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    Preparing phosphorus containing alumina support by sol-gel method for fischer-tropsch synthesis and catalyst preparation thereof
    4.
    发明授权
    Preparing phosphorus containing alumina support by sol-gel method for fischer-tropsch synthesis and catalyst preparation thereof 有权
    通过溶胶 - 凝胶法制备含磷氧化铝载体，用于费 - 托合成及其催化剂制备

    公开(公告)号：US08598066B2

    公开(公告)日：2013-12-03

    申请号：US12594695

    申请日：2008-08-06

    申请人： Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee ,  Ki-won Jun

    发明人： Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee ,  Ki-won Jun

    IPC分类号： B01J27/185 ,  B01J27/18

    CPC分类号： B01J27/1853 ,  B01J21/04 ,  B01J23/75 ,  B01J27/16 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/109 ,  B01J37/033 ,  C10G2/33 ,  C10G2/332

    摘要： The present invention relates to a process of preparing of a phosphorus-containing phosphorus-alumina support by a sol-gel method and a cobalt/phosphorus-alumina catalyst where cobalt is supported onto the phosphorus-alumina support as an active ingredient. The phosphorus-alumina support is prepared by a sol-gel method and has wide specific surface area with bimodal pore size distribution and high cobalt dispersion, thereby enabling to increase heat and mass transfer, stabilize the structure by modifying the surface property of alumina and decrease the deactivation rate due to the reduced oxidation of cobalt component during the F-T reaction. When Fischer-Tropsch reaction (F-T) is conducted on the catalyst, the catalyst maintains a superior thermal stability, inhibits the deactivation due to water generation during the F-T reaction and also causes relatively high conversion of carbon monoxide and stable selectivity of liquid hydrocarbons.

    摘要翻译： 本发明涉及一种通过溶胶 - 凝胶法制备含磷磷 - 氧化铝载体的方法和一种钴/磷 - 氧化铝催化剂，其中钴作为活性成分负载在磷 - 氧化铝载体上。 磷 - 氧化铝载体通过溶胶 - 凝胶法制备，具有宽的比表面积，具有双峰孔径分布和高钴分散性，从而能够增加热和质量传递，通过改变氧化铝的表面性能来稳定结构，并减少 由于在FT反应期间钴组分的氧化降低导致的失活速率。 当在催化剂上进行费 - 托反应（F-T）时，催化剂保持优异的热稳定性，抑制在F-T反应期间由于水的产生而失活，并且还导致一氧化碳相对较高的转化率和液体烃的稳定选择性。

    PREPARING PHOSPHORUS CONTAINING ALUMINA SUPPORT BY SOL-GEL METHOD FOR FISCHER-TROPSCH SYNTHESIS AND CATALYST PREPARATION THEREOF
    5.
    发明申请
    PREPARING PHOSPHORUS CONTAINING ALUMINA SUPPORT BY SOL-GEL METHOD FOR FISCHER-TROPSCH SYNTHESIS AND CATALYST PREPARATION THEREOF 有权
    通过溶胶凝胶法制备含有氧化铝的磷化合物，用于FISCHER-TROPSCH合成及其催化剂的制备

    公开(公告)号：US20100130349A1

    公开(公告)日：2010-05-27

    申请号：US12594695

    申请日：2008-08-06

    申请人： Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee ,  Ki-won Jun

    发明人： Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee ,  Ki-won Jun

    IPC分类号： B01J27/185 ,  B01J27/14 ,  B01J21/04 ,  B01J23/75

    CPC分类号： B01J27/1853 ,  B01J21/04 ,  B01J23/75 ,  B01J27/16 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/109 ,  B01J37/033 ,  C10G2/33 ,  C10G2/332

