Process for producing electrolyte material for polymer electrolyte fuel cells, and membrane-electrode assembly for polymer electrolyte fuel cells
    1.
    发明申请
    Process for producing electrolyte material for polymer electrolyte fuel cells, and membrane-electrode assembly for polymer electrolyte fuel cells 有权
    用于生产用于聚合物电解质燃料电池的电解质材料的方法和用于聚合物电解质燃料电池的膜 - 电极组件

    公开(公告)号:US20060287497A1

    公开(公告)日:2006-12-21

    申请号:US11183748

    申请日:2005-07-19

    IPC分类号: C08J5/20 C08G75/00 C08G73/24

    摘要: A membrane-electrode assembly for polymer electrolyte fuel cells which is excellent in water repellency and gas diffusivity and which exhibits a high output power density, can be obtained by using, as an electrolyte material for polymer electrolyte fuel cells, a fluoropolymer obtained by contacting a fluoropolymer which is excellent in gas diffusivity and which has alicyclic structures in its main chain and further has sulfonic acid groups, with fluorine gas for fluorination to increase water repellency and stabilize the molecule ends. The above fluoropolymer is preferably made of a copolymer comprising repeating units based on the following monomer A and repeating units based on the following monomer B (wherein Y is a fluorine atom or a trifluoromethyl group, m is an integer of from 0 to 3, p is 0 or 1, and n is an integer of from 1 to 12): Monomer A: A perfluoromonomer which gives a polymer having repeating units containing cyclic structures in its main chain by radical polymerization Monomer B: CF2═CF—(OCF2CFY)m—Op—(CF2)n—SO3H

    摘要翻译: 作为聚合物电解质型燃料电池的电解质材料,可以通过使用通过使聚合物电解质燃料电池接触而获得的含氟聚合物,获得具有优异的防水性和气体扩散性并且显示出高功率密度的聚合物电解质燃料电池用膜电极组件 含氟聚合物,其气体扩散性优异,并且在其主链中具有脂环结构并且还具有磺酸基,氟气用于氟化以增加拒水性并稳定分子末端。 上述含氟聚合物优选由包含以下单体A的重复单元和基于以下单体B的重复单元(其中Y为氟原子或三氟甲基,m为0〜3的整数,p 是0或1,n是1至12的整数):单体A:通过自由基聚合在其主链中产生具有含有环状结构的重复单元的聚合物的全氟单体单体B:CF 2 -CF-(OCF 2 C 1 -CY)m -O - - - (CF 2 N)n 3 H 3

    PROCESS FOR PRODUCING ELECTROLYTE MATERIAL FOR POLYMER ELECTROLYTE FUEL CELLS, AND MEMBRANE-ELECTRODE ASSEMBLY FOR POLYMER ELECTROLYTE FUEL CELLS
    2.
    发明申请
    PROCESS FOR PRODUCING ELECTROLYTE MATERIAL FOR POLYMER ELECTROLYTE FUEL CELLS, AND MEMBRANE-ELECTRODE ASSEMBLY FOR POLYMER ELECTROLYTE FUEL CELLS 失效
    用于生产聚合物电解质燃料电池的电解质材料的方法和用于聚合物电解质燃料电池的膜电极组件

    公开(公告)号:US20090215938A1

    公开(公告)日:2009-08-27

    申请号:US12430961

    申请日:2009-04-28

    IPC分类号: C08K5/05

    摘要: A membrane-electrode assembly for polymer electrolyte fuel cells which is excellent in water repellency and gas diffusivity and which exhibits a high output power density, can be obtained by using, as an electrolyte material for polymer electrolyte fuel cells, a fluoropolymer obtained by contacting a fluoropolymer which is excellent in gas diffusivity and which has alicyclic structures in its main chain and further has sulfonic acid groups, with fluorine gas for fluorination to increase water repellency and stabilize the molecule ends. The above fluoropolymer is preferably made of a copolymer comprising repeating units based on the following monomer A and repeating units based on the following monomer B (wherein Y is a fluorine atom or a trifluoromethyl group, m is an integer of from 0 to 3, p is 0 or 1, and n is an integer of from 1 to 12): Monomer A: A perfluoromonomer which gives a polymer having repeating units containing cyclic structures in its main chain by radical polymerization Monomer B: CF2═CF—(OCF2CFY)m-0p-(CF2)n—SO3H

