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1.发明申请Dental Composite Resin Cement, Dental Primer and Dental Adhesive Kit Containing Them 有权牙科复合树脂水泥，牙科底漆和牙科粘合剂包含它们公开(公告)号：US20090048366A1
公开(公告)日：2009-02-19
申请号：US11815098
申请日：2006-02-03
申请人： Keisuke Torii , Hisaki Tanaka , Toshihide Fujii , Yoshiaki Kohro , Mikito Deguti
发明人： Keisuke Torii , Hisaki Tanaka , Toshihide Fujii , Yoshiaki Kohro , Mikito Deguti
CPC分类号： A61K6/0091 , A61K6/0023 , A61K6/0029 , A61K6/083 , C08L33/00 , C08L31/04 , C08L25/04
摘要： The present invention provides a dental resin cement which is excellent in a mechanical strength, workability and storage stability, and a dental primer which significantly improves adhesiveness of the dental resin cement both to enamel and dentin of a tooth. According to the present invention, a salt of barbituric acid is used as a polymerization initiator in the dual-cure two-paste type dental resin cement being excellent in workability and storage stability to improve the storage stability, and a primer containing barbituric acid and amine is applied to a surface of a tooth to significantly improve adhesiveness of the dental resin cement both to enamel and dentin of teeth.
摘要翻译： 本发明提供了一种牙科用树脂水泥，其机械强度，加工性和保存稳定性优异，牙科底漆可显着提高牙科用树脂水泥与牙釉质和牙本质的粘合性。 根据本发明，在双重固化双糊型牙科用树脂水泥中使用巴比妥酸盐作为聚合引发剂，其加工性和储存稳定性优异，以提高储存稳定性，含有巴比妥酸和胺的底漆 施加到牙齿的表面以显着提高牙科用树脂水泥对牙釉质和牙本质的粘附性。
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2.发明授权Dental composite resin cement, dental primer and dental adhesive kit containing them 有权牙科复合树脂水泥，牙科底漆和含有它们的牙科粘合剂套件公开(公告)号：US07879924B2
公开(公告)日：2011-02-01
申请号：US11815098
申请日：2006-02-03
申请人： Keisuke Torii , Hisaki Tanaka , Toshihide Fujii , Yoshiaki Kohro , Mikito Deguti
发明人： Keisuke Torii , Hisaki Tanaka , Toshihide Fujii , Yoshiaki Kohro , Mikito Deguti
CPC分类号： A61K6/0091 , A61K6/0023 , A61K6/0029 , A61K6/083 , C08L33/00 , C08L31/04 , C08L25/04
摘要： The present invention provides a dental resin cement which is excellent in a mechanical strength, workability and storage stability, and a dental primer which significantly improves adhesiveness of the dental resin cement both to enamel and dentin of a tooth. According to the present invention, a salt of barbituric acid is used as a polymerization initiator in the dual-cure two-paste type dental resin cement being excellent in workability and storage stability to improve the storage stability, and a primer containing barbituric acid and amine is applied to a surface of a tooth to significantly improve adhesiveness of the dental resin cement both to enamel and dentin of teeth.