    摘要： The present invention relates to a process of preparing of a phosphorus-containing phosphorus-alumina support by a sol-gel method and a cobalt/phosphorus-alumina catalyst where cobalt is supported onto the phosphorus-alumina support as an active ingredient. The phosphorus-alumina support is prepared by a sol-gel method and has wide specific surface area with bimodal pore size distribution and high cobalt dispersion, thereby enabling to increase heat and mass transfer, stabilize the structure by modifying the surface property of alumina and decrease the deactivation rate due to the reduced oxidation of cobalt component during the F-T reaction. When Fischer-Tropsch reaction (F-T) is conducted on the catalyst, the catalyst maintains a superior thermal stability, inhibits the deactivation due to water generation during the F-T reaction and also causes relatively high conversion of carbon monoxide and stable selectivity of liquid hydrocarbons.

    摘要翻译： 本发明涉及一种通过溶胶 - 凝胶法制备含磷磷 - 氧化铝载体的方法和一种钴/磷 - 氧化铝催化剂，其中钴作为活性成分负载在磷 - 氧化铝载体上。 磷 - 氧化铝载体通过溶胶 - 凝胶法制备，具有宽的比表面积，具有双峰孔径分布和高钴分散性，从而能够增加热和质量传递，通过改变氧化铝的表面性能来稳定结构，并减少 由于在FT反应期间钴组分的氧化降低导致的失活速率。 当在催化剂上进行费 - 托反应（F-T）时，催化剂保持优异的热稳定性，抑制在F-T反应期间由于水的产生而失活，并且还导致一氧化碳相对较高的转化率和液体烃的稳定选择性。

    Catalysts for fischer-tropsch synthesis on cobalt/phosphorus-aluminum oxide and preparation methods thereof
    6.
    发明授权
    Catalysts for fischer-tropsch synthesis on cobalt/phosphorus-aluminum oxide and preparation methods thereof 有权
    钴/磷 - 氧化铝上的费 - 托合成催化剂及其制备方法

    公开(公告)号：US08084387B2

    公开(公告)日：2011-12-27

    申请号：US12594617

    申请日：2008-01-30

    申请人： Ki-won Jun ,  Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee

    发明人： Ki-won Jun ,  Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee

    IPC分类号： B01J27/185 ,  B01J23/40 ,  B01J23/42 ,  B01J23/00 ,  B01J23/08 ,  C01F7/02 ,  C07C27/00 ,  C07C27/06

    CPC分类号： B01J23/75 ,  B01J27/16 ,  B01J27/1853 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/033 ,  B01J37/18 ,  B01J37/28

    摘要： The present invention relates to a cobalt/phosphorus-alumina catalyst in which cobalt is supported as an active component on a phosphorus-alumina support wherein phosphorus is supported on alumina surface. With a bimodal pore structure of pores of relatively different pore sizes, the catalyst provides superior heat- and matter-transfer performance and excellent catalytic reactivity. Especially, when Fischer-Tropsch (F-T) reaction is performed using the catalyst, deactivation by the water produced during the F-T reaction is inhibited and, at the same time, the dispersion and reducing property of cobalt and other active component are improved. Therefore, the cobalt/phosphorus-alumina catalyst for F-T reaction in accordance with the present invention provides good carbon monoxide conversion and stable selectivity for liquid hydrocarbons.

    摘要翻译： 本发明涉及一种钴/磷 - 氧化铝催化剂，其中钴作为活性组分负载在磷 - 氧化铝载体上，其中磷负载在氧化铝表面上。 具有相对不同孔径的孔的双峰孔结构，催化剂提供优异的热和物质转移性能和优异的催化反应性。 特别是当使用催化剂进行费托（F-T）反应时，抑制了F-T反应期间产生的水的失活，同时改善了钴等活性成分的分散还原性。 因此，根据本发明的用于F-T反应的钴/磷 - 氧化铝催化剂提供了良好的一氧化碳转化率和对液体烃的稳定选择性。

