Abstract:
The present disclosure relates to a cucurbituril-polyethylenimine-silica complex, a method for preparing the same and a carbon dioxide absorbent containing the same. According to the present disclosure, a cucurbituril-polyethylenimine-silica complex may be prepared by forming a complex wherein a cucurbituril is bound to polyethylenimine and including the same inside silica, and it may be used as a carbon dioxide absorbent with superior thermal stability and prevented formation of urea.
Abstract:
Disclosed is a dry carbon dioxide capturing device which can improve sorption efficiency by supplying sorbent for absorbing carbon dioxide or exhaust gas containing carbon dioxide to a recovery reactor in multistages at various heights. The dry carbon dioxide (CO2) capturing device with multistage supply structure comprises a recovery reactor 102 to recover CO2 by contacting a solid sorbent with exhaust gas; a recovery cyclone 110 connected to the recovery reactor 102 to discharge a gas while separating the CO2-captured solid sorbent only; a regenerator 114 connected to the recovery cyclone 110 to receive the CO2-captured solid sorbent and separate CO2 captured in the solid sorbent; and a pre-treatment reactor 122 connected to the regenerator 114 for cooling the solid sorbent free from CO2, wherein at least one of the exhaust gas supply line and the sorbent supply line has two or more arranged according to the height of the recovery reactor 102.
Abstract:
Disclosed is a dry CO2 capturing device with improved energy efficiency, which utilizes a difference in temperature between a regeneration operation of isolating CO2 from an sorbent containing CO2 absorbed therein and a pre-treatment operation of allowing H2O to be adsorbed to CO2. The dry carbon dioxide (CO2) capturing device, includes a recovery reactor for recovering CO2, a recovery cyclone for discharging a gas while separating the CO2-captured solid sorbent only, a regenerator for receiving the CO2-captured solid sorbent and separating CO2 captured in the solid sorbent, and a pre-treatment reactor for cooling the solid sorbent free from CO2, wherein a first heat exchanger is provided between the recovery cyclone and the regenerator to pass the CO2-captured solid sorbent therethrough, and a second heat exchanger is provided between the pre-treatment reactor and the regenerator to pass the solid sorbent free from CO2 therethrough. The first and second heat exchanger include a first and second heat exchange jacket mounted thereon which are connected to each other in a closed loop state.
Abstract:
Disclosed herein are an apparatus and method for gas leakage measurement in a high pressure reactor. In particular, the present invention relates to an apparatus for gas leakage measurement in a high pressure reactor including: a gas inlet; a first valve equipped to one side of the gas inlet; a flowmeter; a pressure gauge measuring an internal pressure of the reactor; a gas outlet; and a second valve, wherein if in internal pressure reaches a preset pressure by closing the second valve and injecting a gas to the reactor through the flowmeter in the state of opening the first valve, the gas leakage status in the reactor is measured through pressure changes in the pressure gauge after closing the first valve.
Abstract:
Disclosed are an apparatus and a method for measuring the height of a solid bed in a high-temperature and high-pressure fluidized bed system, and a fluidized bed system having the solid bed height measuring apparatus. The solid bed height measuring apparatus includes a lower pressure probe mounted at an upper side as high as a first height from a gas distributor of a fluidized bed reactor to measure pressure of the mounted location, and a middle pressure probe mounted at an upper side as high as a second height from the lower probe to measure pressure of the mounted location. An upper pressure probe is mounted at the top of the fluidized bed reactor to measure the inside pressure of the fluidized bed reactor. First and second differential pressure gauges are used for measuring differential pressures.
Abstract:
This invention relates to a device for separating carbon dioxide that includes a self-recycling loop, and to a method of separating carbon dioxide, which serve to effectively separate carbon dioxide from a combustion gas using a separation membrane provided with the self-recycling loop. This invention adopts a self-recycling loop in which the residue gas passing through a specific separation membrane is introduced into another separation membrane and in which a permeate gas passing through the specific separation membrane is introduced back into the specific separation membrane. Accordingly, the concentration of carbon dioxide in the feed gas of the specific separation membrane is increased, which increases the concentration of the permeate gas to thus improve the separation performance of the separation membrane, thereby separating high-purity carbon dioxide.
Abstract:
The present invention relates to a fluidized bed system having a sparger capable of minimizing a blockage by solids and controlling method thereof. And, more specifically, the present invention relates to a fluidized bed system having a sparger capable of minimizing a blockage by solids comprising a fluidized bed reactor to store a solid layer with a certain height and to fluidize the solid layer by using fluidization gases; a sparger having a pipe shape submerged in the solid layer and having a plurality of gas-discharging holes to spray fluidization gases onto the solid layer; and a gas-supplying line having its one end contacting a gas-supplying source and the other end connected to the sparger, wherein fluidization gases are introduced through the gas-supplying line into the sparger by driving the gas-supplying source, the fluidization gases are sprayed through the gas-discharging holes onto the solid layer, the gas-supplying source is placed higher than the sparger and the height difference (Hg) between the gas-supplying source and the sparger is greater than the height of the solid layer.
Abstract:
A desulfurization system removes sulfur ingredients included in synthetic gas generated from gasification of coal in a high temperature dry state. The system includes a desulfurization reactor, a desulfurization cyclone, and first and second regeneration reactors branched with the desulfurization cyclone. A first oxidizing agent is injected to a first oxidizing agent inlet of the first regeneration reactor, and a second oxidizing agent is injected to a second oxidizing agent inlet of the second regeneration reactor. A controller operates one of the first and second regeneration reactors in a regeneration mode, controlling the other to operate in a desulfurization mode.
Abstract:
Disclosed herein are a fluid sand falling type circulating fluidized bed boiler with a plurality of risers for preventing erosion and corrosion of water tubes and increasing combustion efficiency, and a method of operating the same. The fluid sand falling type circulating fluidized bed boiler with a plurality of risers includes a boiler section into which fuel and oxidizer are injected, a riser section connected to the boiler section so that the fuel and fluid sand supplied from the boiler section are introduced from the bottom of the riser section and flow up, and a relay section provided on the boiler section to supply the fluid sand having passed through the riser section to the boiler section, wherein the fuel is injected from the top of the boiler section and burned while flowing down therein.
Abstract:
The present disclosure relates to a metal-organic framework and a method for preparing the same. In accordance with the present disclosure, a metal-organic framework having large specific surface area can be prepared and the prepared porous material exhibits high carbon dioxide and carbon monoxide adsorption characteristics at room temperature.