公开(公告)号：US07220468B2

公开(公告)日：2007-05-22

申请号：US11488994

申请日：2006-07-19

申请人： Kazufumi Ogawa ,  Norihisa Mino ,  Shinichi Yamamoto

发明人： Kazufumi Ogawa ,  Norihisa Mino ,  Shinichi Yamamoto

IPC分类号： C09K19/06

CPC分类号： H01L51/0545 ,  B82Y10/00 ,  G02F1/133711 ,  G02F1/133719 ,  G02F1/13378 ,  G02F1/133784 ,  G02F1/133788 ,  G02F2001/133796 ,  G02F2202/027 ,  H01B1/12 ,  H01B1/125 ,  H01B1/127 ,  H01L51/0012 ,  H01L51/0075 ,  H01L51/0508 ,  H01L51/0595 ,  H01L51/42 ,  H01L51/428 ,  Y02E10/549 ,  Y02P70/521 ,  Y10S428/91 ,  Y10T428/10 ,  Y10T428/1005 ,  Y10T428/1014 ,  Y10T428/31663

摘要： It is an object to provide a conductive organic thin film having organic molecules that include at one end a terminal bonding group that is covalently bonded to a substrate surface, a conjugate bonding group that is located at any portion of the organic molecules and that is polymerized with other molecules, and a polar functional group that does not include active hydrogen and that is located at any portion between the terminal bonding group and the conjugate bonding group, wherein the organic molecules are oriented and their conjugate bonding groups are polymerized, forming a conduction network. The conductivity (ρ) of the conductive organic thin film at room temperature (25° C.) is at least 5.5×105 S/cm, and preferably at least 1×107 S/cm, without dopants, having significantly higher conductivity than metals such as gold and silver. In particular, a film of polypyrrole or polythienylene conjugate bonds that is polymerized through polymerization through electrolytic oxidation has high conductivity.

摘要翻译： 本发明的目的是提供一种具有有机分子的导电有机薄膜，该有机分子的一端包含共价结合到基材表面的端键合基团，位于有机分子的任何部分并且被聚合的共轭键合基团 与其它分子，以及不包括活性氢并且位于末端键合基团和共轭键合基团之间的任何部分的极性官能团，其中有机分子取向并且它们的共轭键合基团聚合，形成导电 网络。 导电有机薄膜在室温（25℃）下的电导率（rho）至少为5.5×10 -5 S / cm，优选至少为1×10 7 / S / cm，没有掺杂剂，具有比诸如金和银的金属显着更高的导电率。 特别地，通过电解氧化聚合而聚合的聚吡咯或聚噻吩键共轭键具有高导电性。

公开(公告)号：US07560731B2

公开(公告)日：2009-07-14

申请号：US11633924

申请日：2006-12-05

申请人： Shinichi Yamamoto ,  Norihisa Mino ,  Kazufumi Ogawa

发明人： Shinichi Yamamoto ,  Norihisa Mino ,  Kazufumi Ogawa

IPC分类号： H01L35/24

CPC分类号： G02F1/13439 ,  C08G61/122 ,  G02F1/1343 ,  G02F2001/136295 ,  G02F2202/022 ,  H01L51/0021 ,  H01L51/0035

摘要： An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

摘要翻译： 本发明的有机电子器件包括基板，形成在基板上的至少两个电极，形成在基板上并电连接电极的导电有机薄膜，以及用于涂覆至少一部分 电极。 导电有机薄膜是含有共轭键合基团的有机分子的聚合物，并且每个有机分子的一端化学键合到基底表面，并且有机分子中的共轭键基团与其它分子聚合 共轭键合基团以形成共轭键链。 涂膜将电极与导电性有机薄膜电连接，与直接连接电极和导电性有机薄膜的情况相比，能够实现较小的连接电阻。 作为涂膜，可以使用由金，铂，银等金属制成的膜，导电性聚合物膜，或与电极化学键合的单分子膜。