摘要翻译： 本发明提供了一种牙科用树脂水泥，其机械强度，加工性和保存稳定性优异，牙科底漆可显着提高牙科用树脂水泥与牙釉质和牙本质的粘合性。 根据本发明，在双重固化双糊型牙科用树脂水泥中使用巴比妥酸盐作为聚合引发剂，其加工性和储存稳定性优异，以提高储存稳定性，含有巴比妥酸和胺的底漆 施加到牙齿的表面以显着提高牙科用树脂水泥对牙釉质和牙本质的粘附性。
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公开(公告)号：US20090301346A1
公开(公告)日：2009-12-10
申请号：US12448049
申请日：2006-12-06
IPC分类号： A61K6/02
CPC分类号： A61K6/0023 , A61K6/0017 , A61K6/083 , A61K6/09 , C08L33/04 , C08L75/16
摘要： The present invention provides a dental resin cement composition comprising at least two kinds of pastes, one kind of a paste comprising (a) 20 to 50 parts by weight of a polymerizable monomer composition and (b) 50 to 80 parts by weight of a filler consisting of an inorganic compound, or an organic composite comprising an inorganic compound, amounts of (a) and (b) being based on conversion of 100 parts by weight of the dental resin-based cement composition paste, and the filler (b) comprising (c) 2.0 to 10.0 parts by weight of fine silica particles based on the above conversion, and having (d) a yield viscosity of from 100 to 3,000 [Pa·s], and (e) a thixotropy index of 3.0 or more; and another kind of a paste having the same constituent features (a) to (c) and (e) except that the paste has (d) a yield viscosity of from 70 to 4,000 [Pa·s], wherein upon use, the at least two kinds of pastes are used by mixing them.
摘要翻译： 本发明提供一种牙科用树脂水泥组合物，其包含至少两种糊剂，一种糊剂，其包含（a）20至50重量份的可聚合单体组合物和（b）50至80重量份的填料 由无机化合物或包含无机化合物的有机复合物组成，（a）和（b）的量是基于100重量份的基于牙科树脂的水泥组合物糊料的转化率和填料（b），其包含 （c）基于上述转化率为2.0至10.0重量份的二氧化硅微粒，并且（d）100至3,000 [Pa.s]的屈服粘度，和（e）触变指数为3.0以上; 和具有相同组成特征（a）至（c）和（e）的另一种糊状物，不同之处在于糊料具有（d）70至4,000 [Pa.s]的屈服粘度，其中在使用时， 混合使用最少两种糊剂。
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公开(公告)号：US20100010115A1
公开(公告)日：2010-01-14
申请号：US12318099
申请日：2008-12-22
IPC分类号： A61K6/083
CPC分类号： C09J143/02 , A61K6/083 , A61K6/087 , C09J2201/61 , C08L33/00 , C08L63/00
摘要： The present invention provides a dental self-adhesive resin cement having clinically-acceptable adherability for various adherends without pre-treatment with primers. Specifically, there is provided the dental self-adhesive composite resin cement comprising: (a) a radical polymerizable monomer, (b) a polymerizable monomer having a phosphonic acid group and/or a phosphoric acid ester group, (c) a polymerizable monomer having a dibasic acid carboxyl group, (d) a filler, and (e) a polymerization catalyst.
摘要翻译： 本发明提供了一种具有临床上可接受的粘附性的牙科自粘性树脂粘合剂，而不用引物进行预处理。 具体地说，提供了一种牙科用自粘合复合树脂胶泥，其包含：（a）自由基聚合性单体，（b）具有膦酸基和/或磷酸酯基的聚合性单体，（c） 二元酸羧基，（d）填料和（e）聚合催化剂。
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公开(公告)号：US08183306B2
公开(公告)日：2012-05-22
申请号：US12318099
申请日：2008-12-22
IPC分类号： A61K6/08
CPC分类号： C09J143/02 , A61K6/083 , A61K6/087 , C09J2201/61 , C08L33/00 , C08L63/00
摘要： The present invention provides a dental self-adhesive resin cement having clinically-acceptable adherability for various adherends without pre-treatment with primers. Specifically, there is provided the dental self-adhesive composite resin cement comprising: (a) a radical polymerizable monomer, (b) a polymerizable monomer having a phosphonic acid group and/or a phosphoric acid ester group, (c) a polymerizable monomer having a dibasic acid carboxyl group, (d) a filler, and (e) a polymerization catalyst.
