-
公开(公告)号:US20190202982A1
公开(公告)日:2019-07-04
申请号:US16206266
申请日:2018-11-30
申请人: Cornell University
CPC分类号: C08G64/34 , C07F15/065 , C08G64/0208 , C08G64/183
摘要: The present disclosure is directed, in part, to methods of synthesizing a poly(ethylene carbonate) polymer from the reaction of ethylene oxide (EO) and carbon dioxide (CO2) in the presence of a metal complex. The present disclosure also provides novel metal complexes. In one aspect, the metal complex is of the formula (I), wherein R1, R2, R3, M, X and Ring A are as defined herein.
-
公开(公告)号:US20180297010A1
公开(公告)日:2018-10-18
申请号:US15766495
申请日:2016-10-07
CPC分类号: B01J20/226 , B01D2253/204 , B01D2256/16 , B01D2256/245 , B01J20/28066 , B01J20/3425 , B01J20/3491 , B60K15/03006 , B60K2015/03315 , B60K2015/03322 , C01B3/0015 , C07F15/025 , C07F15/065
摘要: The disclosure provides for adsorbents with stepped isotherms for gas storage applications.
-
公开(公告)号:US10038150B2
公开(公告)日:2018-07-31
申请号:US15099089
申请日:2016-04-14
发明人: Julian Burschka , Florian Kessler , Etienne Baranoff , Mohammad Khaja Nazeeruddin , Michael Graetzel , Shaik Mohammed Zakeeruddin , Anders Hagfeldt , Marina Freitag , Fabrizio Giordano
CPC分类号: H01L51/0083 , C07F15/065 , H01L51/002 , H01L51/0032 , H01L51/4226 , Y02E10/549
摘要: The invention relates to electrochemical devices comprising complexes of cobalt comprising at least one ligand with a 5- or six membered, N-containing heteroring. The complex are useful as p- and n-dopants, as over of electrochemical devices, in particular in organic semiconductors. The complexes are further useful as over-discharge prevention and overvoltage protection agents.
-
公开(公告)号:US09951096B2
公开(公告)日:2018-04-24
申请号:US15251668
申请日:2016-08-30
发明人: Scott D. Allen , Anna E. Cherian , Chris A. Simoneau , Jay J. Farmer , Geoffrey W. Coates , Alexei Gridnev , Robert E. LaPointe
CPC分类号: C07F15/065 , B01J31/0239 , B01J31/0259 , B01J31/0265 , B01J31/182 , B01J31/183 , B01J31/1835 , B01J31/2243 , B01J2531/0238 , B01J2531/025 , B01J2531/0252 , B01J2531/0294 , B01J2531/31 , B01J2531/62 , B01J2531/845 , C07C251/24 , C07C279/12 , C07C2601/14 , C07D213/53 , C07D487/04 , C07D487/22 , C07F9/5355 , C07F9/6561 , C07F19/005 , C08F4/80 , C08G64/34
摘要: The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.
-
公开(公告)号:US20180026209A1
公开(公告)日:2018-01-25
申请号:US15548496
申请日:2016-01-07
申请人: Merck Patent GmbH
IPC分类号: H01L51/00 , C09K11/06 , C07F3/06 , C07B59/00 , C07F15/02 , C07F5/06 , C07F5/00 , C07F15/00 , C07F15/06
CPC分类号: H01L51/0085 , C07B59/004 , C07B2200/05 , C07F3/06 , C07F5/003 , C07F5/069 , C07F15/0013 , C07F15/002 , C07F15/0026 , C07F15/0033 , C07F15/004 , C07F15/0046 , C07F15/0053 , C07F15/0073 , C07F15/008 , C07F15/02 , C07F15/025 , C07F15/06 , C07F15/065 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/1037 , C09K2211/1044 , C09K2211/1059 , C09K2211/1088 , C09K2211/182 , C09K2211/185 , C09K2211/186 , C09K2211/187 , C09K2211/188 , H01L51/0077 , H01L51/0079 , H01L51/0083 , H01L51/0084 , H01L51/0086 , H01L51/0087 , H01L51/0088 , H01L51/0089 , H01L51/0092 , H01L51/5016 , H01L2251/5384 , Y02E10/549
摘要: The present invention relates to metal complexes and to electronic devices, especially organic electroluminescent devices, comprising these metal complexes, especially as emitters.
-
6.
