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公开(公告)号：US08337725B2
公开(公告)日：2012-12-25
申请号：US12596475
申请日：2008-04-22
申请人： Julio Abusleme , Riccardo Pieri , Emma Barchiesi
发明人： Julio Abusleme , Riccardo Pieri , Emma Barchiesi
IPC分类号： H01B1/06 , C08L27/12 , C08F236/16
CPC分类号： C08F214/22 , B01D69/02 , B01D71/34 , B01D71/40 , B01D71/76 , B01D2325/36 , C08F214/225 , C08J5/2237 , C08J2327/16 , H01M4/621
摘要： The present invention pertains to a linear semi-crystalline copolymer [polymer (A)] comprising recurring units derived from vinylidene fluoride (VDF) monomer and at least one hydrophilic (meth)acrylic monomer (MA) of formula: wherein each of R1, R2, R3, equal or different from each other, is independently an hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group, said polymer (A) comprising from 0.05 to 10% by moles of recurring units derived from said hydrophilic (meth)acrylic monomer (MA) and being characterized by a fraction of randomly distributed units (MA) of at least 40%, having improved thermal stability, to a process for its manufacture, to a composition comprising the same, and to its use as binder in batteries or for the manufacture of hydrophilic membranes.
摘要翻译： 本发明涉及包含衍生自偏氟乙烯（VDF）单体和至少一种下式的亲水（甲基）丙烯酸单体（MA））的重复单元的线性半结晶共聚物[聚合物（A）]：其中R1，R2 相同或不同的R 3独立地为氢原子或C 1 -C 3烃基，ROH为氢或包含至少一个羟基的C 1 -C 5烃部分，所述聚合物（A）包含0.05 至10％（摩尔）衍生自所述亲水性（甲基）丙烯酸类单体（MA）的重复单元，其特征在于其制造方法中具有至少40％的随机分布单元（MA）的分数具有改善的热稳定性 涉及包含其的组合物，以及其作为电池中的粘合剂或用于制造亲水膜的用途。
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公开(公告)号：US20100133482A1
公开(公告)日：2010-06-03
申请号：US12596475
申请日：2008-04-22
申请人： Julio Abusleme , Riccardo Pieri , Emma Barchiesi
发明人： Julio Abusleme , Riccardo Pieri , Emma Barchiesi
IPC分类号： H01B1/24 , C08F214/22 , C08L27/16 , H01B1/20
CPC分类号： C08F214/22 , B01D69/02 , B01D71/34 , B01D71/40 , B01D71/76 , B01D2325/36 , C08F214/225 , C08J5/2237 , C08J2327/16 , H01M4/621
摘要： The present invention pertains to a linear semi-crystalline copolymer [polymer (A)] comprising recurring units derived from vinylidene fluoride (VDF) monomer and at least one hydrophilic (meth)acrylic monomer (MA) of formula (I) wherein each of R1, R2, R3, equal or different from each other, is independently an hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group, said polymer (A) comprising from 0.05 to 10% by moles of recurring units derived from said hydrophilic (meth)acrylic monomer (MA) and being characterized by a fraction of randomly distributed units (MA) of at least 40%, having improved thermal stability, to a process for its manufacture, to a composition comprising the same, and to its use as binder in batteries or for the manufacture of hydrophilic membranes.