公开(公告)号：US20070085076A1

公开(公告)日：2007-04-19

申请号：US11633924

申请日：2006-12-05

申请人： Shinichi Yamamoto ,  Norihisa Mino ,  Kazufumi Ogawa

发明人： Shinichi Yamamoto ,  Norihisa Mino ,  Kazufumi Ogawa

IPC分类号： H01L29/08

CPC分类号： G02F1/13439 ,  C08G61/122 ,  G02F1/1343 ,  G02F2001/136295 ,  G02F2202/022 ,  H01L51/0021 ,  H01L51/0035

摘要： An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

公开(公告)号：US20060257588A1

公开(公告)日：2006-11-16

申请号：US11488994

申请日：2006-07-19

申请人： Kazufumi Ogawa ,  Norihisa Mino ,  Shinichi Yamamoto

发明人： Kazufumi Ogawa ,  Norihisa Mino ,  Shinichi Yamamoto

IPC分类号： C09K19/00

CPC分类号： H01L51/0545 ,  B82Y10/00 ,  G02F1/133711 ,  G02F1/133719 ,  G02F1/13378 ,  G02F1/133784 ,  G02F1/133788 ,  G02F2001/133796 ,  G02F2202/027 ,  H01B1/12 ,  H01B1/125 ,  H01B1/127 ,  H01L51/0012 ,  H01L51/0075 ,  H01L51/0508 ,  H01L51/0595 ,  H01L51/42 ,  H01L51/428 ,  Y02E10/549 ,  Y02P70/521 ,  Y10S428/91 ,  Y10T428/10 ,  Y10T428/1005 ,  Y10T428/1014 ,  Y10T428/31663

摘要： It is an object to provide a conductive organic thin film having organic molecules that include at one end a terminal bonding group that is covalently bonded to a substrate surface, a conjugate bonding group that is located at any portion of the organic molecules and that is polymerized with other molecules, and a polar functional group that does not include active hydrogen and that is located at any portion between the terminal bonding group and the conjugate bonding group, wherein the organic molecules are oriented and their conjugate bonding groups are polymerized, forming a conduction network. The conductivity (ρ) of the conductive organic thin film at room temperature (25° C.) is at least 5.5×105 S/cm, and preferably at least 1×107 S/cm, without dopants, having significantly higher conductivity than metals such as gold and silver. In particular, a film of polypyrrole or polythienylene conjugate bonds that is polymerized through polymerization through electrolytic oxidation has high conductivity.

摘要翻译： 本发明的目的是提供一种具有有机分子的导电有机薄膜，该有机分子的一端包含共价结合到基材表面的端键合基团，位于有机分子的任何部分并且被聚合的共轭键合基团 与其它分子，以及不包括活性氢并且位于末端键合基团和共轭键合基团之间的任何部分的极性官能团，其中有机分子取向并且它们的共轭键合基团聚合，形成导电 网络。 导电有机薄膜在室温（25℃）下的电导率（rho）至少为5.5×10 -5 S / cm，优选至少为1×10 7 / S / cm，没有掺杂剂，具有比诸如金和银的金属显着更高的导电率。 特别地，通过电解氧化聚合而聚合的聚吡咯或聚噻吩键共轭键具有高导电性。

公开(公告)号：US07259389B2

公开(公告)日：2007-08-21

申请号：US10503829

申请日：2003-02-07

申请人： Shinichi Yamamoto ,  Norihisa Mino ,  Kazufumi Ogawa

发明人： Shinichi Yamamoto ,  Norihisa Mino ,  Kazufumi Ogawa

IPC分类号： H01L35/24

CPC分类号： G02F1/13439 ,  C08G61/122 ,  G02F1/1343 ,  G02F2001/136295 ,  G02F2202/022 ,  H01L51/0021 ,  H01L51/0035

摘要： An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

摘要翻译： 本发明的有机电子器件包括基板，形成在基板上的至少两个电极，形成在基板上并电连接电极的导电有机薄膜，以及用于涂覆至少一部分 电极。 导电有机薄膜是含有共轭键合基团的有机分子的聚合物，并且每个有机分子的一端化学键合到基底表面，并且有机分子中的共轭键基团与其它分子聚合 共轭键合基团以形成共轭键链。 涂膜将电极与导电性有机薄膜电连接，与直接连接电极和导电性有机薄膜的情况相比，能够实现较小的连接电阻。 作为涂膜，可以使用由金，铂，银等金属制成的膜，导电性聚合物膜，或与电极化学键合的单分子膜。

公开(公告)号：US07198829B2

公开(公告)日：2007-04-03

申请号：US10465939

申请日：2001-12-25

申请人： Kazufumi Ogawa ,  Norihisa Mino ,  Shinichi Yamamoto

发明人： Kazufumi Ogawa ,  Norihisa Mino ,  Shinichi Yamamoto

IPC分类号： C09K19/06

CPC分类号： H01L51/0545 ,  B82Y10/00 ,  G02F1/133711 ,  G02F1/133719 ,  G02F1/13378 ,  G02F1/133784 ,  G02F1/133788 ,  G02F2001/133796 ,  G02F2202/027 ,  H01B1/12 ,  H01B1/125 ,  H01B1/127 ,  H01L51/0012 ,  H01L51/0075 ,  H01L51/0508 ,  H01L51/0595 ,  H01L51/42 ,  H01L51/428 ,  Y02E10/549 ,  Y02P70/521 ,  Y10S428/91 ,  Y10T428/10 ,  Y10T428/1005 ,  Y10T428/1014 ,  Y10T428/31663

