Unsaturated urethanized polyester resins, a process for their production
and their use for the production of coatings
    1.
    发明授权
    Unsaturated urethanized polyester resins, a process for their production and their use for the production of coatings 失效
    不饱和聚酯聚酯树脂,其生产工艺及其用于生产涂料的工艺

    公开(公告)号:US5142015A

    公开(公告)日:1992-08-25

    申请号:US600557

    申请日:1990-10-19

    摘要: The present invention relates to a process for the production of olefinically unsaturated polyester resins containing at least 0.025 moles of urethane groups per 100 g of resin by reactingA) olefinically unsaturated polyester resins which contain alcoholic hydroxyl groups, have a molecular weight (M.sub.n) of 800 to 10,000, an acid vlaue of 0 to 50 and a hydroxyl number of 30 to 120, and are based on the reaction product ofI) a dicarboxylic acid component containing a) 90 to 100 mole percent of maleic acid, maleic anhydride and/or fumaric acid and b) 0 to 10 mole percent of another carboxylic acid andII) 1.1 to 1.5 moles, based on one mole of the dicarboxylic acid component, of a polyol component containing c) 0.1 to 0.5 moles of at least one saturated cycloaliphatic diol having 6 to 18 carbon atoms, d) 0.5 to 0.9 moles of at least one saturated aliphatic diol having 2 to 6 carbon atoms and e) 0.1 to 0.5 moles of at least one .beta.,.gamma.-ethylenically unsaturated ether alcohol having 5 to 14 carbon atoms, withB) an organic polyisocyanate baased on a member selected from the group of biuret-, isocyanurate-, uretdione- and urethane-modified polyisocyanates having 8 to 30% by weight of (cyclo)-aliphatically bound isocyanate groups in an amount sufficient to provide a ratio of isocyanate groups of component B) to hydroxyl groups of component A) of 0.1:1 to 1:1.The present invention also relates to the olefinically unsaturated polyester resins containing urethane groups obtained by this process and to coatings prepared from coating compositions based on these olefinically unsaturated polyester resins and cured by free radical polymerization.

    摘要翻译: 本发明涉及一种通过使A)含有醇羟基的烯属不饱和聚酯树脂,其分子量(Mn)为 800至10,000,酸值为0至50,羟值为30至120,并且基于I)的反应产物,含有a)90至100摩尔%的马来酸,马来酸酐和/ 或富马酸,和b)0至10摩尔%的另一种羧酸和II)基于1摩尔二羧酸组分的1.1至1.5摩尔多元醇组分,其含有c)0.1至0.5摩尔的至少一种饱和脂环族 具有6至18个碳原子的二醇,d)0.5至0.9摩尔的至少一种具有2-6个碳原子的饱和脂肪族二醇和e)0.1-0.5摩尔至少一种具有5个碳原子的β,γ-烯属不饱和醚醇 至少14个碳原子,其中B)有机多异氰酸酯位于选自缩二脲,异氰脲酸酯,脲二酮和氨基甲酸酯改性的多异氰酸酯基团中的组分,其具有8至30重量%的(环) - 阴离子结合的异氰酸酯基团 足以提供组分B)的异氰酸酯基团与组分A)的羟基的比例为0.1:1至1:1的量。 本发明还涉及通过该方法获得的含有氨基甲酸酯基团的烯属不饱和聚酯树脂和由基于这些烯属不饱和聚酯树脂的涂料组合物制备并通过自由基聚合固化的涂料。

    Emulsifiable radiation-curable acryloyl-containing polyesters, a process
for their preparation and their use
    3.
    发明授权
    Emulsifiable radiation-curable acryloyl-containing polyesters, a process for their preparation and their use 失效
    可乳化的可辐射固化的含丙烯酰基的聚酯,其制备方法及其用途