摘要翻译： 本发明涉及包含衍生自偏氟乙烯（VDF）单体和至少一种式（I）的亲水（甲基）丙烯酸单体（MA））的重复单元的线性半结晶共聚物[聚合物（A）]，其中R1 R2，R3彼此相同或不同，独立地为氢原子或C1-C3烃基，ROH为氢或包含至少一个羟基的C 1 -C 5烃部分，所述聚合物（A）包含 衍生自所述亲水性（甲基）丙烯酸单体（MA）的0.05至10摩尔％的重复单元，其特征在于具有改善的热稳定性的至少40％的随机分布单位（MA）的分数至少为40％ 其制造，包含该组合物的组合物，以及其作为电池中的粘合剂或用于制造亲水膜的用途。
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公开(公告)号：US07033671B2
公开(公告)日：2006-04-25
申请号：US10347353
申请日：2003-01-21
CPC分类号： B32B27/08 , Y10T428/3154 , Y10T428/31725 , Y10T428/31739 , Y10T428/31743 , Y10T428/3175 , Y10T428/31935
摘要： Multilayers comprising at least one laminate formed in sequence by the following layers: A) one thermoprocessable fluoropolymer layer comprising units deriving from vinylidenfluoride (VDF); B) one polyamide layer blended with 0.01%–5% by weight of a diamine or one polyamide layer having at least 20 μeq/g of —NH2 groups, or one thermoprocessable polymer layer containing (—COO—) units and/or —CN groups; and C) one layer based on chlorinated polyvinylchloride (CPVC) containing from 58% to 75% by weight of chlorine.
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公开(公告)号：US07282267B2
公开(公告)日：2007-10-16
申请号：US11357030
申请日：2006-02-21
CPC分类号： B32B27/08 , Y10T428/3154 , Y10T428/31725 , Y10T428/31739 , Y10T428/31743 , Y10T428/3175 , Y10T428/31935
摘要： Multilayers comprising at least one laminate formed in sequence by the following layers: A) one thermoprocessable fluoropolymer layer comprising units deriving from vinylidenfluoride (VDF); B) one polyamide layer blended with 0.01%-5% by weight of a diamine or one polyamide layer having at least 20 μeq/g of —NH2 groups, or one thermoprocessable polymer layer containing (—COO—) units and/or —CN groups; and C) one layer based on chlorinated polyvinylchloride (CPVC) containing from 58% to 75% by weight of chlorine.
摘要翻译： 多层包含至少一层由以下层顺序形成的层压材料：A）一个热可加工含氟聚合物层，其包含衍生自偏氟乙烯（VDF）的单元; B）一种聚酰胺层，其与0.01％-5％重量的二胺或一种聚酰胺层共混，所述二胺或一个聚酰胺层具有至少20个mueq / g的-NH 2基团，或一个含有（-COO）的热可加工聚合物层 - ）单元和/或-CN基团; 和C）基于含有58重量％至75重量％氯的氯化聚氯乙烯（CPVC）的一层。
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公开(公告)号：US6107393A
公开(公告)日：2000-08-22
申请号：US44032
申请日：1998-03-19
申请人： Julio Abusleme , Claudia Manzoni
发明人： Julio Abusleme , Claudia Manzoni
IPC分类号： C08L27/12 , C08F14/24 , C08F14/26 , C08F210/02 , C08F214/18 , C08F214/24 , C08F214/26 , C08K5/00 , C08L23/08 , C08L27/18 , C08L33/06 , C08L33/18 , H01B3/42 , H01B3/44
CPC分类号： C08L23/08 , C08F210/02 , C08F214/18 , C08F214/186 , C08F214/245 , C08F214/265 , C08K5/00 , C08K5/0016 , C08L27/12 , C08L27/18 , H01B3/427 , H01B3/441 , H01B3/445 , H01B3/447 , H01B3/448 , C08F214/24 , C08L33/06 , C08L33/18
摘要： A copolymer comprising:(a) from 10 to 70% by moles of ethylene,(b) from 30 to 90% by moles of a fluorinated monomer selected from tetrafluoroethylene, chlorotrifluoroethylene, or their mixtures,(c) from 0.1 to 30% by moles, with respect to the total amount of monomers (a) and (b), of a hydrogenated monomer having the formula:CH.sub.2 =CH--(CH.sub.2).sub.n --R.sub.1 (I) where R.sub.1 =--OR.sub.2, --(O).sub.t CO(O).sub.p R.sub.2 with t and p as integers: t=0 or 1 and p=0 or 1 and R.sub.2 is a hydrogenated radical from 1 to 20 carbon atoms C.sub.1 -C.sub.20, branched and/or linear alkyl and cyclo-alkyl radical or R.sub.2 is H. The R.sub.2 radical may optionally contain: heteroatoms preferably Cl, O, N; one or more functional groups, preferably chosen among OH, COOH, epoxide, ester and ether; and double bonds. The n subscript is an integer number between 0 and 10.