    CATALYSTS FOR FISCHER-TROPSCH SYNTHESIS ON COBALT/PHOSPHORUS-ALUMINUM OXIDE AND PREPARATION METHODS THEREOF
    7.
    发明申请
    CATALYSTS FOR FISCHER-TROPSCH SYNTHESIS ON COBALT/PHOSPHORUS-ALUMINUM OXIDE AND PREPARATION METHODS THEREOF 有权
    钴/磷 - 氧化铝合成催化剂及其制备方法

    公开(公告)号：US20100093523A1

    公开(公告)日：2010-04-15

    申请号：US12594617

    申请日：2008-01-30

    申请人： Ki-won Jun ,  Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee

    发明人： Ki-won Jun ,  Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee

    IPC分类号： B01J27/185

    CPC分类号： B01J23/75 ,  B01J27/16 ,  B01J27/1853 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/033 ,  B01J37/18 ,  B01J37/28

    摘要： The present invention relates to a cobalt/phosphorus-alumina catalyst in which cobalt is supported as an active component on a phosphorus-alumina support wherein phosphorus is supported on alumina surface. With a bimodal pore structure of pores of relatively different pore sizes, the catalyst provides superior heat- and matter-transfer performance and excellent catalytic reactivity. Especially, when Fischer-Tropsch (F-T) reaction is performed using the catalyst, deactivation by the water produced during the F-T reaction is inhibited and, at the same time, the dispersion and reducing property of cobalt and other active component are improved. Therefore, the cobalt/phosphorus-alumina catalyst for F-T reaction in accordance with the present invention provides good carbon monoxide conversion and stable selectivity for liquid hydrocarbons.

    摘要翻译： 本发明涉及一种钴/磷 - 氧化铝催化剂，其中钴作为活性组分负载在磷 - 氧化铝载体上，其中磷负载在氧化铝表面上。 具有相对不同孔径的孔的双峰孔结构，催化剂提供优异的热和物质转移性能和优异的催化反应性。 特别是当使用催化剂进行费托（F-T）反应时，抑制了F-T反应期间产生的水的失活，同时改善了钴等活性成分的分散还原性。 因此，根据本发明的用于F-T反应的钴/磷 - 氧化铝催化剂提供了良好的一氧化碳转化率和对液体烃的稳定选择性。

    Method and apparatus for the continuous separation and discharge of solid catalysts and products for Fischer-Tropsch synthesis reactions
    8.
    发明授权
    Method and apparatus for the continuous separation and discharge of solid catalysts and products for Fischer-Tropsch synthesis reactions 有权
    用于费 - 托合成反应的固体催化剂和产物的连续分离和排放的方法和装置

    公开(公告)号：US08852516B2

    公开(公告)日：2014-10-07

    申请号：US12919919

    申请日：2008-12-08

    申请人： Kwang Jae Woo ,  Ki-won Jun ,  Suk-Hwan Kang ,  Seung-Moon Kim ,  Jong-Wook Bae

    发明人： Kwang Jae Woo ,  Ki-won Jun ,  Suk-Hwan Kang ,  Seung-Moon Kim ,  Jong-Wook Bae

    IPC分类号： B01J8/20 ,  B01J8/22 ,  B01J4/00 ,  C10G2/00 ,  B01J8/00 ,  B01J8/18

    CPC分类号： B01J8/22 ,  B01J8/006 ,  B01J8/1809 ,  B01J2208/00061 ,  B01J2208/0007 ,  B01J2208/0061 ,  B01J2219/002 ,  B01J2219/00213 ,  B01J2219/00236 ,  C10G2/342 ,  C10G2300/4056 ,  C10G2300/4081

