摘要:
The invention relates to a process for the preparation of optionally branched, high molecular weight polyarylene sulphides with melt viscosities which can be established at defined values and low corrosion.These polyarylene sulphides are obtained by reacting alkali metal sulphides, if appropriate mixed with alkali metal bisulphides and reaction accelerators, with dihalogenoaromatics and, if appropriate, polyhalogenoaromatics, with the addition of particular monohalogenoaromatics as chain stoppers.
摘要:
The invention relates to a process for the preparation of optionally branched, high molecular weight polyarylene sulphides with melt viscosities which can be established within a defined range and low corrosion.These polyarylene sulphides have been obtained by reacting alkali metal sulphides, if appropriate mixed with alkali metal bisulphides and reaction accelerators, with dihalogenoaromatics and polyhalogenoaromatics, with the addition of monohalogen and monomercapto compounds.
摘要:
This invention relates to a process for the preparation of high molecular weight, optionally branched polyarylene sulphides. These may be prepared from alkali metal sulphides and aromatic halogen compounds in a polar organic solvent in the absence of water.
摘要:
This invention relates to optionally branched polyarylene sulphides and a process for the production thereof in a polar solvent, from 0.2 to 100 mole %, based on the aromatic dihalogen compounds, of an amino acid being added to the reaction mixture.
摘要:
This invention relates to a process for the production of high molecular weight, optionally branched polyarylene sulphides from alkali metal sulphides and halogenated aromatic compounds in the presence of from 0.5 to 100 mol %, based on the molar quantity of aromatic dihalogen compounds, of an ester or anhydride of a carboxylic acid.
摘要:
The invention relates to a process for the preparation of high-molecular, optionally branched polyarylene sulphides. These can be prepared without a catalyst in a polar organic solvent by reacting dihalogenoaromatic compounds with mixtures of sodium and potassium sulphides and hydrogensulphides.