摘要翻译： 一种共聚物，其包含：（a）10至70摩尔％的乙烯，（b）30至90摩尔％的选自四氟乙烯，三氟氯乙烯或其混合物的氟化单体，（c）0.1至30％ 相对于单体（a）和（b）的总量，具有式：CH 2 = CH-（CH 2）n -R 1（I）的氢化单体的摩尔数，其中R 1 = -OR 2， - （O）tCO （O）pR2，其中t和p为整数：t = 0或1，p = 0或1，R 2为1-20个碳原子的C 1 -C 20氢化基团，支链和/或直链烷基和环烷基或 R2是H.可以任选地含有：杂原子，优选Cl，O，N; 一个或多个官能团，优选选自OH，COOH，环氧化物，酯和醚; 和双重债券。 n下标是0到10之间的整数。
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公开(公告)号：US20090105420A1
公开(公告)日：2009-04-23
申请号：US12297888
申请日：2007-04-23
申请人： Julio Abusleme , Alessio Marrani
发明人： Julio Abusleme , Alessio Marrani
CPC分类号： C08L27/12 , C08L27/16 , C08L27/18 , C08L2205/02 , C08L2205/03 , C08L2666/04
摘要： This invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic hydrogen-containing fluoropolymer [polymer (A)]; and from 0.1 to 10% by weight of (A) of at least one per(halo)fluoropolymer chosen among tetrafluoroethylene (TFE) copolymers having a dynamic viscosity at a shear rate of 1 rad sec−1 of less than 10 Pa sec at a temperature of 280° C. [polymer (B)]. The addition of a TFE copolymer [polymer (B)] of low melt viscosity advantageously enables improvement of rheological behavior of thermoplastic hydrogen-containing fluoropolymer (A), making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency.Still objects of the invention are a process for manufacturing said thermoplastic fluoropolymer composition and the articles, such as shaped articles, films, cable sheathing, pipes, flexible pipes, hollow bodies comprising said thermoplastic fluoropolymer composition.
摘要翻译： 本发明涉及一种热塑性含氟聚合物组合物，其包含：至少一种含热塑性氢的含氟聚合物[聚合物（A）]; 和（A）至少一种选自四氟乙烯（TFE）共聚物中的至少一种每（卤代）含氟聚合物，其在剪切速率为1radsec-1时的动态粘度小于10Pa·sec， 温度280℃[聚合物（B）]。 加入低熔体粘度的TFE共聚物[聚合物（B）]有利于改善热塑性含氢含氟聚合物（A）的流变行为，使得在不太严格的条件下可能的加工，并产生具有优异表面面积和良好均匀性的最终部件 和一致性。 本发明的另一目的是制造所述热塑性含氟聚合物组合物和制品的方法，例如成型制品，薄膜，电缆护套，管，柔性管，包含所述热塑性含氟聚合物组合物的中空体。
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公开(公告)号：US06656991B2
公开(公告)日：2003-12-02
申请号：US09931010
申请日：2001-08-17
申请人： Anna Staccione , Julio Abusleme
发明人： Anna Staccione , Julio Abusleme
IPC分类号： C08K318
CPC分类号： C08K5/14 , C08L27/22 , C08L33/04 , C08L27/12 , C08L2666/04
摘要： Compounds comprising a peroxide and a curable blend by peroxidic way, consisting essentially of hydrocarbon elastomers containing at least an acrylic monomer, and of unsaturated fluorinated elastomers obtained by dehydro halogenation of fluorinated VDF-based elastomers, said fluorinated elastomers having in the polymer chain at least 5% by moles of hydrogenated C1 groups of the type —CH2— and/or —CH3, the amount of unsaturated fluorinated elastomer in the elastomeric blend being comprised from 1 to 99% by weight.
