公开(公告)号：US4540418A

公开(公告)日：1985-09-10

申请号：US600450

申请日：1984-04-16

申请人： Katsumasa Otake ,  Takashi Omura ,  Yutaka Kayane ,  Kunihiko Imada

发明人： Katsumasa Otake ,  Takashi Omura ,  Yutaka Kayane ,  Kunihiko Imada

IPC分类号： D06P1/384 ,  C09B67/24 ,  D06P1/38 ,  D06P3/66

CPC分类号： C09B67/0072 ,  Y10S8/918

摘要： A reactive dye composition comprising at least one alkylnaphthalenesulfonic acid/formaldehyde condensate and a compound represented by the following formula, ##STR1## wherein D is an organic dye residue having at least one sulfo group, R.sub.1 and R.sub.2 are independently a hydrogen atom or a C.sub.1 to C.sub.4 alkyl group unsubstituted or substituted with a halogen atom or a hydroxy, cyano, alkoxy, carboxy, carbamoyl, alkoxycarbonyl, alkylcarbonyloxy, sulfo or sulfamoyl group, A is a phenylene group unsubstituted or substituted with one or two substituents selected from chlorine and bromine atoms and methyl, ethyl, methoxy, ethoxy and sulfo groups, or a naphthylene group unsubstituted or substituted with one sulfo group, X is a halogen atom, and Y is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z in which Z is a group capable of being split by an alkali, which composition is very readily soluble in water and aqueous alkaline solution, so that a dyeing or printing of cellulose fiber materials can be effectively carried out even by one-bath pad dyeing or one-phase printing methods to give a dyed product of a deep color having excellent levelness and no speck.

摘要翻译： 包含至少一种烷基萘磺酸/甲醛缩合物和由下式表示的化合物的活性染料组合物，其中D是具有至少一个磺基的有机染料残基，R 1和R 2独立地是氢原子或C 1 未取代或被卤素原子或羟基，氰基，烷氧基，羧基，氨基甲酰基，烷氧基羰基，烷基羰基氧基，磺基或氨磺酰基取代的C4烷基，A是未取代的或被一个或两个选自氯和溴的取代基取代的亚苯基 原子和甲基，乙基，甲氧基，乙氧基和磺基，或未被取代或被一个磺基取代的亚萘基，X为卤素原子，Y为-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z，其中Z为能够 用碱分解，该组合物非常易溶于水和碱性水溶液，从而可以有效地进行纤维素纤维材料的染色或印花 通过单浴垫染色或单相印刷方法，得到具有优良水平性和无斑点的深色染色产品。

公开(公告)号：US4511507A

公开(公告)日：1985-04-16

申请号：US563587

申请日：1983-12-20

申请人： Yutaka Kayane ,  Takashi Omura ,  Katsumasa Otake ,  Akira Takeshita

发明人： Yutaka Kayane ,  Takashi Omura ,  Katsumasa Otake ,  Akira Takeshita

IPC分类号： C09B33/10 ,  C09B62/44 ,  C09B62/51 ,  D06P1/38 ,  C09B62/08 ,  D06P3/10

CPC分类号： D06P1/38 ,  C09B62/4413 ,  Y10S8/918

摘要： A monoazo compound which is useful for dyeing or printing fiber materials, particularly cellulose fiber materials in red color, and which is represented by a free acid of the formula, ##STR1## wherein D is a phenyl group substituted with one to three substituents selected from the group consisting of halogen atoms and methyl, ethyl, methoxy, ethoxy, acetylamino, propionylamino, sulfo and carboxyl groups, R is a C.sub.1 to C.sub.4 alkyl group unsubstituted or substituted with a halogen atom or a hydroxyl, cyano, alkyl, alkoxy, carboxyl, carbamoyl, alkoxycarbonyl or sulfo group, A is a phenylene group unsubstituted or substituted with one or two substituents selected from the group consisting of methyl, ethyl, methoxy, ethoxy and sulfo groups and chlorine and bromine atoms, or a naphthylene group unsubstituted or substituted with one sulfo group, and X is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y in which Y is a group capable of being split by the action of an alkali.

