公开(公告)号：US07531588B2

公开(公告)日：2009-05-12

申请号：US10918828

申请日：2004-08-13

申请人： Keith J. Weller ,  Lesley Hwang ,  Richard W. Cruse ,  Leda Gonzalez ,  Robert J. Pickwell ,  Martin Hofstetter ,  Wesley E. Sloan ,  Prashant G. Joshi

发明人： Keith J. Weller ,  Lesley Hwang ,  Richard W. Cruse ,  Leda Gonzalez ,  Robert J. Pickwell ,  Martin Hofstetter ,  Wesley E. Sloan ,  Prashant G. Joshi

IPC分类号： C08K5/24 ,  C07F7/04

CPC分类号： C08K5/5425 ,  C07F7/1804 ,  C08K5/5406 ,  C08L21/00

摘要： Silane compositions of the general formula are provided herein comprising [(RO)x(R1)(3-x)—Si-Mt]q-L-[(Ra)cAr—(CR2═CR22)y]z wherein R and R1 are independently a hydrocarbon group of from 1 to about 20 carbon atoms; R2 are each independently hydrogen or a hydrocarbon group of from 1 to about 20 carbon atoms; M optionally is a divalent hydrocarbon connecting group of from 1 to about 20 carbon atoms to link the silicon atom and the L group; L is a covalently bound hydrocarbon linking group of from 1 to about 20 carbon atoms or a heteroatom linking group selected from the group consisting of —O—, —S—, —NR3— wherein R3 is hydrogen or a hydrocarbon group of from 1 to about 20 carbon atoms; Ra is an alkyl group of 1 to 12 carbon atoms; Ar is a substituted or unsubstituted aromatic group; q is an integer of 1 to 4; t and c are each independently 0 or 1; and x, y and z are each independently integers of 1 to 3, inclusive, with the proviso that t is 1 when L is a heteroatom group. Also provided are processes for preparing the silane compositions and rubber composition comprising the silane compositions.

摘要翻译： 本文提供的硅烷组合物包括<？in-line-formula description =“In-line Formulas”end =“lead”？> [（RO）x（R1）（3-x）-Si-Mt] qL- [（Ra）cAr-（CR2-CR22）y] z <βin-line-formula description =“In-line Formulas”end =“tail”？>其中R和R 1独立地为1 至约20个碳原子; R 2各自独立地为氢或1〜约20个碳原子的烃基; M任选是1至约20个碳原子的连接硅原子和L基团的二价烃连接基团; L是共价键合的1至约20个碳原子的烃连接基团或选自-O - ， - S - ， - NR 3 - 的杂原子连接基团，其中R 3是氢或1〜 约20个碳原子; Ra是1〜12个碳原子的烷基; Ar是取代或未取代的芳基; q为1〜4的整数， t和c各自独立地为0或1; 并且x，y和z各自独立地为1〜3的整数，条件是当L为杂原子基团时，t为1。 还提供了制备包含硅烷组合物的硅烷组合物和橡胶组合物的方法。

公开(公告)号：US20060281841A1

公开(公告)日：2006-12-14

申请号：US10918828

申请日：2004-08-13

申请人： Keith Weller ,  Lesley Hwang ,  Richard Cruse ,  Leda Gonzalez ,  Robert Pickwell ,  Martin Hofstetter ,  Wesley Sloan ,  Prashant Joshi

发明人： Keith Weller ,  Lesley Hwang ,  Richard Cruse ,  Leda Gonzalez ,  Robert Pickwell ,  Martin Hofstetter ,  Wesley Sloan ,  Prashant Joshi

IPC分类号： C08K5/24

CPC分类号： C08K5/5425 ,  C07F7/1804 ,  C08K5/5406 ,  C08L21/00

摘要： Silane compositions of the general formula are provided herein comprising [(RO)x(R1)(3-x)—Si-Mt]q-L-[(Ra)cAr—(CR2═CR22)y]z wherein R and R1 are independently a hydrocarbon group of from 1 to about 20 carbon atoms; R2 are each independently hydrogen or a hydrocarbon group of from 1 to about 20 carbon atoms; M optionally is a divalent hydrocarbon connecting group of from 1 to about 20 carbon atoms to link the silicon atom and the L group; L is a covalently bound hydrocarbon linking group of from 1 to about 20 carbon atoms or a heteroatom linking group selected from the group consisting of —O—, —S—, —NR3— wherein R3 is hydrogen or a hydrocarbon group of from 1 to about 20 carbon atoms; Ra is an alkyl group of 1 to 12 carbon atoms; Ar is a substituted or unsubstituted aromatic group; q is an integer of 1 to 4; t and c are each independently 0 or 1; and x, y and z are each independently integers of 1 to 3, inclusive, with the proviso that t is 1 when L is a heteroatom group. Also provided are processes for preparing the silane compositions and rubber composition comprising the silane compositions.

摘要翻译： 本文提供了通式的硅烷组合物，其包含<？in-line-formula description =“In-line Formulas”end =“lead”→>（（R））x（R 1） （3-x）-Si-M （CR 2）2 - （CR 2）2 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 其中R 1和R 2独立地为下式的烃基：其中R 1，R 2，R 3， 1至约20个碳原子; R 2各自独立地为氢或1至约20个碳原子的烃基; M任选是1至约20个碳原子的连接硅原子和L基团的二价烃连接基团; L是共价键合的1至约20个碳原子的烃连接基团或选自-O - ， - S - ， - NR 3 - 的杂原子连接基团，其中R 0 > 3是氢或1至约20个碳原子的烃基; R a是1至12个碳原子的烷基; Ar是取代或未取代的芳基; q为1〜4的整数， t和c各自独立地为0或1; 并且x，y和z各自独立地为1〜3的整数，条件是当L为杂原子基团时，t为1。 还提供了制备包含硅烷组合物的硅烷组合物和橡胶组合物的方法。