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公开(公告)号：US08829139B2
公开(公告)日：2014-09-09
申请号：US12992775
申请日：2009-05-15
摘要： A method for easily producing high-purity polydimethylsilane or polydiphenylsilane, where by-products such as alkali metal salt and alkaline earth metal salt can be efficiently removed, is provided. Dimethyldichlorosilane or diphenyldichlorosilane is reacted with an alkali metal such as metal sodium and metal magnesium and/or an alkaline earth metal in an organic solvent such as toluene to obtain crude polydimethylsilane or crude polydiphenylsilane, methanol having dissolved therein an ether ester-type nonionic surfactant or a surfactant such as alkylbenzenesulfonate is added to the crude polydimethylsilane or the crude polydiphenylsilane to deactivate the remaining alkali metal and alkaline earth metal, and the crude polydimethylsilane or the crude polydiphenylsilane is washed with water in the presence of a surfactant to efficiently remove an alkali metal salt, an alkaline earth metal salt and the like, whereby high-purity polydimethylsilane or polydiphenylsilane is obtained.
摘要翻译： 提供容易生产高纯度聚二甲基硅烷或聚二苯基硅烷的方法，其中可以有效地除去碱金属盐和碱土金属盐等副产物。 二甲基二氯硅烷或二苯基二氯硅烷与有机溶剂如甲苯中的金属钠和金属镁和/或碱土金属的碱金属反应，得到粗的聚二甲基硅烷或粗的聚二苯基硅烷，其中溶解有醚酯型非离子表面活性剂的甲醇或 将烷基苯磺酸盐等表面活性剂加入到粗聚二甲基硅烷或粗聚二苯基硅烷中，使剩余的碱金属和碱土金属失活，粗面聚二甲基硅烷或粗聚二苯基硅烷在表面活性剂存在下用水洗涤，有效地除去碱金属 盐，碱土金属盐等，得到高纯度聚二甲基硅烷或聚二苯基硅烷。
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公开(公告)号：US20110071269A1
公开(公告)日：2011-03-24
申请号：US12992775
申请日：2009-05-15
IPC分类号： C08G77/12
摘要： A method for easily producing high-purity polydimethylsilane or polydiphenylsilane, where by-products such as alkali metal salt and alkaline earth metal salt can be efficiently removed, is provided. Dimethyldichlorosilane or diphenyldichlorosilane is reacted with an alkali metal such as metal sodium and metal magnesium and/or an alkaline earth metal in an organic solvent such as toluene to obtain crude polydimethylsilane or crude polydiphenylsilane, methanol having dissolved therein an ether ester-type nonionic surfactant or a surfactant such as alkylbenzenesulfonate is added to the crude polydimethylsilane or the crude polydiphenylsilane to deactivate the remaining alkali metal and alkaline earth metal, and the crude polydimethylsilane or the crude polydiphenylsilane is washed with water in the presence of a surfactant to efficiently remove an alkali metal salt, an alkaline earth metal salt and the like, whereby high-purity polydimethylsilane or polydiphenylsilane is obtained.