    摘要： The present invention relates to a continuous separation and discharge apparatus and method of solid catalysts and liquid products for Fischer-Tropsch synthesis reactions, and more particularly, to a continuous separation and discharge apparatus and method of solid catalysts and products for Fischer-Tropsch synthesis reactions involving the conversion of synthetic gas into synthetic oil, by which products of the Fischer-Tropsch synthesis including wax, as a long-chain hydrocarbon, can be stably obtained by continuously separating the products from a slurry comprising solid catalyst particles and the products using periodic pulses of a feeding gas and discharging the products through a lower portion of a reactor. Provided is a continuous separation and discharge apparatus of solid catalysts and products for Fischer-Tropsch synthesis reactions including: a level sensing device which is installed at an upper portion of a reactor and detects the slurry-level of reactants; a solid catalyst/product separation device and a discharge device which are installed at a lower portion of the reactor and separate and discharge liquid products from a mixed slurry in the reactor; and a control unit which receives a signal from the level sensing device to open and close the discharge device, wherein the separation device filters the solid catalysts, and the discharge device continuously discharges the products separated from the solid catalysts through the lower portion of the reactor by the amount of the synthesized products measured by a level sensing device.

    摘要翻译： 本发明涉及用于费 - 托合成反应的固体催化剂和液体产品的连续分离和排出装置和方法，更具体地说，涉及用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置和方法 包括将合成气转化为合成油，由此通过使包含固体催化剂颗粒和产物的浆料的产物通过使用周期性的方式连续分离，可以稳定地获得包含蜡作为长链烃的费 - 托合成产物 进料气体的脉冲并将产物排出反应器的下部。 提供了用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置，包括：液位传感装置，其安装在反应器的上部并检测反应物的浆料水平; 固体催化剂/产物分离装置和排出装置，其安装在反应器的下部，并将反应器中的混合浆料分离和排出液体产物; 以及控制单元，其接收来自液位感测装置的信号以打开和关闭排出装置，其中分离装置对固体催化剂进行过滤，并且排出装置连续排出与固体催化剂分离的产物通过反应器的下部 通过液位感测装置测量的合成产品的量。

    Method and Apparatus for the Continuous Separation and Discharge of Solid Catalysts and Products for Fischer-Tropsch Synthesis Reactions
    9.
    发明申请
    Method and Apparatus for the Continuous Separation and Discharge of Solid Catalysts and Products for Fischer-Tropsch Synthesis Reactions 有权
    用于费 - 托合成反应的固体催化剂和产物的连续分离和排放的方法和装置

    公开(公告)号：US20110028574A1

    公开(公告)日：2011-02-03

    申请号：US12919919

    申请日：2008-12-08

    申请人： Kwang Jae Woo ,  Ki-won Jun ,  Suk-Hwan Kang ,  Seung-Moon Kim ,  Jong-Wook Bae

    发明人： Kwang Jae Woo ,  Ki-won Jun ,  Suk-Hwan Kang ,  Seung-Moon Kim ,  Jong-Wook Bae

    IPC分类号： C07C1/12 ,  B01J19/00

    CPC分类号： B01J8/22 ,  B01J8/006 ,  B01J8/1809 ,  B01J2208/00061 ,  B01J2208/0007 ,  B01J2208/0061 ,  B01J2219/002 ,  B01J2219/00213 ,  B01J2219/00236 ,  C10G2/342 ,  C10G2300/4056 ,  C10G2300/4081

    摘要： The present invention relates to a continuous separation and discharge apparatus and method of solid catalysts and liquid products for Fischer-Tropsch synthesis reactions, and more particularly, to a continuous separation and discharge apparatus and method of solid catalysts and products for Fischer-Tropsch synthesis reactions involving the conversion of synthetic gas into synthetic oil, by which products of the Fischer-Tropsch synthesis including wax, as a long-chain hydrocarbon, can be stably obtained by continuously separating the products from a slurry comprising solid catalyst particles and the products using periodic pulses of a feeding gas and discharging the products through a lower portion of a reactor. Provided is a continuous separation and discharge apparatus of solid catalysts and products for Fischer-Tropsch synthesis reactions including: a level sensing device which is installed at an upper portion of a reactor and detects the slurry-level of reactants; a solid catalyst/product separation device and a discharge device which are installed at a lower portion of the reactor and separate and discharge liquid products from a mixed slurry in the reactor; and a control unit which receives a signal from the level sensing device to open and close the discharge device, wherein the separation device filters the solid catalysts, and the discharge device continuously discharges the products separated from the solid catalysts through the lower portion of the reactor by the amount of the synthesized products measured by a level sensing device.