    摘要翻译: 作为聚合物电解质型燃料电池的电解质材料,可以通过使用通过使聚合物电解质燃料电池接触而获得的含氟聚合物,获得具有优异的防水性和气体扩散性并且显示出高功率密度的聚合物电解质燃料电池用膜电极组件 含氟聚合物,其气体扩散性优异,并且在其主链中具有脂环结构并且还具有磺酸基,氟气用于氟化以增加拒水性并稳定分子末端。 上述含氟聚合物优选由包含以下单体A的重复单元和基于以下单体B的重复单元(其中Y为氟原子或三氟甲基,m为0〜3的整数,p 是0或1,n是1至12的整数):单体A:通过自由基聚合在其主链中产生具有含有环状结构的重复单元的聚合物的全氟单体单体B:CF 2 -CF-(OCF 2 CF 3)m -Op-(CF2)n-SO3H

    Process for producing electrolyte material for polymer electrolyte fuel cells, and membrane-electrode assembly for polymer electrolyte fuel cells
    3.
    发明授权
    Process for producing electrolyte material for polymer electrolyte fuel cells, and membrane-electrode assembly for polymer electrolyte fuel cells 失效
    用于生产用于聚合物电解质燃料电池的电解质材料的方法和用于聚合物电解质燃料电池的膜 - 电极组件

    公开(公告)号:US08198394B2

    公开(公告)日:2012-06-12

    申请号:US12430961

    申请日:2009-04-28

    IPC分类号: C08J5/20

    摘要: A membrane-electrode assembly for polymer electrolyte fuel cells which is excellent in water repellency and gas diffusivity and which exhibits a high output power density, can be obtained by using, as an electrolyte material for polymer electrolyte fuel cells, a fluoropolymer obtained by contacting a fluoropolymer which is excellent in gas diffusivity and which has alicyclic structures in its main chain and further has sulfonic acid groups, with fluorine gas for fluorination to increase water repellency and stabilize the molecule ends. The above fluoropolymer is preferably made of a copolymer comprising repeating units based on the following monomer A and repeating units based on the following monomer B (wherein Y is a fluorine atom or a trifluoromethyl group, m is an integer of from 0 to 3, p is 0 or 1, and n is an integer of from 1 to 12): Monomer A: A perfluoromonomer which gives a polymer having repeating units containing cyclic structures in its main chain by radical polymerization Monomer B: CF2═CF—(OCF2CFY)m-0p-(CF2)n—SO3H.

    摘要翻译: 作为聚合物电解质型燃料电池的电解质材料,可以通过使用通过使聚合物电解质燃料电池接触而获得的含氟聚合物,获得具有优异的防水性和气体扩散性并且显示出高功率密度的聚合物电解质燃料电池用膜电极组件 含氟聚合物,其气体扩散性优异,并且在其主链中具有脂环结构并且还具有磺酸基,氟气用于氟化以增加拒水性并稳定分子末端。 上述含氟聚合物优选由包含以下单体A的重复单元和基于以下单体B的重复单元(其中Y为氟原子或三氟甲基,m为0〜3的整数,p 是0或1,n为1至12的整数):单体A:通过自由基聚合在其主链中产生含有环状结构的重复单元的聚合物的全氟单体单体B:CF 2 = CF-(OCF 2 CF 3)m -Op-(CF2)n-SO3H。

    Process for producing electrolyte material for polymer electrolyte fuel cells, and membrane-electrode assembly for polymer electrolyte fuel cells
    4.
    发明授权
    Process for producing electrolyte material for polymer electrolyte fuel cells, and membrane-electrode assembly for polymer electrolyte fuel cells 有权
    用于生产用于聚合物电解质燃料电池的电解质材料的方法和用于聚合物电解质燃料电池的膜 - 电极组件

