Oxynitride glass-ceramics
    6.
    发明授权
    Oxynitride glass-ceramics 失效
    氧氮化物玻璃陶瓷

    公开(公告)号:US4141739A

    公开(公告)日:1979-02-27

    申请号:US896355

    申请日:1978-04-14

    IPC分类号: C03C3/11 C03C10/00 C03C3/22

    CPC分类号: C03C3/111 C03C10/0009

    摘要: The instant invention is directed to the production of glass-ceramic articles from thermally crystallizable glass compositions containing, by weight, about 40-85% SiO.sub.2 and 2.5-17% N as basic constituents and utilizing such modifiers as the alkali metals, the elements of Groups IIA and IIB of the Periodic Table, boron, and aluminum to obtain practical glass-forming compositions. In general, at N contents greater than about 3.5%, the predominant crystal phase developed in situ will customarily comprise "nitrogen mullite", silicon oxynitride (Si.sub.2 ON.sub.2), and/or .beta.'--Si.sub.3 N.sub.4 solid solution. The crystal phase which has been denominated in the literature as "nitrogen-mullite" has a lath-like morphology and, hence, is useful in reinforcing the crystalline body. Where the predominant crystal phase comprises a silicate, it is believed that nitrogen is present in some manner within the silicate crystal structure. The parent thermally crystallizable glasses appear to be self-nucleating, i.e., the addition of a conventional nucleating agent such as TiO.sub.2, ZrO.sub.2, or SnO.sub.2 is not required to cause crystallization in situ. It is postulated that N may function as a nucleating agent.

    摘要翻译: 本发明涉及从可热结晶的玻璃组合物中制备玻璃陶瓷制品,该玻璃组合物含有约40-85%的SiO 2和2.5-17%的N作为碱性组分,并且利用这种改性剂作为碱金属, 元素周期表IIA和IIB族,硼和铝,以获得实用的玻璃形成组合物。 通常,在大于约3.5%的N含量下,原位显影的主要结晶相通常包含“氮莫来石”,氮氧化硅(Si 2 ON 2)和/或β'-Si 3 N 4固溶体。 在文献中称为“氮 - 莫来石”的结晶相具有板条形态,因此可用于增强结晶体。 当主要结晶相包含硅酸盐时,认为氮以某种方式存在于硅酸盐晶体结构内。 母体热可结晶玻璃似乎是自成核的,即不需要加入常规的成核剂如TiO 2,ZrO 2或SnO 2以引起原位结晶。 假设N可以作为成核剂起作用。

    Silica-alumina-nitrogen containing glasses for production of
glass-ceramics
    7.
    发明授权
    Silica-alumina-nitrogen containing glasses for production of glass-ceramics 失效
    用于生产玻璃陶瓷的二氧化硅 - 氧化铝 - 含氮玻璃

    公开(公告)号:US4097295A

    公开(公告)日:1978-06-27

    申请号:US843872

    申请日:1977-10-20

    CPC分类号: C03C3/111 C03C10/0009

    摘要: The instant invention is directed to the production of glass-ceramic articles from thermally crystallizable glass compositions containing, by weight, about 40-85% SiO.sub.2 and 2.5-17% N as basic constituents and utilizing such modifiers as the alkali metals, the elements of Groups IIA and IIB of the Periodic Table, boron, and aluminum to obtain practical glass-forming compositions. In general, at N contents greater than about 3.5%, the predominant crystal phase developed in situ will customarily comprise "nitrogen mullite," silicon oxynitride (Si.sub.2 ON.sub.2), and/or .beta.'-Si.sub.3 N.sub.4 solid solution. The crystal phase which has been denominated in the literature as "nitrogen-mullite" has a lath-like morphology and, hence, is useful in reinforcing the crystalline body. Where the predominant crystal phase comprises a silicate, it is believed that nitrogen is present in some manner within the silicate crystal structure. The parent thermally crystallizable glasses appear to be self-nucleating, i.e., the addition of a conventional nucleating agent such as TiO.sub.2, ZrO.sub.2, or SnO.sub.2 is not required to cause crystallization in situ. It is postulated that N may function as a nucleating agent.