摘要翻译： 本发明提供了一种具有临床上可接受的粘附性的牙科自粘性树脂粘合剂，而不用引物进行预处理。 具体地说，提供了一种牙科用自粘合复合树脂胶泥，其包含：（a）自由基聚合性单体，（b）具有膦酸基和/或磷酸酯基的聚合性单体，（c） 二元酸羧基，（d）填料和（e）聚合催化剂。
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公开(公告)号：US20100101453A1
公开(公告)日：2010-04-29
申请号：US12585974
申请日：2009-09-30
IPC分类号： A61K6/00
CPC分类号： C09J163/00 , A61C2202/00 , A61C2202/01 , A61K6/0029 , C08G77/20 , C08L83/04
摘要： Disclosed is a one-pack type dental adhesive composition comprising: (a) 1.0 to 40.0 parts by weight of a silane coupling agent, (b) 0.01 to 0.4 part by weight of a weak acidic compound which is at least one of organic acid, boric acid and silicic acid, and has an acid dissociation exponent pKa of 3 or more in the form of an aqueous solution, (c) 0.01 to 0.4 part by weight of a strong acidic compound which is at least one of HF, HCl, HBr, HI, HNO3, HClO3, HClO4, HBrO4, HMnO4, H2SO4 and H3PO4 and has an acid dissociation exponent pKa of less than 3, (d) 0.1 to 5.0 part by weight of water, and (e) 20.0 to 99.0 parts by weight of a volatile organic solvent.
摘要翻译： 公开了一种单组分型牙科粘合剂组合物，其包含：（a）1.0至40.0重量份的硅烷偶联剂，（b）0.01至0.4重量份的弱酸性化合物，其为有机酸， 硼酸和硅酸，并且酸溶解指数pKa为水溶液形式的3或更多，（c）0.01至0.4重量份的强酸性化合物，其为HF，HCl，HBr中的至少一种 ，HI，HNO 3，HClO 3，HClO 4，HBrO 4，HMnO 4，H 2 SO 4和H 3 PO 4，并且具有小于3的酸解离指数pKa，（d）0.1至5.0重量份的水，和（e）20.0至99.0重量份 的挥发性有机溶剂。
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公开(公告)号：US20090076182A1
公开(公告)日：2009-03-19
申请号：US12230225
申请日：2008-08-26
CPC分类号： A61K6/0023 , A61K6/083 , A61K6/093 , C08L33/10 , C08L83/10
摘要： An object of the present invention is to provide a one-pack type dental adhesive composition which can exhibit excellent adhesion to any material, for example, dental ceramics, organic composites containing inorganic compounds, dental noble metals and dental non-noble metals, and also has excellent storage stability.Disclosed is a one-pack type dental adhesive composition comprising a silane coupling agent as a component (a), an acidic group-containing polymerizable monomer as a component (b), a sulfur atom-containing polymerizable monomer as a component (d), and other components.
摘要翻译： 本发明的目的是提供一种能够对任何材料，例如牙科陶瓷，含有无机化合物的有机复合物，牙科贵金属和牙科非贵金属的材料表现出优异粘合性的单组分型牙科粘合剂组合物，以及 具有优良的储存稳定性。 公开了一种单组分型牙科粘合剂组合物，其包含作为组分（a）的硅烷偶联剂，作为组分（b）的含酸性基团的可聚合单体，作为组分（d）的含硫原子的可聚合单体） 和其他组件。
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8.发明授权Single component dental composition containing silane coupling agent and acidic group containing polymerizable monomer 有权含有硅烷偶联剂和含酸性基团的可聚合单体的单组分牙科组合物公开(公告)号：US08158694B2
公开(公告)日：2012-04-17
申请号：US13008174
申请日：2011-01-18
CPC分类号： A61K6/0023 , A61K6/083 , C08L33/04 , C08L43/02
摘要： The present invention provides a one-component dental adhesive composition which can exhibit excellent adhesion to both materials of a dental ceramics and an organic composite containing an inorganic compound, and is excellent in can-stability. More particularly, the present invention provides a one-component dental adhesive composition comprising 1 to 60 parts by weight of (a) a silane coupling agent, 1.0 to 20.0 parts by weight based on 100 parts by weight of the (a) component of (b) an acidic group-containing polymerizable monomer, and 28 to 99 parts by weight of (c) a volatile organic solvent.