摘要翻译： 包含过氧化物和通过过氧化方式的可固化共混物的化合物，基本上由至少含有丙烯酸单体的烃弹性体和通过氟化VDF基弹性体的脱氢卤化获得的不饱和氟化弹性体组成，所述氟化弹性体至少在聚合物链中具有 5％（摩尔）类型为-CH 2 - 和/或-CH 3的氢化C1基团，弹性体共混物中不饱和氟化弹性体的量为1至99重量％。
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公开(公告)号：US06576100B2
公开(公告)日：2003-06-10
申请号：US09885921
申请日：2001-06-22
IPC分类号： C25B1300
CPC分类号： C08J5/225 , B01D71/32 , B01D71/82 , C08F214/262 , C08J2327/16 , H01M8/1023 , H01M8/1039 , H01M8/1046 , H01M8/1072 , Y02P70/56
摘要： Crosslinked sulphonic fluorinated ionomers having an equivalent weight 380-1300 g/eq, comprising: (A) monomeric units deriving from one or more fluorinated monomers containing at least one ethylene unsaturation; (B) fluorinated monomeric units containing sulphonyl groups —SO2F in an amount such as to give the above indicated equivalent weight.
摘要翻译： 具有当量重量为380-1300g / eq的交联磺化氟化离聚物，其包含：（A）衍生自一种或多种含至少一种乙烯不饱和度的氟化单体的单体单元;（B）含有磺酰基-SO 2 F的氟化单体单元， 例如给出上述等效重量。
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公开(公告)号：US20060229421A1
公开(公告)日：2006-10-12
申请号：US11384823
申请日：2006-03-21
IPC分类号： C08F214/18
CPC分类号： B01D71/32 , B01D67/0009 , B01D67/0018 , B01D67/003 , B01D67/0093 , B01D71/36 , B01D71/38 , B01D71/40 , B01D2323/20 , B01D2325/24 , B01D2325/30 , B01D2325/36 , C08F214/24 , C08F214/26
摘要： Powders or hydrophilic manufactured articles of E/CTFE and/or E/TFE thermoprocessable polymers, or of CTFE copolymers, wherein, on the surface of the powder or the manufactured article, one or more of the following hydrophilic units are present: —C(COOH)H—CH2—; —C(COOM)H—CH2—; —C(OCOOH)H—CH2—; —C(OCOOM)H—CH2—; with M=alkaline ion.
摘要翻译： E / CTFE和/或E / TFE热可加工聚合物或CTFE共聚物的粉末或亲水制品，其中在粉末或制品的表面上存在一种或多种下列亲水单元：-C（ COOH）H-CH 2 - ; -C（COOM）H-CH 2 - ; -C（OCOOH）H-CH 2 - ; -C（OCOOM）H-CH 2 - ; M =碱性离子。
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公开(公告)号：US20060141263A1
公开(公告)日：2006-06-29
申请号：US11357030
申请日：2006-02-21
CPC分类号： B32B27/08 , Y10T428/3154 , Y10T428/31725 , Y10T428/31739 , Y10T428/31743 , Y10T428/3175 , Y10T428/31935
摘要： Multilayers comprising at least one laminate formed in sequence by the following layers: A) one thermoprocessable fluoropolymer layer comprising units deriving from vinylidenfluoride (VDF); B) one polyamide layer blended with 0.01%-5% by weight of a diamine or one polyamide layer having at least 20 μeq/g of —NH2 groups, or one thermoprocessable polymer layer containing (—COO—) units and/or —CN groups; and C) one layer based on chlorinated polyvinylchloride (CPVC) containing from 58% to 75% by weight of chlorine.
摘要翻译： 多层包含至少一层由以下层顺序形成的层压材料：A）一个热可加工含氟聚合物层，其包含衍生自偏氟乙烯（VDF）的单元; B）一种聚酰胺层，其与0.01％-5％重量的二胺或一种聚酰胺层共混，所述二胺或一个聚酰胺层具有至少20个mueq / g的-NH 2基团，或一个含有（-COO）的热可加工聚合物层 - ）单元和/或-CN基团; 和C）基于含有58重量％至75重量％氯的氯化聚氯乙烯（CPVC）的一层。
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