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公开(公告)号:US09267030B2
公开(公告)日:2016-02-23
申请号:US13575617
申请日:2011-01-26
CPC分类号: C08L63/04 , C08G59/4014
摘要: Embodiments of the present disclosure provide a composition that includes a phosphorous-containing compound, a cyanate ester, an epoxy resin, and a maleimide. For the various embodiments, a viscosity of the composition increases less than 100% as measured by Gardner Bubble Viscosity a temperature of 23° C. in at least 3 days. For the various embodiments, the composition of the present disclosure can also include an aprotic solvent, such as a ketone. Embodiments of the present disclosure further include a composition that includes the phosphorous-containing compound, the cyanate ester, and the aprotic solvent. For the various embodiments, the composition can also include the epoxy resin and the maleimide. For the various embodiments, the composition does not include an aliphatic alcohol.
摘要翻译: 本公开的实施方案提供了包含含磷化合物,氰酸酯,环氧树脂和马来酰亚胺的组合物。 对于各种实施方案,组合物的粘度增加小于100%,如通过Gardner Bubble Viscosity在至少3天内23℃的温度测量的。 对于各种实施方案,本公开的组合物还可以包括非质子溶剂,例如酮。 本公开的实施方案还包括包含含磷化合物,氰酸酯和非质子传递溶剂的组合物。 对于各种实施方案,组合物还可以包括环氧树脂和马来酰亚胺。 对于各种实施方案,组合物不包括脂族醇。
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公开(公告)号:US20130005857A1
公开(公告)日:2013-01-03
申请号:US13575617
申请日:2011-01-26
CPC分类号: C08L63/04 , C08G59/4014
摘要: Embodiments of the present disclosure provide a composition that includes a phosphorous-containing compound, a cyanate ester, an epoxy resin, and a maleimide. For the various embodiments, a viscosity of the composition increases less than 100% as measured by Gardner Bubble Viscosity a temperature of 23° C. in at least 3 days. For the various embodiments, the composition of the present disclosure can also include an aprotic solvent, such as a ketone. Embodiments of the present disclosure further include a composition that includes the phosphorous-containing compound, the cyanate ester, and the aprotic solvent. For the various embodiments, the composition can also include the epoxy resin and the maleimide. For the various embodiments, the composition does not include an aliphatic alcohol.
摘要翻译: 本公开的实施方案提供了包含含磷化合物,氰酸酯,环氧树脂和马来酰亚胺的组合物。 对于各种实施方案,组合物的粘度增加小于100%,如通过Gardner Bubble Viscosity在至少3天内23℃的温度测量的。 对于各种实施方案,本公开的组合物还可以包括非质子溶剂,例如酮。 本公开的实施方案还包括包含含磷化合物,氰酸酯和非质子传递溶剂的组合物。 对于各种实施方案,组合物还可以包括环氧树脂和马来酰亚胺。 对于各种实施方案,组合物不包括脂族醇。
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3.