摘要翻译： 用于染色或印刷纤维材料，特别是红色的纤维素纤维材料的单偶氮化合物，其由下式的游离酸表示，其中D是被一至三个选自以下的取代基取代的苯基： 由卤素原子和甲基，乙基，甲氧基，乙氧基，乙酰氨基，丙酰氨基，磺基和羧基组成的基团，R是未被取代或被卤素原子或羟基，氰基，烷基，烷氧基，羧基取代的C1至C4烷基 ，氨基甲酰基，烷氧基羰基或磺基，A是未被取代或被一个或两个选自甲基，乙基，甲氧基，乙氧基和磺基以及氯和溴原子的取代基取代的亚苯基，或未取代或取代的亚萘基 具有一个磺基，X是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Y，其中Y是能够通过碱的作用而分裂的基团。

公开(公告)号：US4631341A

公开(公告)日：1986-12-23

申请号：US610750

申请日：1984-05-16

申请人： Yutaka Kayane ,  Takashi Omura ,  Katsumasa Otake ,  Akira Takeshita

发明人： Yutaka Kayane ,  Takashi Omura ,  Katsumasa Otake ,  Akira Takeshita

IPC分类号： C09B62/44 ,  D06P1/38 ,  C07D251/50

CPC分类号： C09B62/4409 ,  D06P1/38

摘要： A compound, or a salt thereof, represented by the formula, ##STR1## wherein X is a halogen atom, Y is a group of --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z (in which Z is a group capable of being split by the action of an alkali), A is an unsubstituted or substituted phenylene or naphthylene group, B is a cycloalkylene group of the formula, ##STR2## an arylene group of the formula, ##STR3## or an alkylene of the formula --(CH.sub.2).sub.1 --, (in which R.sub.3 and R.sub.4 are independently a hydrogen atom or a methyl, ethyl or methoxy group, n is 0, 1 or 2 and 1 is an integer of 2 to 6), R.sub.1 and R.sub.2 are independently a hydrogen atom or an unsubstituted or substituted lower alkyl group, and m is 0, 1 or 2, provided that the group Y is located at m- or p-position to the group ##STR4## when B is the arylene group, which is useful for dyeing fiber materials, particularly cellulose fiber materials, in a blue color having excellent fastness, with excellent build-up and level-dyeing properties.

摘要翻译： 由下式表示的化合物或其盐，其中X是卤素原子，Y是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z的基团（其中Z是能够通过 A是未取代或取代的亚苯基或亚萘基，B是下式的亚环烷基，下式的亚芳基，或者式 - （CH 2）1 - 的亚烷基， （其中R 3和R 4独立地为氢原子或甲基，乙基或甲氧基，n为0,1或2，1为2至6的整数），R 1和R 2独立地为氢原子或未取代的或未取代的 取代的低级烷基，并且m为0,1或2，条件是当B是亚芳基时，基团Y位于基团“m”或p位置，这可用于染色纤维材料，特别是 纤维素纤维材料，具有优异坚牢度的蓝色，具有优异的聚集和水平染色性能。

公开(公告)号：US4626589A

公开(公告)日：1986-12-02

申请号：US699182

申请日：1985-02-07

申请人： Takashi Omura ,  Yutaka Kayane ,  Mikoto Takahashi ,  Tetsuya Miyamoto ,  Akira Takeshita ,  Naoki Harada ,  Katsumasa Otake

发明人： Takashi Omura ,  Yutaka Kayane ,  Mikoto Takahashi ,  Tetsuya Miyamoto ,  Akira Takeshita ,  Naoki Harada ,  Katsumasa Otake

IPC分类号： C09B62/002 ,  C09B62/04 ,  C09B62/44 ,  C09B62/503 ,  D06P1/38 ,  C09B44/02 ,  C09B44/08 ,  C09B62/523 ,  C09B62/527