摘要： It is an object to provide a conductive organic thin film having organic molecules that include at one end a terminal bonding group that is covalently bonded to a substrate surface, a conjugate bonding group that is located at any portion of the organic molecules and that is polymerized with other molecules, and a polar functional group that does not include active hydrogen and that is located at any portion between the terminal bonding group and the conjugate bonding group, wherein the organic molecules are oriented and their conjugate bonding groups are polymerized, forming a conduction network. The conductivity (ρ) of the conductive organic thin film at room temperature (25° C.) is at least 5.5×105 S/cm, and preferably at least 1×107 S/cm, without dopants, having significantly higher conductivity than metals such as gold and silver. In particular, a film of polypyrrole or polythienylene conjugate bonds that is polymerized through polymerization through electrolytic oxidation has high conductivity.

摘要翻译： 本发明的目的是提供一种具有有机分子的导电有机薄膜，该有机分子的一端包含共价结合到基材表面的端键合基团，位于有机分子的任何部分并且被聚合的共轭键合基团 与其它分子，以及不包括活性氢并且位于末端键合基团和共轭键合基团之间的任何部分的极性官能团，其中有机分子取向并且它们的共轭键合基团聚合，形成导电 网络。 导电有机薄膜在室温（25℃）下的电导率（rho）至少为5.5×10 -5 S / cm，优选至少为1×10 7 / S / cm，没有掺杂剂，具有比诸如金和银的金属显着更高的导电率。 特别地，通过电解氧化聚合而聚合的聚吡咯或聚噻吩键共轭键具有高导电性。

公开(公告)号：US07027327B2

公开(公告)日：2006-04-11

申请号：US10486628

申请日：2002-12-16

申请人： Shinichi Yamamoto ,  Kazufumi Ogawa ,  Norihisa Mino

发明人： Shinichi Yamamoto ,  Kazufumi Ogawa ,  Norihisa Mino

IPC分类号： G11C11/34

CPC分类号： G11C13/0014 ,  B82Y10/00 ,  G11C13/0016 ,  H01L51/0094

摘要： A nonvolatile memory includes at least a first electrode (71) and a second electrode (72) provided on a substrate, the first and second electrodes being separated from each other, and a conductive organic thin film (73) for electrically connecting the first and second electrodes. The conductive organic thin film (73) has a first electric state in which it exhibits a first resistance, and a second electric state in which it exhibits a second resistance. A first threshold voltage for a transition from the first electric state to the second electric state, and a second threshold voltage for a transition from the second electric state to the first electric state are different from each other, and either the first electric state or the second electric state is maintained a voltage in a range between the first threshold voltage and the second threshold voltage.

摘要翻译： 非易失性存储器至少包括设置在基板上的第一电极（71）和第二电极（72），所述第一和第二电极彼此分离;以及导电有机薄膜（73），用于电连接所述第一和 第二电极。 导电性有机薄膜（73）具有第一电气状态，其呈现第一电阻，第二电气状态呈现出第二电阻。 用于从第一电状态转换到第二电状态的第一阈值电压和用于从第二电状态转换到第一电状态的第二阈值电压彼此不同，并且第一电状态或 第二电状态保持在第一阈值电压和第二阈值电压之间的范围内的电压。

公开(公告)号：US06593000B2

公开(公告)日：2003-07-15

申请号：US10058220

申请日：2002-01-29

申请人： Tadashi Ohtake ,  Norihisa Mino ,  Kazufumi Ogawa

发明人： Tadashi Ohtake ,  Norihisa Mino ,  Kazufumi Ogawa

IPC分类号： B32B904

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  Y10T428/261 ,  Y10T428/31504 ,  Y10T428/31663

摘要： A highly dense chemically adsorbed film is formed by repeating the alternate process of adsorption reaction and washing. Adsorption reaction is directed by contacting the substrate surface, which has or is given an alkali metal or a functional group, with a chemical adsorbent, having halosilyl or alkoxysilyl groups at the end of molecules. An unreacted chemical adsorbent is then washed away from the substrate surface. The alternate treatment of adsorption reaction and washing is repeated, thereby covalently bonding a chemically adsorbed film to the substrate surface. As a result, a chemically adsorbed film is formed in which stem molecules are directly or indirectly covalently bonded to the substrate surface via at least one element chosen from the group consisting of Si, Ge, Sn, Ti, Zr, S or C and graft molecules are covalently bonded to at least one element chosen from Si, Ge, Sn, Ti, Zr, S or C via at least one bond chosen from —SiO—, —GeO—, SnO—, —TiO—, ZrO—, —SO2—, —SO— and —C—.

