Process for making a pressure fog-resistant photographic element
    1.
    发明授权
    Process for making a pressure fog-resistant photographic element 失效
    制造耐压摄影元件的工艺

    公开(公告)号:US5168035A

    公开(公告)日:1992-12-01

    申请号:US634449

    申请日:1990-12-27

    IPC分类号: G03C1/015 G03C1/035

    摘要: A method for controlling pressure-induced fog in a silver bromide photographic material involves surface treatment of the emulsion AgBr grains with thiocyanate and an iodide salt. In particular, a process for making a pressure fog-resistant photographic emulsion includes steps of forming a photographic emulsion containing cubic or cubooctahedral silver bromide grains, surface-treating the AgBr grains with a thiocyanate by adding the thiocyanate to the emulsion, chemically sensitizing the emulsion, maintaining the emulsion at a temperature and for a time sufficient to allow the thiocyanate to react with the grain surfaces, and then surface-treating the AgBr grains with an iodide salt by adding the salt to the emulsion in an amount and under conditions effective to fill in cubic faces of the AgBr grains. The latter step partially or fully converts the AgBr grains to octahedral grains. A photographic element can then be made by coating the emulsion on a suitable base.

    摘要翻译: 在溴化银照相材料中控制压力引起的雾的方法包括用硫氰酸盐和碘化物盐对乳液AgBr颗粒进行表面处理。 特别地,制造耐压雾照相乳剂的方法包括形成含有立方或立方八面体溴化银颗粒的照相乳剂的步骤,用硫氰酸盐将硫氰酸盐加入到乳液中,对乳液进行表面处理,使乳液化学增感 将乳液保持在足以允许硫氰酸盐与颗粒表面反应的温度和时间,然后用碘盐将表面处理AgBr颗粒,通过向该乳液中加入一定量和在有效 填充AgBr颗粒的立方面。 后一步骤部分或全部将AgBr晶粒转化为八面体晶粒。 然后可以通过将乳液涂覆在合适的基底上来制备照相元件。

    Pressure fog-resistant photographic element
    2.
    发明授权
    Pressure fog-resistant photographic element 失效
    耐压防雾照相材料

    公开(公告)号:US5298384A

    公开(公告)日:1994-03-29

    申请号:US955345

    申请日:1992-10-01

    IPC分类号: G03C1/015 G03C1/035

    摘要: A method for controlling pressure-induced fog in a silver bromide photographic material involves surface treatment of the emulsion AgBr grains with thiocyanate and an iodide salt. In particular, a process for making a pressure fog-resistant photographic emulsion includes steps of forming a photographic emulsion containing cubic or cubooctahedral silver bromide grains, surface-treating the AgBr grains with a thiocyanate by adding the thiocyanate to the emulsion, chemically sensitizing the emulsion, maintaining the emulsion at a temperature and for a time sufficient to allow the thiocyanate to react with the grain surfaces, and then surface-treating the AgBr grains with an iodide salt by adding the salt to the emulsion in an amount and under conditions effective to fill in cubic faces of the AgBr grains. The latter step partially or fully converts the AgBr grains to octahedral grains. A photographic element can then be made by coating the emulsion on a suitable base.

    摘要翻译: 在溴化银照相材料中控制压力引起的雾的方法包括用硫氰酸盐和碘化物盐对乳液AgBr颗粒进行表面处理。 特别地,制造耐压雾照相乳剂的方法包括形成含有立方或立方八面体溴化银颗粒的照相乳剂的步骤,用硫氰酸盐将硫氰酸盐加入到乳液中,对乳液进行表面处理,使乳液化学增感 将乳液保持在足以允许硫氰酸盐与颗粒表面反应的温度和时间,然后用碘盐将表面处理AgBr颗粒,通过向该乳液中加入一定量和在有效 填充AgBr颗粒的立方面。 后一步骤部分或全部将AgBr晶粒转化为八面体晶粒。 然后可以通过将乳液涂覆在合适的基底上来制备照相元件。

    Color developer containing hydroxylamine antioxidants
    4.
    发明授权
    Color developer containing hydroxylamine antioxidants 失效
    含有羟胺抗氧化剂的彩色显影剂

    公开(公告)号:US5660974A

    公开(公告)日:1997-08-26

    申请号:US448075

    申请日:1995-05-23

    摘要: A composition for developing a silver halide color photographic material comprising a color developing agent and a hydroxylamine compound represented by Formula I or II: ##STR1## wherein Stab is a stabilizing group such that when the hydroxylamine compound is added to a test developer solution of the following formula the pH of the test developer solution decreases less than 0.12 at an aeration time of 90 hours: TABLE 1 ______________________________________ Developer Formulation Components Quantity/L ______________________________________ Lithium salt of sulfonated 0.25 mL Polystyrene (30% wt/wt Liq) Triethanolamine 11.0 mL Stilbene Stain-Reducing Agent 2.3 g Hydroxylamine compound 0.05 moles Lithium Sulfate 2.7 g 1-Hydroxyethylidene-1-diphosphonic 0.8 mL acid (60% wt/wt Liq) Potassium Chloride 1.8 g Potassium Bromide 0.2 g 4-amino-3-methyl-N-ethyl-N-(.beta.- 4.85 g methanesulfonamidoethyl)aniline (color developer) Potassium Carbonate 25.0 g Water to 1 L solution pH adjusted to 10.12 with KOH ______________________________________ and wherein R is a substituted or unsubstituted alkyl, aryl or heterocyclic group bonded to N by a carbon atom.

    摘要翻译: 用于显影卤化银彩色照相材料的组合物,其包含彩色显影剂和由式I或II表示的羟胺化合物:其中Stab是稳定基团,使得当将羟胺化合物加入到 表1-显影剂配方 - 组分数量/ L - 磺化的锂盐0.25mL - 聚苯乙烯(30%wt /重量/体积比) 重量份Liq) - 三乙醇胺11.0mL - 二苯乙烯染色剂2.3g - 羟胺化合物0.05摩尔 - 硫酸锂2.7g-1-羟基亚乙基-1-二膦酸0.8mL-酸(60%wt / wt Liq) - 氯化钾1.8g - 溴化钾0.2g-4-氨基-3-甲基-N-乙基-N-(β-4.85g-甲磺酰氨基乙基)苯胺 - (显色剂) - 碳酸钾25.0g - 水至1L溶液 - pH调节至10.12 与KOH - 并且其中R为 被碳原子与N键合的取代或未取代的烷基,芳基或杂环基。