摘要:
There is disclosed a light-sensitive silver halide photographic material having at least one silver halide emulsion layer containing silver halide crystal grains which comprises at least one of the silver halide emulsion layer contains silver halide crystal grains which satisfy the following conditions of:(1) composed substantially of silver iodobromide,(2) having a maximum point of a silver iodide content at 67% or less of a distance from the center of the silver halide grain relative to a distance (l.sub.0) from the center of the silver halide grain to the outermost surface thereof,(3) having a minimum point of the silver iodide content at 58% or more of the distance form the center of the silver halide grain relative to l.sub.0 ,(4) substantially monotonously reduced in the silver halide content from the maximum point of the silver halide content to the minimum point thereof, and(5) satisfies the following formula: ##EQU1## wherein l.sub.0 has the same meaning as defined above, l.sub.1 represents a distance of the maximum point of the silver halide content from the center of the silver halide grain and l.sub.2 represents a distance of the minimum point of the silver halide content from the center of the silver halide grain.
摘要:
Process for preparing photographic emulsion comprising bringing aqueous silver and chloride-containing halide salt solutions into contact in the presence of a dispersing medium to form octahedral silver halide grains having a halide content of at least 50 mole percent chloride, based on total moles of silver present, the improvement forming the grains in the presence of a crystal modifying amount of an aminoazapyridine as described in pH range of 2.5 to 9, pCl range of 0 to 3, the aminoazapyridine compound being added after at least about 6% to about 45% of the silver salt solution has been added.The photographic emulsion is useful in x-ray, laser scanner films, as color separation elements and inverse transfer systems, etc.
摘要:
A silver halide color photographic light-sensitive material with a magenta emulsion layer containing a pyrazolotriazole magenta dye-forming coupler and containing an emulsion whose silver chloride content is 98 mol % or more, with a light-insensitive hydrophilic colloidal layer containing a solid fine-particle dispersion of a dye. The magenta emulsion layer is a light-sensitive silver halide emulsion layer most apart from the light-insensitive hydrophilic colloidal layer among all the light-sensitive silver halide emulsion layers. A silver halide color photographic light-sensitive material for cinema, in which light-sensitive silver halide particles have a silver chloride content of 95 mol % or more, a total coated amount of silver is 1.7 g/m2 or less, a thickness of the film on the support on the side of layers containing the light-sensitive silver halide is 12.0 μm or less, and the swelling rate to water is 200% or less. An image-forming method utilizing the silver halide color photographic light-sensitive material for cinema.
摘要翻译:一种卤化银彩色照相感光材料,其具有含有吡唑并三唑品红色染料形成成色剂的品红色乳剂层,并含有氯化银含量为98摩尔%以上的乳液,其中含有固体精细化合物的不透光亲水胶体层, 染料的颗粒分散。 品红乳剂层是在所有感光卤化银乳剂层中与光不敏感的亲水胶体层最相近的感光卤化银乳剂层。 用于电影的卤化银彩色照相感光材料,其中感光卤化银颗粒的氯化银含量为95摩尔%以上,银的总涂布量为1.7g / m 2以下,a 在含有感光卤化银的层一侧的载体上的膜的厚度为12.0μm以下,对水的溶胀率为200%以下。 利用用于电影的卤化银彩色摄影感光材料的图像形成方法。
摘要:
A silver halide photographic emulsion is disclosed, comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide grain contained in the silver halide emulsion layer has a silver chloride content of 50 mol % or more, 30% or more of the surface area of the grain comprises a (111) face, and the silver halide grain is formed in the presence of at least one compound represented by formula (I) and contains a hexacyano complex represented by formula (II) such that the outermost layer of the grain has a hexacyano complex concentration of at least 1.times.10.sup.-4 mol/mol-Ag. ##STR1##
摘要:
The invention is directed to a method for producing a silver halide photographic emulsion comprising the step of reacting a water-soluble silver salt and at least one water-soluble halide salt containing chloride or bromide in aqueous solution in the presence of an organic Grain Growth Modifier (GGM) compound, containing a halide X, which halide is not released in the form of an ion, to form light-sensitive silver halide grains having a silver halide content of a least 50 mole %, said grain growth modifier compound being water-soluble with a solubility>4 mmole per liter, and being selected from the group of compounds with an aliphatic or cyclo-aliphatic backbone R to which is attached one or more halide groups and at least one polar group.