CPC分类号： C09B62/4403 ,  D06P1/38

摘要： A compound of the formula, ##STR1## wherein D is an organic dye moiety, R.sub.1 and R.sub.2 are independently hydrogen or a substituted or unsubstituted lower alkyl group, R.sub.3 is hydrogen or a substituted or unsubstituted lower alkyl, phenyl or naphthyl group, X.sub.1 and X.sub.2 are independently hydrogen, halogen or a lower alkyl, cyano, carbamoyl, vinyl, .beta.-hydroxyethyl, .beta.-sulfoethyl, .beta.-sulfatoethyl, carboxyl, carboxylic acid ester or sulfonic acid group, and Z is appended to the above-defined D or R.sub.3 and stands for --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y, in which Y is a group capable of being split by the action of an alkali, which is useful for dyeing hydroxyl or amido group-containing fiber materials with excellent build-up properties, thereby giving dyed products having excellent various fastness properties.

摘要翻译： 下式的化合物，其中D是有机染料部分，R1和R2独立地是氢或取代或未取代的低级烷基，R3是氢或取代或未取代的低级烷基，苯基或萘基，X1和 X 2独立地是氢，卤素或低级烷基，氰基，氨基甲酰基，乙烯基，β-羟基乙基，β-磺基乙基，β-磺基乙基，羧基，羧酸酯或磺酸基，并且Z附加到上述定义的D或 R3代表-SO2CH = CH2或-SO2CH2CH2Y，其中Y是能够通过碱的作用分裂的基团，其可用于染色具有优异累积性质的含羟基或含酰胺基的纤维材料，因此 给出具有优异的各种牢度特性的染色产品。

公开(公告)号：US4551150A

公开(公告)日：1985-11-05

申请号：US617032

申请日：1984-06-04

申请人： Katsumasa Otake ,  Takashi Ikeda ,  Takashi Omura ,  Kunihiko Imada

发明人： Katsumasa Otake ,  Takashi Ikeda ,  Takashi Omura ,  Kunihiko Imada

IPC分类号： D06P1/38 ,  D06P3/66 ,  D06P5/08

CPC分类号： D06P3/66 ,  D06P5/08 ,  Y10S8/918

摘要： Cellulose fiber materials are dyed with a dye represented by a free acid of the formula, ##STR1## wherein W.sub.1 and W.sub.2 are independently a direct linkage or a bridging group, Q.sub.1 and Q.sub.2 are independently a fiber-reactive group, A.sub.1 and A.sub.2 are independently a phenylene or naphthylene group unsubstituted or substituted, D is a residue of 1-amino-8-naphthol mono- or di-sulfonic acid, m and n are independently 0, 1 or 2, provided that they satisfy the formula, 0

摘要翻译： 纤维素纤维材料用下式游离酸代表的染料染色，其中W1和W2独立地是直链或桥键基，Q1和Q2独立地是纤维反应性基团，A1和A2独立地是 未取代或取代的亚苯基或亚萘基，D是1-氨基-8-萘酚单 - 或二 - 磺酸的残基，m和n独立地为0,1或2，条件是它们满足式0

公开(公告)号：US6136970A

公开(公告)日：2000-10-24

申请号：US967617

申请日：1992-10-29

申请人： Kazufumi Yokogawa ,  Takahiko Fujisaki ,  Miyao Takahashi ,  Shigeru Kawabata ,  Naoki Harada ,  Kingo Akahori ,  Yutaka Kayane ,  Takashi Omura

发明人： Kazufumi Yokogawa ,  Takahiko Fujisaki ,  Miyao Takahashi ,  Shigeru Kawabata ,  Naoki Harada ,  Kingo Akahori ,  Yutaka Kayane ,  Takashi Omura