    公开(公告)号:US07557178B2

    公开(公告)日:2009-07-07

    申请号:US11183748

    申请日:2005-07-19

    IPC分类号: C08J5/20

    摘要: A membrane-electrode assembly for polymer electrolyte fuel cells which is excellent in water repellency and gas diffusivity and which exhibits a high output power density, can be obtained by using, as an electrolyte material for polymer electrolyte fuel cells, a fluoropolymer obtained by contacting a fluoropolymer which is excellent in gas diffusivity and which has alicyclic structures in its main chain and further has sulfonic acid groups, with fluorine gas for fluorination to increase water repellency and stabilize the molecule ends. The above fluoropolymer is preferably made of a copolymer comprising repeating units based on the following monomer A and repeating units based on the following monomer B (wherein Y is a fluorine atom or a trifluoromethyl group, m is an integer of from 0 to 3, p is 0 or 1, and n is an integer of from 1 to 12): Monomer A: A perfluoromonomer which gives a polymer having repeating units containing cyclic structures in its main chain by radical polymerization Monomer B: CF2═CF—(OCF2CFY)m—Op—(CF2)n—SO3H.

    摘要翻译: 作为聚合物电解质型燃料电池的电解质材料,可以通过使用通过使聚合物电解质燃料电池接触而获得的含氟聚合物,获得具有优异的防水性和气体扩散性并且显示出高功率密度的聚合物电解质燃料电池用膜电极组件 含氟聚合物,其气体扩散性优异,并且在其主链中具有脂环结构并且还具有磺酸基,氟气用于氟化以增加拒水性并稳定分子末端。 上述含氟聚合物优选由包含以下单体A的重复单元和基于以下单体B的重复单元(其中Y为氟原子或三氟甲基,m为0〜3的整数,p 是0或1,n是1至12的整数):单体A:通过自由基聚合在其主链中产生具有含有环状结构的重复单元的聚合物的全氟单体单体B:CF 2 -CF-(OCF 2 CF 3)m -Op-(CF2)n-SO3H。

    Fuel cell system
    7.
    发明授权
    Fuel cell system 有权
    燃料电池系统

    公开(公告)号:US08182951B2

    公开(公告)日:2012-05-22

    申请号:US12828710

    申请日:2010-07-01

    IPC分类号: H01M8/04 H01M8/10

    摘要: To provide a fuel cell system provided with a polymer electrolyte fuel cell which is excellent in the power generation characteristics under high temperature and low or no humidity conditions.A fuel cell system 20 comprising a polymer electrolyte fuel cell 22 having a membrane/electrode assembly 10 having a catalyst layer containing a polymer (H) which has repeating units based on a perfluoromonomer having an alicyclic structure and has ion exchange groups, a temperature controlling means for controlling temperature of the polymer electrolyte fuel cell 22, a temperature sensor 38 for detecting temperature of the polymer electrolyte fuel cell 22, and a controlling device 40 for controlling the temperature controlling means based on temperature information from the temperature sensor 38 so that the maximum temperature of the polymer electrolyte fuel cell 22 becomes within the range of from 90 to 140° C.

    摘要翻译: 提供一种设置有在高温低湿条件下发电特性优异的聚合物电解质型燃料电池的燃料电池系统。 一种燃料电池系统20,包括具有膜/电极组件10的聚合物电解质燃料电池22,所述膜/电极组件10具有含有聚合物(H)的催化剂层,所述聚合物(H)具有基于具有脂环结构的全氟单体的重复单元并具有离子交换基团,温度控制 用于控制聚合物电解质燃料电池22的温度的装置,用于检测聚合物电解质燃料电池22的温度的温度传感器38,以及用于基于来自温度传感器38的温度信息来控制温度控制装置的控制装置40, 聚合物电解质燃料电池22的最高温度在90〜140℃的范围内。