    摘要翻译： 本发明涉及用于费 - 托合成反应的固体催化剂和液体产品的连续分离和排出装置和方法，更具体地说，涉及用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置和方法 包括将合成气转化为合成油，由此通过使包含固体催化剂颗粒和产物的浆料的产物通过使用周期性的方式连续分离，可以稳定地获得包含蜡作为长链烃的费 - 托合成产物 进料气体的脉冲并将产物排出反应器的下部。 提供了用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置，包括：液位传感装置，其安装在反应器的上部并检测反应物的浆料水平; 固体催化剂/产物分离装置和排出装置，其安装在反应器的下部，并将反应器中的混合浆料分离和排出液体产物; 以及控制单元，其接收来自液位感测装置的信号以打开和关闭排出装置，其中分离装置对固体催化剂进行过滤，并且排出装置连续排出与固体催化剂分离的产物通过反应器的下部 通过液位感测装置测量的合成产品的量。

    Integrated development method for RAM-LSA-TM
    10.
    发明申请
    Integrated development method for RAM-LSA-TM 审中-公开
    RAM-LSA-TM的集成开发方法

    公开(公告)号：US20060173902A1

    公开(公告)日：2006-08-03

    申请号：US11206328

    申请日：2005-08-17

    申请人： Sang-Kyun Mok ,  Jong-Wook Bae ,  Jong-Min Ahn ,  Jong-Jin Kim

    发明人： Sang-Kyun Mok ,  Jong-Wook Bae ,  Jong-Min Ahn ,  Jong-Jin Kim

    IPC分类号： G06F17/00 ,  G06F7/00

    CPC分类号： G06Q10/00 ,  G06F16/93

    摘要： Disclosed is an integrated development method for RAM-LSA-TM. The integrated development method for RAM-LSA-TM comprises the steps of: comparing the reference number of identification key information of a first item from a Ram part list table of a RAM calculation module DB and the reference number of a second item from a HG table of an international standard DB; if the reference numbers are the same as a result of the comparison, comparing the reference number of the next higher assembly of the identification key information of the first item and the reference number of the next higher assembly of the second item from the HG table of the international standard DB, and determining if the first item and the second item are the same or not based on a result of the comparison; creating a technical manual database by detecting technical manual related information about supply and maintenance from the international standard LSA DB; entering key information specifying a technical manual to register the technical manual based on the entered key information and automatically creating a basic table of contents of the technical manual; and automatically creating a technical manual DB of MIL-PRF-87269 standard by importing data of the LSA DB to the created table of contents.

    摘要翻译： 公开了一种用于RAM-LSA-TM的集成开发方法。 RAM-LSA-TM的集成开发方法包括以下步骤：将来自RAM计算模块DB的Ram部分列表表的第一项的识别密钥信息的参考号与来自HG的第二项的参考号进行比较 国际标准DB表; 如果参考编号与比较结果相同，则比较第一项目的识别密钥信息的下一较高组件的参考编号与第二项目的下一较高组件的参考编号与第二项目的HG表 国际标准DB，并且基于比较的结果来确定第一项和第二项是否相同; 通过国际标准LSA DB检测技术手册相关的供应和维护信息，建立技术手册数据库; 输入指定技术手册的密钥信息，根据输入的密钥信息注册技术手册，并自动创建技术手册的基本目录; 并通过将LSA DB的数据导入到创建的目录中，自动创建MIL-PRF-87269标准的技术手册DB。