IPC分类号： C07D265/34 ,  C09B19/00 ,  C09B62/002 ,  C09B62/02 ,  C09B62/44 ,  C09B62/503 ,  C07D498/04

CPC分类号： C09B62/5033 ,  C09B62/0025 ,  C09B62/021 ,  C09B62/4405

摘要： An asymmetric dioxazine compound represented by the following formula (I) in the free acid form: ##STR1## wherein A.sub.1 and A.sub.2 independently of one another are each sulfo, halo, alkyl or alkoxy, X.sub.1 and X.sub.2 independently of one another are each hydrogen, halo, alkyl, alkoxy or phenoxy, R.sub.1 is hydrogen or unsubstituted or substituted alkyl, R.sub.2 and R.sub.3 independently of one another are each hydrogen, alkyl, alkoxy, halo or unsubstituted or substituted amino, Z is a fiber-reactive group, m and n independently of one another are each 0 or 1, provided that m.noteq.n, and L is 1 or 2. This compound is suitable for dyeing and printing cellulose fiber, natural and synthetic polyamide fibers, polyurethane fiber, leather and the like and mixed yarns thereof, to obtain dyed or printed products of a color fast to light, wetness and chlorine with superior build-up and level dyeing properties.

摘要翻译： 由游离酸形式的下式（I）表示的不对称二嗪类化合物：其中A1和A2彼此独立地各自为磺基，卤素，烷基或烷氧基，X 1和X 2彼此独立地为氢，卤素，烷基 ，烷氧基或苯氧基，R 1是氢或未取代或取代的烷基，R 2和R 3彼此独立地各自为氢，烷基，烷氧基，卤素或未取代或取代的氨基，Z为纤维反应性基团，m和n独立地为一个 另外每个都为0或1，条件是m注意n和L为1或2.该化合物适用于将纤维素纤维，天然和合成聚酰胺纤维，聚氨酯纤维，皮革等及其混合纱线染色和印刷到 获得染色或印刷的产品，颜色快速到轻，湿和氯，具有优异的积聚和水平的染色性能。

公开(公告)号：US4977261A

公开(公告)日：1990-12-11

申请号：US141762

申请日：1988-01-11

申请人： Yutaka Kayane ,  Takashi Omura ,  Naoki Harada ,  Yasuji Mori ,  Yosuke Yamamoto ,  Tetsuya Miyamoto ,  Takehiro Kusumoto

发明人： Yutaka Kayane ,  Takashi Omura ,  Naoki Harada ,  Yasuji Mori ,  Yosuke Yamamoto ,  Tetsuya Miyamoto ,  Takehiro Kusumoto

IPC分类号： C09B62/505

CPC分类号： C09B62/505

摘要： A compound of the following formula in the free acid form, ##STR1## wherein and R and R.sub.1 are each hydrogen or alkyl, A is a divalent group of the formula, ##STR2## wherein R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, methyl, ethyl, methoxy or ethoxy, m is 0 or 1, n, u and v are each 0, 1 or 2, p is 0, 1, 2 or 3, q and s are each an integer of 2 to 6, and r is 1 or 2, B.sub.1 is phenylene or naphthylene, Z.sub.1 is vinyl, .beta.-sulfatoethyl or the like, l is 0, 1 or 2, and X is a group of the formula, ##STR3## wherein R.sub.2 is hydrogen or alkyl, B.sub.2 is phenylene or naphtylene, Z.sub.2 is vinyl, .beta.-sulfatoethyl or the like, R.sub.6 and R.sub.7 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, and R, A and l are as defined above, which is useful for dyeing or printing fiber materials to give a dyed or printed product of a brilliant blue color superior in fastness properties such as light fastness and perspiration-light fastness, with superior build-up property.

公开(公告)号：US4975094A

公开(公告)日：1990-12-04

申请号：US390278

申请日：1989-08-07

申请人： Masayuki Miki ,  Kingo Akahori ,  Yutaka Kayane ,  Naoki Harada ,  Takashi Omura

发明人： Masayuki Miki ,  Kingo Akahori ,  Yutaka Kayane ,  Naoki Harada ,  Takashi Omura