    FLUOROSULFONYL GROUP-CONTAINING COMPOUND, METHOD FOR ITS PRODUCTION AND POLYMER THEREOF
    8.
    发明申请
    FLUOROSULFONYL GROUP-CONTAINING COMPOUND, METHOD FOR ITS PRODUCTION AND POLYMER THEREOF 有权
    含氟聚合物的含氟化合物,其生产方法及其聚合物

    公开(公告)号:US20090187044A1

    公开(公告)日:2009-07-23

    申请号:US12410524

    申请日:2009-03-25

    IPC分类号: C07C309/82

    摘要: A compound containing two fluorosulfonyl groups which are groups convertible to sulfonic acid groups, an intermediate therefor, and methods for their production with high productivity, are provided. Also provided are a fluorosulfonyl group-containing polymer obtained by polymerizing such a compound, and a sulfonic acid group-containing polymer obtained from such a polymer.A method for producing a compound of the following formula (m0), such a compound, a fluorosulfonyl group-containing polymer obtained by polymerizing such a compound, and a sulfonic acid group-containing polymer obtained from such a polymer, provided that RF01 is a single bond or a C1-6 bivalent perfluoro organic group, RF02 is a C1-6 bivalent perfluoro organic group, and n is 0 or 1:

    摘要翻译: 提供了含有可转化成磺酸基团的两个氟磺酰基的化合物,其中间体,以及高生产率的生产方法。 还提供了通过聚合这种化合物获得的含氟磺酰基的聚合物和由这种聚合物获得的含磺酸基的聚合物。 制备下式(m0)化合物的方法,该化合物,通过聚合该化合物得到的含氟磺酰基的聚合物和由这种聚合物得到的含磺酸基的聚合物,条件是RF01为 单键或C1-6二价全氟有机基团,RF02为C1-6二价全氟有机基团,n为0或1:

    Electrolyte material, liquid composition and membrane/electrode assembly for polymer electrolyte fuel cell
    10.
    发明授权
    Electrolyte material, liquid composition and membrane/electrode assembly for polymer electrolyte fuel cell 有权
    用于聚合物电解质燃料电池的电解质材料,液体组合物和膜/电极组件

    公开(公告)号:US09508463B2

    公开(公告)日:2016-11-29

    申请号:US12790391

    申请日:2010-05-28

    IPC分类号: H01B1/12 H01M8/10 C08F216/14

    摘要: It is to provide an electrolyte material with which an increase in the water content can be suppressed even when the ion exchange capacity of a polymer having repeating units based on a monomer having a dioxolane ring is high; and a membrane/electrode assembly excellent in the power generation characteristics under low or no humidity conditions and under high humidity conditions.It is to use an electrolyte material, which comprises a polymer (H) having ion exchange groups converted from precursor groups in a polymer (F), and having an ion exchange capacity of at least 1.35 meq/g dry resin, the polymer (F) having repeating units (A) based on a perfluoromonomer having a precursor group of an ion exchange group and a dioxolane ring and repeating units (B) based on a perfluoromonomer having no precursor group and having a dioxolane ring, and having a TQ of at least 200° C., which is a temperature at which the melt volume rate becomes 100 mm3/sec when the polymer (F) is subjected to melt-extrusion under an extrusion pressure condition of 2.94 MPa from a nozzle having a length of 1 mm and an inner diameter of 1 mm.

    摘要翻译: 使用电解质材料,其包含在聚合物(F)中由前体基团转化的离子交换基团的聚合物(H),并且具有至少1.35meq / g干树脂的离子交换容量,所述聚合物(F )具有基于具有离子交换基团的前体基团和二氧戊环的全氟单体的重复单元(A)和基于不具有前体基团并具有二氧戊环的全氟单体的重复单元(B),并且具有TQ为 至少200℃,当聚合物(F)在长度为1mm的喷嘴的挤出压力条件为2.94MPa下进行熔融挤出时,其熔体体积率为100mm 3 / sec的温度 内径为1mm。