5/0525 ,  G03G5/0696 ,  H05B6/74

摘要： Disclosed herein are a method and an apparatus for preparing oxytitanium phthalocyanine as a charge generating material. The method comprises the steps of homogeneously mixing an oxytitanium phthalocyanine crude with an organic solvent while microwave energy having a frequency of 0.1˜100 GHz and a power of 10˜3,000 W and ultrasonic wave energy having a frequency of 1˜1,000 kHz and a power of 10˜5,000 W are applied thereto, and reacting the mixture at 30˜100° C. for 0.5˜5 hours. The apparatus comprises: a magnetron 1 capable of generating a frequency of 0.1˜100 GHz and a power of 100˜3,000 W; a mode stirrer 3 for making the wavelength of microwaves uniform in a microwave container 2; a PID type temperature controller 9 for accurately measurement and controlling the temperature of reactants; a K-type thermocouple shielded from microwaves 4; a condenser 5; an agitator 6, the thermocouple 4, the condenser 5 and the agitator 6 being inserted into three openings formed at a top of the microwave container 2; an ultrasonic tip 7 inserted into an opening formed at a bottom of the microwave container 2; a Pyrex container 9 into which the reactants are introduced; and a solvent tank 10. According to the method and the apparatus, an oxytitanium phthalocyanine charge generating material having superior thermal stability and crystal stability can be prepared in an efficient manner.

摘要翻译： 本文公开了一种制备氧钛酞菁作为电荷产生材料的方法和装置。 该方法包括以下步骤：将氧钛酞菁粗品与有机溶剂均匀混合，同时具有频率为0.1〜100GHz，功率为10〜3000W的微波能量，频率为1〜1000kHz的超声波能量和功率 施加10〜5000W，并使混合物在30〜100℃下反应0.5〜5小时。 该装置包括：能够产生0.1〜100GHz的频率和100〜3000W的功率的磁控管1; 用于使微波波长在微波容器2中均匀的模式搅拌器3; 用于精确测量和控制反应物温度的PID型温度控制器9; 与微波屏蔽的K型热电偶4; 冷凝器5; 搅拌器6，热电偶4，冷凝器5和搅拌器6插入形成在微波容器2的顶部的三个开口中; 插入到形成在微波容器2的底部的开口中的超声波尖端7; 其中引入反应物的Pyrex容器9; 和溶剂罐10.根据该方法和装置，可以有效地制备具有优异的热稳定性和晶体稳定性的氧钛酞菁电荷产生材料。