    公开(公告)号:US4585828A

    公开(公告)日:1986-04-29

    申请号:US665566

    申请日:1984-10-29

    摘要: The invention relates to acryloyl-containing polyesters having acid numbers AN of 1-50 mg of KOH/g of substance and having been polymerized from cocondensed units of(A) 1.0 mole of at least one dicarboxylic anhydride,(B) 0.02-0.08 mole of at least one saturated dihydric polyether alcohol having a molecular weight Mn of about 1,000 to 2,000,(C) 0.48-0.42 mole of at least one dihydric saturated alcohol,(D) 1.0 mole of at least one trihydric saturated oxyalkylated alcohol with a degree of oxyalkylation of 2-6, up to 50 mole-% of said oxalkylated alcohol may be replaced by a trihydric, saturated, non-oxalkylated alcohol, and(E) 1.0-2.0 moles of acrylic acid, to a process for their preparation, and to their use as radiation-curable binders in aqueous emulsion preferably for coating wood and woodlike materials, for which the presence of customary external surface-active agents and reactive radiation-curable diluents is not necessary.

    摘要翻译: 本发明涉及具有1-50mg KOH / g物质的酸值AN的丙烯酰基聚酯,并且由(A)1.0摩尔的至少一种二羧酸酐的共缩合单元聚合,(B)0.02-0.08摩尔 的至少一种饱和二元聚醚醇,其分子量&Upbar&Mn为约1,000-2,000,(C)0.48-0.42摩尔至少一种二羟基饱和醇,(D)1.0摩尔至少一种三羟基饱和烷氧基化醇与 其氧化烷基化程度为2-6,高达50%(摩尔)的所述烷氧基化醇可以被三元饱和的非烷基烷基化醇和(E)1.0-2.0摩尔的丙烯酸代替。 ,以及它们作为水性乳液中的可辐射固化粘合剂的用途,优选用于涂覆木材和木质材料,其中不需要常规的外部表面活性剂和反应性可辐射固化的稀释剂的存在。

    Unsaturated polyester resins, a process for their preparation and
compositions containing these polyester resins
    4.
    发明授权
    Unsaturated polyester resins, a process for their preparation and compositions containing these polyester resins 失效
    不饱和聚酯树脂,其制备方法和含有这些聚酯树脂的组合物

    公开(公告)号:US4921883A

    公开(公告)日:1990-05-01

    申请号:US169967

    申请日:1988-03-18

    摘要: Unsaturated polyester resins having an acid number of from 0 to 50 and a hydroxyl number of from 10 to 150 which are composed of 0.6 to 0.8 moles of groups derived from maleic and/or fumaric acid, 0.2 to 0.4 moles of groups derived from norbornene dicarboxylic acid, 0.6 to 0.8 moles of groups derived from ethylene and/or propylene glycol, 0.2 to 0.4 moles of groups derived from diethylene glycol, 0.1 to 0.2 moles of groups derived from benzylalcohol and/or benzoic acid and 0 to 0.2 moles of groups derived from other alcohols, a process for their manufacture by a solvent-free or azeotropic esterification of said monomers and compositions which can be cured under influence of UV radiation, containing from 40 to 80 parts by weight of said polyester resins, from 20 to 60 parts by weight of styrene from 0.5 to 5 parts by weight of at least one photoinitiator and optionally known auxiliary agents and additives.

    摘要翻译: 由0.6至0.8摩尔衍生自马来酸和/或富马酸的基团组成的酸值为0至50且羟基数为10至150的不饱和聚酯树脂,衍生自降冰片烯二羧酸的基团为0.2至0.4摩尔 酸,0.6至0.8摩尔衍生自乙烯和/或丙二醇的基团,0.2至0.4摩尔衍生自二甘醇的基团,0.1至0.2摩尔衍生自苄醇和/或苯甲酸的基团和0至0.2摩尔衍生的基团 来自其它醇的方法,其通过所述单体的无溶剂或共沸酯化制备的方法,所述单体和组合物可以在UV辐射的影响下固化,所述组合物含有40至80重量份的所述聚酯树脂,20至60重量份 的苯乙烯0.5至5重量份的至少一种光引发剂和任选地已知的助剂和添加剂。

    Coating compositions curable by radiation and their use for preparing
coated substrates
    6.
    发明授权
    Coating compositions curable by radiation and their use for preparing coated substrates 失效
    通过辐射固化的涂料组合物及其用于制备涂布的基材