    摘要翻译: 本发明涉及从可热结晶的玻璃组合物中制备玻璃陶瓷制品,该玻璃组合物含有约40-85%的SiO 2和2.5-17%的N作为碱性组分,并且利用这种改性剂作为碱金属, 元素周期表IIA和IIB族,硼和铝,以获得实用的玻璃形成组合物。 通常,在大于约3.5%的N含量下,原位显影的主要结晶相通常包含“氮富铝红柱石”,氮氧化硅(Si2ON2)和/或β'-Si3N4固溶体。 在文献中称为“氮 - 莫来石”的结晶相具有板条形态,因此可用于增强结晶体。 当主要结晶相包含硅酸盐时,认为氮以某种方式存在于硅酸盐晶体结构内。 母体热可结晶玻璃似乎是自成核的,即不需要加入常规的成核剂如TiO 2,ZrO 2或SnO 2以引起原位结晶。 假设N可以作为成核剂起作用。

    Preparation of oxynitride glass-ceramics
    8.
    发明授权
    Preparation of oxynitride glass-ceramics 失效
    氮氧化物玻璃陶瓷的制备

    公开(公告)号:US4222760A

    公开(公告)日:1980-09-16

    申请号:US63151

    申请日:1979-08-02

    摘要: The instant invention is directed to the production of glass-ceramic articles from thermally crystallizable glass compositions containing, by weight, about 40-85% SiO.sub.2 and 2.5-17% N as basic constituents and utilizing such modifiers as the alkali metals, the elements of Groups IIA and IIB of the Periodic Table, boron, and aluminum to obtain practical glass-forming compositions. In general, at N contents greater than about 3.5%, the predominant crystal phase developed in situ will customarily comprise "nitrogen mullite", silicon oxynitride (Si.sub.2 ON.sub.2), and/or .beta.'-Si.sub.3 N.sub.4 solid solution. The crystal phase which has been denominated in the literature as "nitrogen-mullite" has a lath-like morphology and, hence, is useful in reinforcing the crystalline body. Where the predominant crystal phase comprises a silicate, it is believed that nitrogen is present in some manner within the silicate crystal structure. The parent thermally crystallizable glasses appear to be self-nucleating, i.e., the addition of a conventional nucleating agent such as TiO.sub.2, ZrO.sub.2, or SnO.sub.2 is not required to cause crystallization in situ. It is postulated that N may function as a nucleating agent.

    摘要翻译: 本发明涉及从可热结晶的玻璃组合物中制备玻璃陶瓷制品,该组合物含有约40-85%的SiO 2和2.5-17%的N作为碱性组分,并且利用这种改性剂作为碱金属, 元素周期表IIA和IIB族,硼和铝,以获得实用的玻璃形成组合物。 通常,在大于约3.5%的N含量下,原位显影的主要结晶相通常包含“氮莫来石”,氮氧化硅(Si 2 ON 2)和/或β'-Si 3 N 4固溶体。 在文献中称为“氮 - 莫来石”的结晶相具有板条形态,因此可用于增强结晶体。 当主要结晶相包含硅酸盐时,认为氮以某种方式存在于硅酸盐晶体结构内。 母体热可结晶玻璃似乎是自成核的,即不需要加入常规的成核剂如TiO 2,ZrO 2或SnO 2以引起原位结晶。 假设N可以作为成核剂起作用。

    Oxynitride glass-ceramics
    9.
    发明授权
    Oxynitride glass-ceramics 失效
    氧氮化物玻璃陶瓷

    公开(公告)号:US4186021A

    公开(公告)日:1980-01-29

    申请号:US966193

    申请日:1978-12-04

    IPC分类号: C03C3/11 C03C10/00 C03C3/22

    CPC分类号: C03C10/0009 C03C3/111

    摘要: The instant invention is directed to the production of glass-ceramic articles from thermally crystallizable glass compositions containing, by weight, about 40-85% SiO.sub.2 and 2.5-17% N as basic constituents and utilizing such modifiers as the alkali metals, the elements of Groups IIA and IIB of the Periodic Table, boron, and aluminum to obtain practical glass-forming compositions. In general, at N contents greater than about 3.5%, the predominant crystal phase developed in situ will customarily comprise "nitrogen mullite", silicon oxynitride (Si.sub.2 ON.sub.2), and/or .beta.'-Si.sub.3 N.sub.4 solid solution. The crystal phase which has been denominated in the literature as "nitrogen-mullite" has a lath-like morphology and, hence, is useful in reinforcing the crystalline body. Where the predominant crystal phase comprises a silicate, it is believed that nitrogen is present in some manner within the silicate crystal structure. The parent thermally crystallizable glasses appear to be self-nucleating, i.e., the addition of a conventional nucleating agent such as TiO.sub.2, ZrO.sub.2, or SnO.sub.2 is not required to cause crystallization in situ. It is postulated that N may function as a nucleating agent.