IPC分类号： C09B62/44 ,  C09B62/505

CPC分类号： C09B62/505 ,  C09B62/4403

摘要： Anthrapyridone compounds of the formula, ##STR1## wherein R.sub.1 is hydrogen, benzoyl, acetyl or alkyloxycarbonyl, R.sub.2 is hydrogen or alkyl, R.sub.3 is hydrogen, halogen, sulfo, phenoxy, phenylthio or alkoxy, R.sub.4 is hydrogen, halogen or sulfo, R.sub.5 and R.sub.6 are each hydrogen or alkyl, V is --O--, --S-- or ##STR2## in which R.sub.7 is hydrogen, acetyl or alkyl, B is phenylene or naphthylene, D is vinyl or --CH.sub.2 CH.sub.2 L such as --CH.sub.2 CH.sub.2 OSO.sub.3 H, A is a divalent group, and X is halogen, quaternary ammonium, pyridinio, amino or a ##STR3## like group, which are useful for dyeing or printing fiber materials with superior dyeing performance.

公开(公告)号：US4701524A

公开(公告)日：1987-10-20

申请号：US795123

申请日：1985-11-05

申请人： Yutaka Kayane ,  Hirokazu Sawamoto ,  Takashi Omura ,  Naoki Harada ,  Akira Takeshita

发明人： Yutaka Kayane ,  Hirokazu Sawamoto ,  Takashi Omura ,  Naoki Harada ,  Akira Takeshita

IPC分类号： C09B62/51 ,  D06P1/38 ,  D06P1/384 ,  C09B62/45 ,  C09B62/53 ,  D06P3/66

CPC分类号： C09B62/51

摘要： A monoazo compound, or a salt thereof, of the formula, ##STR1## wherein W is a hydrogen atom or a carbamoyl group, R.sub.1 is a lower alkyl group, R.sub.2 and R.sub.3 are independently a hydrogen atom or a lower alkyl group, A is an unsubstituted or substituted phenylene or naphthylene group, Y is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a group capable of being split by the action of an alkali, and X is an aromatic or aliphatic group substituted with one or two members selected from sulfonic acid group and carboxylic acid group, which is useful for dyeing fiber materials to give dyed products of a characteristic yellow color excellent in various fastness properties.

摘要翻译： 下式的单偶氮化合物或其盐，其中W是氢原子或氨基甲酰基，R1是低级烷基，R2和R3独立地是氢原子或低级烷基，A是 未取代或取代的亚苯基或亚萘基，Y是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z，其中Z是能够被碱作用的基团，X是被一个或两个成员取代的芳族或脂族基团 选自磺酸基和羧酸基，其可用于染色纤维材料以得到具有优异的各种牢度性质的特征黄色的染色产品。

公开(公告)号：US4618671A

公开(公告)日：1986-10-21

申请号：US682241

申请日：1984-12-17

申请人： Yutaka Kayane ,  Tetsuya Miyamoto ,  Takashi Omura ,  Hirokazu Sawamoto ,  Naoki Harada ,  Akira Takeshita

发明人： Yutaka Kayane ,  Tetsuya Miyamoto ,  Takashi Omura ,  Hirokazu Sawamoto ,  Naoki Harada ,  Akira Takeshita

IPC分类号： C09B62/51 ,  C09B62/44 ,  D06P1/38 ,  D06P1/384 ,  C09B62/085 ,  C09B62/53 ,  D06P1/382 ,  D06P3/66

CPC分类号： C09B62/4413 ,  D06P1/384

摘要： A pyridone compound of the following formula, or a salt thereof, ##STR1## wherein R.sub.1 and R.sub.2 are independently a hydrogen atom or a lower alkyl group having up to 4 carbon atoms, X is a hydrogen atom or a methyl or sulfo group, A is an unsubstituted or substituted phenylene or naphthylene group, and Y is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a group capable of being split by the action of an alkali. The compound is useful for dyeing or printing fiber materials to give a dyed product of a brilliant yellow color excellent in various fastness properties with good reproducibility.

摘要翻译： 下式的吡啶酮化合物或其盐，其中R 1和R 2独立地为氢原子或具有至多4个碳原子的低级烷基，X为氢原子或甲基或磺基，A 是未取代或取代的亚苯基或亚萘基，Y是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z，其中Z是能够通过碱的作用而分裂的基团。 该化合物可用于染色或印刷纤维材料，得到具有良好重现性的各种牢度性能优异的亮黄色染色产品。