公开(公告)号:US20150148502A1
公开(公告)日:2015-05-28
申请号:US14116788
申请日:2012-05-11
申请人: Matthew D. Christianson , Timothy S. De Vries , Robert D. Froese , Matthias S. Ober , Jasson T. Patton , Duane R. Romer , Gordon R. Roof , Lixin Sun , Endre Szuromi , Curt N. Theriault , Dean M. Welsh , Timothy T. Wenzel , Paul H. Moran
发明人: Matthew D. Christianson , Timothy S. De Vries , Robert D. Froese , Matthias S. Ober , Jasson T. Patton , Duane R. Romer , Gordon R. Roof , Lixin Sun , Endre Szuromi , Curt N. Theriault , Dean M. Welsh , Timothy T. Wenzel , Paul H. Moran
IPC分类号: C08F4/78 , C08F210/06 , C07F11/00 , C08F110/06
CPC分类号: C08F4/78 , C07F11/00 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F4/69112 , C08F210/16 , C08F2500/15
摘要: Provided is a non-cyclopentadienyl-based chromium-ligand complex, preferably a chromium-ligand complex of formula (J): LCr(RA)m(D)k (J), wherein L is a non-Cp monoanionic ligand; Cr (chromium) is in a formal oxidation state of +3 or +2; when Cr formally is Cr+3, either m is 1 and RA is hydrocarbylene (a hydrocarbylene chromium-ligand complex of formula (J)) or m is 2 and each RA independently is hydrocarbyl (a dihydrocarbyl chromium-ligand complex of formula (J)), wherein each hydrocarbyl or hydrocarbylene of RA independently is unsubstituted or substituted by from 1 to 5 RAS; each RAS independently is a neutral aprotic heteroalkyl, neutral aprotic heterocycloalkyl, neutral aprotic heteroaryl, or neutral aprotic aryl; when Cr formally is Cr+2, m is 1 and RA is hydrocarbyl (a hydrocarbyl chromium-ligand complex of formula (J)); k is an integer of 0 or 1; D is absent when k is 0 or D is a neutral ligand when k is 1; wherein the chromium-ligand complex of formula (J) is overall neutral and lacks a cyclopentadienyl-based (Cp-based) moiety. Also provided is a chromium catalyst comprising or prepared from the complex. Also provided is a process of making the catalyst and a process employing the chromium catalyst for polymerizing the olefin monomer, especially a straight chain 1-alkene, to prepare the polyolefin, especially a partially chain-straightened poly(1-alkene) or olefin block copolymer. Further provided is the partially chain-straightened poly(1-alkene) or olefin block copolymer prepared thereby. Also provided is a high throughput workflow.
摘要翻译: 提供非环戊二烯基铬配体络合物,优选式(J)的铬 - 配体络合物:LCr(RA)m(D)k(J),其中L是非-C 1单阴离子配体; Cr(铬)处于+3或+2的正式氧化态; 当Cr正式为Cr + 3时,m为1,RA为亚烃基(式(J))的亚烃基铬 - 配体配合物)或m为2,各RA独立地为烃基(式(J)的二烃基铬 - 配体络合物 )),其中RA的各个烃基或亚烃基独立地未被取代或被1至5个RAS取代; 每个RAS独立地是中性非质子杂烷基,中性非质子性杂环烷基,中性非质子杂芳基或中性非质子性芳基; 当Cr正式为Cr + 2时,m为1,RA为烃基(式(J))的烃基铬 - 配体络合物); k是0或1的整数; 当k为0时,D不存在,或当k为1时D为中性配体; 其中式(J)的铬配体络合物是总体中性的,并且缺少基于环戊二烯基的(Cp-基)部分。 还提供了包含或由络合物制备的铬催化剂。 还提供了制备催化剂的方法和使用铬催化剂聚合烯烃单体,特别是直链1-烯烃的方法,以制备聚烯烃,特别是部分链改性的聚(1-烯烃)或烯烃嵌段 共聚物。 进一步提供由其制备的部分链直链化的聚(1-烯烃)或烯烃嵌段共聚物。 还提供了高吞吐量的工作流程。
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公开(公告)号:US20120083575A1
公开(公告)日:2012-04-05
申请号:US13228892
申请日:2011-09-09
申请人: Phillip D. Hustad , Endre Szuromi , Francis J. Timmers , Edmund M. Carnahan , Thomas P. Clark , Gordon R. Roof , Sara B. Klamo , Daniel J. Arriola
发明人: Phillip D. Hustad , Endre Szuromi , Francis J. Timmers , Edmund M. Carnahan , Thomas P. Clark , Gordon R. Roof , Sara B. Klamo , Daniel J. Arriola
IPC分类号: C08F293/00 , C08F4/52 , C08F4/50 , C08F4/76 , C08F4/00
CPC分类号: C08F210/16 , C08F297/08 , C08F2410/01 , C08F2410/04 , C08F4/64048 , C08F4/64144 , C08F4/64193
摘要: Embodiments of the invention provide a comb architecture olefin block copolymer, a method of making the comb olefin block copolymer and blends comprising the comb olefin block copolymer.