摘要:
Disclosed is a silver halide color photographic light-sensitive material that comprises at least one magenta emulsion layer containing at least one specific pyrazolotriazole magenta dye-forming coupler, in which a silver halide emulsion in the magenta emulsion layer containing the magenta dye-forming coupler comprises a high silver chloride emulsion whose silver chloride content is 98 mol % or more, at least one light-insensitive hydrophilic colloidal layer contains a solid fine-particle dispersion of a dye that has 1 to 7 dissociable hydrogen or group having a dissociable hydrogen, and the magenta emulsion layer containing the magenta dye-forming coupler is a light-sensitive silver halide emulsion layer most apart from the light-insensitive hydrophilic colloidal layer containing the solid fine-particle dispersion of the dye, among all the light-sensitive silver halide emulsion layers. Further, there is disclosed a silver halide color photographic light-sensitive material for cinema, in which light-sensitive silver halide particles in each of a yellow color-forming light-sensitive silver halide emulsion layer, a magenta color-forming light-sensitive silver halide emulsion layer, and a cyan color-forming light-sensitive silver halide emulsion layer, has silver chloride content of 95 mol % or more, the total coated amount of silver is 1.7 g/m2 or less, the thickness of the film on the support on the side of layers containing the light-sensitive silver halide is 12.0 &mgr;m or less, and the swelling rate to water is 200% or less. Further, an image-forming method utilizing the silver halide color photographic light-sensitive material for cinema is also disclosed.
摘要:
A silver halide color photographic material containing at least one coupler compound of the formula (1) in at least one hydrophilic colloid layer which is provided on a support:R.sup.1 OCOCHXCONR.sup.2 R.sup.3 (1)where R.sup.1 represents a branched alkyl group including a cyclic alkyl group and a cyclic alkyl-substituted alkyl group, an aryl group or a heterocyclic group; R.sup.2 represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; R.sup.3 represents an alkyl group, an aryl group or a heterocyclic group; X represents a group which splits off from the coupler compound when the coupler compound is reacted with an oxidation product of an aromatic primary amine developing agent; and R.sup.2 and R.sup.3 may be bonded to each other to form a ring. The coupler has a high dye-forming rate to give a dye having a high color density and a high color fastness. The material has improved sharpness and color fastness and an elevated sensitivity.
摘要:
A method for controlling pressure-induced fog in a silver bromide photographic material involves surface treatment of the emulsion AgBr grains with thiocyanate and an iodide salt. In particular, a process for making a pressure fog-resistant photographic emulsion includes steps of forming a photographic emulsion containing cubic or cubooctahedral silver bromide grains, surface-treating the AgBr grains with a thiocyanate by adding the thiocyanate to the emulsion, chemically sensitizing the emulsion, maintaining the emulsion at a temperature and for a time sufficient to allow the thiocyanate to react with the grain surfaces, and then surface-treating the AgBr grains with an iodide salt by adding the salt to the emulsion in an amount and under conditions effective to fill in cubic faces of the AgBr grains. The latter step partially or fully converts the AgBr grains to octahedral grains. A photographic element can then be made by coating the emulsion on a suitable base.
摘要:
Disclosed is a silver halide color photographic light-sensitive material that comprises at least one magenta emulsion layer containing at least one specific pyrazolotriazole magenta dye-forming coupler, in which a silver halide emulsion in the magenta emulsion layer containing the magenta dye-forming coupler comprises a high silver chloride emulsion whose silver chloride content is 98 mol % or more, at least one light-insensitive hydrophilic colloidal layer contains a solid fine-particle dispersion of a dye that has 1 to 7 dissociable hydrogen or group having a dissociable hydrogen, and the magenta emulsion layer containing the magenta dye-forming coupler is a light-sensitive silver halide emulsion layer most apart from the light-insensitive hydrophilic colloidal layer containing the solid fine-particle dispersion of the dye, among all the light-sensitive silver halide emulsion layers. Further, there is disclosed a silver halide color photographic light-sensitive material for cinema, in which light-sensitive silver halide particles in each of a yellow color-forming light-sensitive silver halide emulsion layer, a magenta color-forming light-sensitive silver halide emulsion layer, and a cyan color-forming light-sensitive silver halide emulsion layer, has silver chloride content of 95 mol % or more, the total coated amount of silver is 1.7 g/m2 or less, the thickness of the film on the support on the side of layers containing the light-sensitive silver halide is 12.0 nullm or less, and the swelling rate to water is 200% or less. Further, an image-forming method utilizing the silver halide color photographic light-sensitive material for cinema is also disclosed.
摘要:
The invention is directed to a method for producing a silver halide photographic emulsion comprising the step of reacting a water-soluble silver salt and at least one water-soluble halide salt containing chloride or bromide in aqueous solution in the presence of an organic Grain Growth Modifier (GGM) compound, containing a halide X, which halide is not released in the form of an ion, to form light-sensitive silver halide grains having a silver halide content of a least 50 mole %, said grain growth modifier compound being water-soluble with a solubility >4 mmole per liter, and being selected from the group of compounds with an aliphatic or cyclo-aliphatic backbone R to which is attached one or more halide groups and at least one polar group.