    公开(公告)号:US5744248A

    公开(公告)日:1998-04-28

    申请号:US789047

    申请日:1997-01-28

    摘要: The present invention relates to coating compositions, which are curable by radiation and contain I) 0 to 95 parts by weight of at least one binder curable by radiation and containing maleate, fumarate and/or acryloyl groups other than those of component II), II) 5 to 100 parts by weight of a mixture of A) 20 to 80 parts by weight of at least one polyester resin prepared from fatty acids, provided that at least 20 wt. % of component A) is a fatty acid having a number average molecular weight of 112 to 400 and B) 20 to 80 parts by weight of compounds containing (meth)acryloyl groups, having a viscosity at 23.degree. C. of 10 to 1,000 mPa.s and having a number average molecular weight of 170 to 1,000, wherein the sum of the parts by weight of components I) and II) adds up to 100, based on the weight of components I) and II), and the sum of the parts by weight of components A) and B) adds up to 100, based on the weight of components A) and B).

    摘要翻译: 本发明涉及涂料组合物,其可通过辐射固化并含有I)0至95重量份的至少一种可通过辐射固化并可含有除组分II),II之外的马来酸酯,富马酸酯和/或丙烯酰基的粘合剂 )5至100重量份的A)20至80重量份的由脂肪酸制备的至少一种聚酯树脂的混合物,条件是至少20重量份 组分A)的%是数均分子量为112〜400的脂肪酸,B)20〜80重量份含有(甲基)丙烯酰基的化合物,在23℃下的粘度为10〜1000mPa 并且其数均分子量为170至1,000,其中基于组分I)和II)的重量,组分I)和II)的重量份的总和相加至100,并且 组分A)和B)的重量份数基于组分A)和B)的重量加起来高达100。

    Radically curable coating compositions and their use for coating wood
substrates
    7.
    发明授权
    Radically curable coating compositions and their use for coating wood substrates 失效
    可自由基固化的涂料组合物及其用于涂覆木质基材的用途

    公开(公告)号:US5470897A

    公开(公告)日:1995-11-28

    申请号:US234753

    申请日:1994-04-28

    摘要: A radically curable coating composition containing) 50 to 95 parts by weight of an unsaturated polyester component having a viscosity at 23.degree. C. of 1,000 to 15,000 mPa.s, B) 5 to 50 parts by weight of compounds containing (meth)acryloyl groups and/or vinyl ether groups, C) 0.01 to 0.3 wt. %, based on the total weight, of waxes and/or paraffins having a melting point of 35+ to 100.degree. C. and D) 0 to 10 wt. %, based on the total weight, of at least one plasticizer or carbamic acid resin, and the use of the coating composition for coating substrates, in particular wood substrates.

    摘要翻译: 一种可自由基固化的涂料组合物,其含有50至95重量份的在23℃下的粘度为1,000至15,000mPa.s的不饱和聚酯组分,B)5至50重量份含(甲基)丙烯酰基的化合物 和/或乙烯基醚基,C)0.01〜0.3重量% %,基于总重量,熔点为35℃至100℃的蜡和/或链烷烃,和D)0至10重量%。 基于总重量,至少一种增塑剂或氨基甲酸树脂,以及用于涂覆基材,特别是木质基材的涂料组合物的用途。

    Plug-in connector for printed circuits
    8.
    发明授权
    Plug-in connector for printed circuits 失效
    用于印刷电路的插入式连接器

    公开(公告)号:US08043110B2

    公开(公告)日:2011-10-25

    申请号:US12760057

    申请日:2010-04-14

    IPC分类号: H01R4/24

    摘要: A plug connector for printed circuit boards includes a number of contact elements positioned in a housing. The contact elements each have two connection ends and an intermediate contact positioned between the two ends, where one connection end is in the form of an insulation displacement contact for connecting wires. The insulation displacement contacts are supported on the housing, so that the contact elements are held captively in the housing when connection forces act on the insulation displacement contacts.