摘要翻译: 本发明的实施方案提供梳状结构烯烃嵌段共聚物,制备梳状烯烃嵌段共聚物的方法和包含梳形烯烃嵌段共聚物的共混物。
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公开(公告)号:US09296836B2
公开(公告)日:2016-03-29
申请号:US14116788
申请日:2012-05-11
申请人: Matthew D. Christianson , Timothy S. De Vries , Robert D. Froese , Matthias S. Ober , Jasson T. Patton , Duane R. Romer , Gordon R. Roof , Lixin Sun , Endre Szuromi , Curt N. Theriault , Dean M. Welsh , Timothy T. Wenzel , Paul H. Moran
发明人: Matthew D. Christianson , Timothy S. De Vries , Robert D. Froese , Matthias S. Ober , Jasson T. Patton , Duane R. Romer , Gordon R. Roof , Lixin Sun , Endre Szuromi , Curt N. Theriault , Dean M. Welsh , Timothy T. Wenzel , Paul H. Moran
IPC分类号: C08F4/78 , C08F10/00 , C08F210/06 , C07F11/00 , C08F110/06
CPC分类号: C08F4/78 , C07F11/00 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F4/69112 , C08F210/16 , C08F2500/15
摘要: Provided is a non-cyclopentadienyl-based chromium-ligand complex, preferably a chromium-ligand complex of formula (J): LCr(RA)m(D)k (J), wherein L is a non-Cp monoanionic ligand; Cr (chromium) is in a formal oxidation state of +3 or +2; when Cr formally is Cr+3, either m is 1 and RA is hydrocarbylene (a hydrocarbylene chromium-ligand complex of formula (J)) or m is 2 and each RA independently is hydrocarbyl (a dihydrocarbyl chromium-ligand complex of formula (J)), wherein each hydrocarbyl or hydrocarbylene of RA independently is unsubstituted or substituted by from 1 to 5 RAS; each RAS independently is a neutral aprotic heteroalkyl, neutral aprotic heterocycloalkyl, neutral aprotic heteroaryl, or neutral aprotic aryl; when Cr formally is Cr+2, m is 1 and RA is hydrocarbyl (a hydrocarbyl chromium-ligand complex of formula (J)); k is an integer of 0 or 1; D is absent when k is 0 or D is a neutral ligand when k is 1; wherein the chromium-ligand complex of formula (J) is overall neutral and lacks a cyclopentadienyl-based (Cp-based) moiety. Also provided is a chromium catalyst comprising or prepared from the complex. Also provided is a process of making the catalyst and a process employing the chromium catalyst for polymerizing the olefin monomer, especially a straight chain 1-alkene, to prepare the polyolefin, especially a partially chain-straightened poly(1-alkene) or olefin block copolymer. Further provided is the partially chain-straightened poly(1-alkene) or olefin block copolymer prepared thereby. Also provided is a high throughput workflow.
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公开(公告)号:US08907034B2
公开(公告)日:2014-12-09
申请号:US13228892
申请日:2011-09-09
申请人: Phillip D. Hustad , Endre Szuromi , Francis J. Timmers , Edmund M. Carnahan , Thomas P. Clark , Gordon R. Roof , Sara B. Klamo , Daniel J. Arriola
发明人: Phillip D. Hustad , Endre Szuromi , Francis J. Timmers , Edmund M. Carnahan , Thomas P. Clark , Gordon R. Roof , Sara B. Klamo , Daniel J. Arriola
IPC分类号: C08F293/00 , C08F4/52 , C08F4/50 , C08F4/76 , C08F4/00 , C08F210/16 , C08F297/08
CPC分类号: C08F210/16 , C08F297/08 , C08F2410/01 , C08F2410/04 , C08F4/64048 , C08F4/64144 , C08F4/64193
摘要: Embodiments of the invention provide a comb architecture olefin block copolymer, a method of making the comb olefin block copolymer and blends comprising the comb olefin block copolymer.
摘要翻译: 本发明的实施方案提供梳状结构烯烃嵌段共聚物,制备梳状烯烃嵌段共聚物的方法和包含梳形烯烃嵌段共聚物的共混物。
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