    摘要翻译: 本发明涉及从可热结晶的玻璃组合物中制备玻璃陶瓷制品,该组合物含有约40-85%的SiO 2和2.5-17%的N作为碱性组分,并且利用这种改性剂作为碱金属, 元素周期表IIA和IIB族,硼和铝,以获得实用的玻璃形成组合物。 通常,在大于约3.5%的N含量下,原位显影的主要结晶相通常包含“氮莫来石”,氮氧化硅(Si 2 ON 2)和/或β'-Si 3 N 4固溶体。 在文献中称为“氮 - 莫来石”的结晶相具有板条形态,因此可用于增强结晶体。 当主要结晶相包含硅酸盐时,认为氮以某种方式存在于硅酸盐晶体结构内。 母体热可结晶玻璃似乎是自成核的,即不需要加入常规的成核剂如TiO 2,ZrO 2或SnO 2以引起原位结晶。 假设N可以作为成核剂起作用。

    SiO.sub.2 -Al.sub.2 O.sub.3 -N glass for production of oxynitride
glass-ceramics
    10.
    发明授权
    SiO.sub.2 -Al.sub.2 O.sub.3 -N glass for production of oxynitride glass-ceramics 失效
    用于生产氮氧化物玻璃陶瓷的SiO {HD 2 {B-Al {hd 2 {b O {HD 3 {B -N glass

    公开(公告)号:US4070198A

    公开(公告)日:1978-01-24

    申请号:US735313

    申请日:1976-10-26

    CPC分类号: C03C10/0009 C03C3/111

    摘要: The instant invention is directed to the production of glass-ceramic articles from thermally crystallizable glass compositions containing, by weight, about 40-85% SiO.sub.2 and 2.5-17% N as basic constituents and utilizing such modifiers as the alkali metals, the elements of Groups IIA and IIB of the Periodic Table, boron, and aluminum to obtain practical glass-forming compositions. In general, at N contents greater than about 3.5%, the predominant crystal phase developed in situ will customarily comprise "nitrogen mullite", silicon oxynitride (Si.sub.2 ON.sub.2), and/or .beta.'-Si.sub.3 N.sub.4 solid solution. The crystal phase which has been denominated in the literature as "nitrogen-mullite" has a lath-like morphology and, hence, is useful in reinforcing the crystalline body. Where the predominant crystal phase comprises a silicate, it is believed that nitrogen is present in some manner within the silicate crystal structure. The parent thermally crystallizable glasses appear to be self-nucleating, i.e., the addition of a conventional nucleating agent such as TiO.sub.2, ZrO.sub.2, or SnO.sub.2 is not required to cause crystallization in situ. It is postulated that N may function as a nucleating agent.

    摘要翻译: 本发明涉及从可热结晶的玻璃组合物中制备玻璃陶瓷制品,该组合物含有约40-85%的SiO 2和2.5-17%的N作为碱性组分,并且利用这种改性剂作为碱金属, 元素周期表IIA和IIB族,硼和铝,以获得实用的玻璃形成组合物。 通常,在大于约3.5%的N含量下,原位显影的主要结晶相通常包含“氮莫来石”,氮氧化硅(Si 2 ON 2)和/或β'-Si 3 N 4固溶体。 在文献中称为“氮 - 莫来石”的结晶相具有板条形态,因此可用于增强结晶体。 当主要结晶相包含硅酸盐时,认为氮以某种方式存在于硅酸盐晶体结构内。 母体热可结晶玻璃似乎是自成核的,即不需要加入常规的成核剂如TiO 2,ZrO 2或SnO 2以引起原位结晶。 假设N可以作为成核剂起作用。