    摘要翻译: 用于印刷电路板的插头连接器包括定位在壳体中的多个接触元件。 接触元件各自具有两个连接端和位于两端之间的中间触点,其中一个连接端为用于连接导线的绝缘位移触点的形式。 绝缘位移触头支撑在壳体上,使得当连接力作用在绝缘位移触点上时,接触元件被保持在壳体中。

    WIRE TERMINAL BLOCK AND METHOD FOR PRODUCTION OF A WIRE TERMINAL BLOCK WITH GEL FILLER
    9.
    发明申请
    WIRE TERMINAL BLOCK AND METHOD FOR PRODUCTION OF A WIRE TERMINAL BLOCK WITH GEL FILLER 审中-公开
    电线端子块及其制造方法,用于制造带有凝胶填料的电线端子块

    公开(公告)号:US20110130039A1

    公开(公告)日:2011-06-02

    申请号:US12921955

    申请日:2009-01-21

    申请人: Manfred Muller

    发明人: Manfred Muller

    IPC分类号: H01R13/40 H01R43/16

    摘要: The invention relates to a core-connecting terminal strip (1) and to a method for producing a core-connecting terminal strip (1) with gel filling, the core-connecting terminal strip (1) comprising at least one two-part housing (2, 3), in which core connection contacts (5) are arranged, the housing (2, 3) forming cavities, which are filled with a dielectric gel (10), the gel (10) changing its viscosity, the gel (10) being introduced into the housing (2, 3) in at least two temporally separate steps, the time between the steps being selected in such a way that the viscosity of the gel (10) of the preceding step has changed.

    摘要翻译: 本发明涉及一种芯连接端子条(1)和一种用于制造具有凝胶填充物的芯连接端子条(1)的方法,所述芯连接端子条(1)包括至少一个两部分壳体 2,3),其中布置有芯连接触点(5),形成空腔的壳体(2,3)填充有电介质凝胶(10),凝胶(10)改变其粘度,凝胶(10 )在至少两个时间上分离的步骤中引入到壳体(2,3)中,步骤之间的时间被选择为使得前一步骤的凝胶(10)的粘度已经改变。

    Plug-in connector for printed circuits
    10.
    发明授权
    Plug-in connector for printed circuits 失效
    用于印刷电路的插入式连接器

    公开(公告)号:US07717732B2

    公开(公告)日:2010-05-18

    申请号:US11547453

    申请日:2005-03-19

    IPC分类号: H01R4/24

    摘要: The invention relates to a plug-in connector for printed circuits, comprising a plurality of contact elements, whereby said contact elements have two connecting faces each. The one connecting face is configured as an insulation displacement contact for connecting cores and the other connecting face is configured as a tuning fork contact for contacting contact surfaces on a printed circuit. The insulation displacement contacts of the contact elements can be inserted into a plastic housing. At least one lower edge of the insulation displacement contacts is supported on the plastic housing so that the contact elements are captivated in the plastic housing when connecting forces act upon the insulation displacement contacts. The plastic housing comprises at least one chamber-type area. The tuning fork contacts are completely received by the plastic housing in the longitudinal direction. The contact element is configured as a two-part element, a first part of the contact element comprising the insulation displacement contact and the second part comprising the tuning fork contact. One contact arm each is positioned on both parts of the contact element and the two contact arms interact to give a disconnector.

    摘要翻译: 本发明涉及一种用于印刷电路的插入式连接器,包括多个接触元件,由此所述接触元件各具有两个连接面。 一个连接面被配置为用于连接芯的绝缘位移触点,另一个连接面被配置为用于接触印刷电路上的接触表面的音叉触点。 接触元件的绝缘位移触点可插入塑料外壳中。 绝缘位移触点的至少一个下边缘被支撑在塑料外壳上,使得当连接力作用于绝缘位移触点时,接触元件被吸收在塑料外壳中。 塑料外壳包括至少一个室型区域。 音叉接触件由塑料外壳沿纵向完全接收。 接触元件被配置为两部分元件,接触元件的第一部分包括绝缘位移触点,第二部分包括音叉触点。 一个接触臂各自定位在接触元件的两个部分上,并且两个接触臂相互作用以产生隔离开关。