公开(公告)号:US20170361300A1
公开(公告)日:2017-12-21
申请号:US15186004
申请日:2016-06-17
IPC分类号: B01J19/10 , B01J19/00 , C07F1/08 , C07F15/04 , B01J37/00 , B01J20/22 , B01J20/30 , B01J31/16 , B01J35/02 , C07F15/06 , B01J19/06
CPC分类号: B01J19/10 , B01J19/0013 , B01J19/06 , B01J20/226 , B01J20/3085 , B01J20/3204 , B01J20/3236 , B01J20/3293 , B01J31/1691 , B01J35/026 , B01J37/0072 , B01J2219/00051 , B01J2219/0877 , B01J2231/005 , B01J2531/16 , B01J2531/845 , B01J2531/847 , C07C51/418 , C07C51/43 , C07C63/307 , C07C65/05 , C07F3/003 , C07F7/003 , C07F15/045 , C07F15/065
摘要: A MOF production system and method of making are detailed for continuous and controlled synthesis of MOFs and MOF composites. The system can provide optimized yields of MOFs and MOF composites greater than or equal to 95%.
-
公开(公告)号:US09822446B2
公开(公告)日:2017-11-21
申请号:US15017105
申请日:2016-02-05
CPC分类号: C23C16/45527 , C07F11/005 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065
摘要: A method of forming a thin film on a substrate which includes a step of contacting a surface with a precursor compound having a transition metal and one or more alkyl-1,3-diazabutadiene ligands is provided. The resulting modified surface is then contacted with an activating compound.
-
公开(公告)号:US09771453B2
公开(公告)日:2017-09-26
申请号:US14941988
申请日:2015-11-16
发明人: Myungahn Ok , Jisu Jeong , BunYeoul Lee , Sujith S. , Anish Cyriac , JaeKi Min , JongEon Seong
IPC分类号: C08G64/34 , C07C251/24 , C07C37/16 , C07C39/24 , C07C45/63 , C07C45/68 , C07F15/06 , C07C45/00 , C07C249/02
CPC分类号: C08G64/34 , C07C37/16 , C07C39/24 , C07C45/00 , C07C45/63 , C07C45/68 , C07C249/02 , C07C251/24 , C07C2601/14 , C07F15/065 , C07C47/565
摘要: Provided are a complex prepared from ammonium salt-containing ligands and having such an equilibrium structural formula that the metal center takes a negative charge of 2 or higher, and a method for preparing polycarbonate via copolymerization of an epoxide compound and carbon dioxide using the complex as a catalyst. When the complex is used as a catalyst for copolymerizing an epoxide compound and carbon dioxide, it shows high activity and high selectivity and provides high-molecular weight polycarbonate, and thus easily applicable to commercial processes. In addition, after forming polycarbonate via carbon dioxide/epoxide copolymerization using the complex as a catalyst, the catalyst may be separately recovered from the copolymer.
-
公开(公告)号:US09663546B2
公开(公告)日:2017-05-30
申请号:US14906386
申请日:2014-07-25
发明人: Roy Gerald Gordon
IPC分类号: C07F15/06 , C07F7/28 , C07F11/00 , C07F13/00 , C07D207/46 , C07D211/92 , C07F15/02 , C07F15/04 , H01L21/768
CPC分类号: C07F15/065 , C07D207/46 , C07D211/92 , C07F7/28 , C07F11/005 , C07F13/005 , C07F15/025 , C07F15/045 , H01L21/7685
摘要: Compounds, and oligomers of the compounds, are synthesized with cyclic amine ligands attached to a metal atom. These compounds are useful for the synthesis of materials containing metals. Examples include pure metals, metal alloys, metal oxides, metal nitrides, metal phosphides, metal sulfides, metal selenides, metal tellurides, metal borides, metal carbides, metal silicides and metal germanides. Techniques for materials synthesis include vapor deposition (chemical vapor deposition and atomic layer deposition), liquid solution methods (sol-gel and precipitation) and solid-state pyrolysis. Suitable applications include electrical interconnects in microelectronics and magnetoresistant layers in magnetic information storage devices. The films have very uniform thickness and high step coverage in narrow holes.
-
公开(公告)号:US09593203B2
公开(公告)日:2017-03-14
申请号:US14233571
申请日:2012-07-18
申请人: Scott D. Allen , Jay J. Farmer , Gabriel E. Job , Anna E. Cherian
发明人: Scott D. Allen , Jay J. Farmer , Gabriel E. Job , Anna E. Cherian
CPC分类号: C08G64/34 , C07F15/065
摘要: The present invention provides novel metal complexes, methods of making, and methods of using the same.
摘要翻译: 本发明提供新颖的金属络合物,制备方法及其使用方法。
-
-
-
-
-
-
-
-
-