公开(公告)号：US06333074B1

公开(公告)日：2001-12-25

申请号：US09480252

申请日：2000-01-11

申请人： Kazufumi Ogawa ,  Yasuo Takebe ,  Norihisa Mino

发明人： Kazufumi Ogawa ,  Yasuo Takebe ,  Norihisa Mino

IPC分类号： B05D300

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  F28F17/005 ,  F28F2245/02 ,  Y10T428/2936 ,  Y10T428/2995 ,  Y10T428/31663 ,  Y10T428/31678

摘要： By forming a film that comprises a microcrystalline polymer having at least a fluorocarbon group and has a rough surface on a surface of a base material, super-water-repellency is provided, the dew condensation water of an air conditioner, for example, can be easily removed, and the freezing of the fin of the heat exchanger can be prevented. A fin that is made of aluminium is coated with a solution for forming a coating film, in which CF3(CF2)7—(CH2)2—SiCl3 is diluted with nonaqueous cyclohexamethyl trisiloxane at a concentration of 10 vol. % for preparation, to a thickness of 1 to 10 &mgr;m by a brush, and then the cyclohexamethyl trisiloxane is vaporized in an atmosphere having a relative humidity of about 75% at room temperature. CF3(CF2)7—(CH2)2—SiCl3 that remained on the fin is rapidly hydrolyzed with the moisture in the atmosphere, and the moisture in air and a —SiCl3 group dehydrochlorinated to form a microcrystalline polymer on the fin. As a result, a coating film having a surface roughness in the range of 1 to 40 &mgr;m and a contact angle of about 171° to water can be formed.

摘要翻译： 通过形成包含至少具有碳氟化合物基团并且在基材表面上具有粗糙表面的微晶聚合物的膜，提供超疏水性，例如空调的结露水可以是 容易地除去，并且可以防止热交换器的翅片的冻结。 用铝制成的翅片涂覆有形成涂膜的溶液，其中CF 3（CF 2）7 - （CH 2）2 -SiCl 3用10体积浓度的非水性环己甲基三硅氧烷稀释。 制备时，用刷子将其厚度设定为1〜10μm，然后在室温下在相对湿度为约75％的气氛中将环己甲基三硅氧烷蒸发。 残留在翅片上的CF 3（CF 2）7 - （CH 2）2 -SiCl 3随着大气中的水分，空气中的水分和-SiCl 3基团脱氯化氢而迅速水解，从而在翅片上形成微晶聚合物。 结果，可以形成表面粗糙度为1〜40μm，与水接触角为约171°的涂膜。

公开(公告)号：US5869136A

公开(公告)日：1999-02-09

申请号：US12753

申请日：1993-02-03

申请人： Tadashi Ohtake ,  Norihisa Mino ,  Kazufumi Ogawa

发明人： Tadashi Ohtake ,  Norihisa Mino ,  Kazufumi Ogawa

IPC分类号： B05D1/18 ,  C03C23/00 ,  B05D1/36

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  C03C23/00

摘要： A chemically adsorbed multilayer film is formed through the process of replacing a halogen atom on the surface of a chemically adsorbed film with an alkaline metal or changing the halogen atom to a Grignard group by Grignard reaction. This manufacturing method does not disrupt the molecules of the chemically adsorbed film, is easy to perform, low in cost and is safe. After replacing the halogen (for example, Br) on the surface of the film with an alkaline metal such as Li, a condensation reaction including a dealkalihalide reaction is promoted by contacting the chemically adsorbed film with an adsorbent, such as a chemical adsorbent--containing a halosilane group at one end of a molecule--dissolved in a nonaqueous solvent. A chemically adsorbed multilayer film is then formed by reacting the chemically adsorbed film with chemical absorption composition and with water after removing unreacted adsorbents using a nonaqueous solution.

摘要翻译： 通过用碱金属代替化学吸附膜表面上的卤素原子或通过格利雅反应将卤素原子改变成格利雅特基团的方法形成化学吸附的多层膜。 该制造方法不会破坏化学吸附膜的分子，容易实施，成本低，安全。 用Li等碱性金属取代膜表面的卤素（例如Br）后，通过使化学吸附膜与吸附剂（如含化学吸附剂）接触来促进包括脱卤化物反应的缩合反应 分子一端的卤代硅烷基溶解在非水溶剂中。 然后通过使用非水溶液除去未反应的吸附剂，使化学吸附膜与化学吸收组合物和水反应形成化学吸附的多层膜。