摘要翻译： 本发明提供一种能够对牙科用陶瓷材料和含有无机化合物的有机复合材料的粘合性优异的单组分牙科用粘合剂组合物，其稳定性优异。 更具体地，本发明提供了一种单组分牙科粘合剂组合物，其包含1至60重量份的（a）硅烷偶联剂，基于100重量份的（a）（a）成分 b）含酸性基团的可聚合单体和28至99重量份的（c）挥发性有机溶剂。
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9.发明申请Single-Component dental composition containing silane coupling agent and acidic group-containing polymerizable monomer 审中-公开含有硅烷偶联剂和含酸性基团的可聚合单体的单组分牙科组合物公开(公告)号：US20100069524A1
公开(公告)日：2010-03-18
申请号：US12312243
申请日：2007-11-02
CPC分类号： A61K6/0023 , A61K6/083 , C08L33/04 , C08L43/02
摘要： The present invention provides a one-component dental adhesive composition which can exhibit excellent adhesion to both materials of a dental ceramics and an organic composite containing an inorganic compound, and is excellent in can-stability. More particularly, the present invention provides a one-component dental adhesive composition comprising 1 to 60 parts by weight of (a) a silane coupling agent, 1.0 to 20.0 parts by weight based on 100 parts by weight of the (a) component of (b) an acidic group-containing polymerizable monomer, and 28 to 99 parts by weight of (c) a volatile organic solvent.
摘要翻译： 本发明提供一种能够对牙科用陶瓷材料和含有无机化合物的有机复合材料的粘合性优异的单组分牙科用粘合剂组合物，其稳定性优异。 更具体地，本发明提供了一种单组分牙科粘合剂组合物，其包含1至60重量份的（a）硅烷偶联剂，基于100重量份的（a）（a）成分 b）含酸性基团的可聚合单体和28至99重量份的（c）挥发性有机溶剂。
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公开(公告)号：US08029613B2
公开(公告)日：2011-10-04
申请号：US12585974
申请日：2009-09-30
CPC分类号： C09J163/00 , A61C2202/00 , A61C2202/01 , A61K6/0029 , C08G77/20 , C08L83/04
摘要： Disclosed is a one-pack type dental adhesive composition comprising: (a) 1.0 to 40.0 parts by weight of a silane coupling agent, (b) 0.01 to 0.4 part by weight of a weak acidic compound which is at least one of organic acid, boric acid and silicic acid, and has an acid dissociation exponent pKa of 3 or more in the form of an aqueous solution, (c) 0.01 to 0.4 part by weight of a strong acidic compound which is at least one of HF, HCl, HBr, HI, HNO3, HClO3, HClO4, HBrO4, HMnO4, H2SO4 and H3PO4 and has an acid dissociation exponent pKa of less than 3, (d) 0.1 to 5.0 part by weight of water, and (e) 20.0 to 99.0 parts by weight of a volatile organic solvent.
摘要翻译： 公开了一种单组分型牙科粘合剂组合物，其包含：（a）1.0至40.0重量份的硅烷偶联剂，（b）0.01至0.4重量份的弱酸性化合物，其为有机酸， 硼酸和硅酸，并且酸溶解指数pKa为水溶液形式的3或更多，（c）0.01至0.4重量份的强酸性化合物，其为HF，HCl，HBr中的至少一种 ，HI，HNO 3，HClO 3，HClO 4，HBrO 4，HMnO 4，H 2 SO 4和H 3 PO 4，并且具有小于3的酸解离指数pKa，（d）0.1至5.0重量份的水，和（e）20.0至99.0重量份 的挥发性有机溶剂。
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