摘要翻译： 提供容易生产高纯度聚二甲基硅烷或聚二苯基硅烷的方法，其中可以有效地除去碱金属盐和碱土金属盐等副产物。 二甲基二氯硅烷或二苯基二氯硅烷与有机溶剂如甲苯中的金属钠和金属镁和/或碱土金属的碱金属反应，得到粗的聚二甲基硅烷或粗的聚二苯基硅烷，其中溶解有醚酯型非离子表面活性剂的甲醇或 将烷基苯磺酸盐等表面活性剂加入到粗聚二甲基硅烷或粗聚二苯基硅烷中，使剩余的碱金属和碱土金属失活，粗面聚二甲基硅烷或粗聚二苯基硅烷在表面活性剂存在下用水洗涤，有效地除去碱金属 盐，碱土金属盐等，得到高纯度聚二甲基硅烷或聚二苯基硅烷。
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3.发明授权Process for production of cyclic silane compound and/or cyclic carbosilane compound 有权环状硅烷化合物和/或环状碳硅烷化合物的制造方法公开(公告)号：US08669390B2
公开(公告)日：2014-03-11
申请号：US13259554
申请日：2010-04-09
IPC分类号： C07F7/21
CPC分类号： C07F7/0896 , C07F7/0803 , C07F7/0807 , C07F7/21
摘要： The present invention relates to: a process for producing a cyclic silane compound, which comprises subjecting a chained polysilane to pyrolysis in the presence of an oxide of a transition metal belonging to Group 8 or Group 11 of the periodic table; and a process for producing a cyclic carbosilane compound, which comprises subjecting a chained polysilane to pyrolysis in the presence of a simple substance of a metal selected from the group consisting of transition metal elements and elements belonging to Groups 12 to 15 of the periodic table or a compound thereof.
摘要翻译： 本发明涉及一种环状硅烷化合物的制备方法，其包括使链状聚硅烷在属于周期表第8族或第11族的过渡金属的氧化物存在下进行热解; 以及环状碳硅烷化合物的制造方法，其特征在于，在选自过渡金属元素和元素周期表第12〜15族的元素的金属的单质的存在下，使链状聚硅烷进行热解，或 其化合物。
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4.发明申请PROCESS FOR PRODUCTION OF CYCLIC SILANE COMPOUND AND/OR CYCLIC CARBOSILANE COMPOUND 有权生产环状硅烷化合物和/或环状碳酸酯化合物的方法公开(公告)号：US20120016149A1
公开(公告)日：2012-01-19
申请号：US13259554
申请日：2010-04-09
申请人： Satoru Yamazaki , Kimihiko Oohata , Minoru Okada , Masamichi Yasuhara , Hideki Maekawa , Hiroyuki Yamanaka
发明人： Satoru Yamazaki , Kimihiko Oohata , Minoru Okada , Masamichi Yasuhara , Hideki Maekawa , Hiroyuki Yamanaka
CPC分类号： C07F7/0896 , C07F7/0803 , C07F7/0807 , C07F7/21
摘要： The present invention relates to: a process for producing a cyclic silane compound, which comprises subjecting a chained polysilane to pyrolysis in the presence of an oxide of a transition metal belonging to Group 8 or Group 11 of the periodic table; and a process for producing a cyclic carbosilane compound, which comprises subjecting a chained polysilane to pyrolysis in the presence of a simple substance of a metal selected from the group consisting of transition metal elements and elements belonging to Groups 12 to 15 of the periodic table or a compound thereof.
摘要翻译： 本发明涉及一种环状硅烷化合物的制备方法，其包括使链状聚硅烷在属于周期表第8族或第11族的过渡金属的氧化物存在下进行热解; 以及环状碳硅烷化合物的制造方法，其特征在于，在选自过渡金属元素和元素周期表第12〜15族的元素的金属的单质的存在下，使链状聚硅烷进行热解，或 其化合物。
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5.发明授权Processes for the preparation of 4(5)-amino-5(4)-carboxamidoimidazoles and intermediates thereof 有权制备4（5） - 氨基-5（4） - 羧酰氨基咪唑的方法及其中间体公开(公告)号：US06797828B1
公开(公告)日：2004-09-28
申请号：US10088425
申请日：2002-03-15
申请人： Hiroaki Shibasaki , Fumihiko Nagasaki , Mitsuru Takase , Satoru Yamazaki , Yutaka Ishii , Kimihiko Oohata
发明人： Hiroaki Shibasaki , Fumihiko Nagasaki , Mitsuru Takase , Satoru Yamazaki , Yutaka Ishii , Kimihiko Oohata
IPC分类号： C07D23370
CPC分类号： C07C257/14 , C07D233/90
摘要： The invention provides novel processes for preparing efficiently compounds of general formula (1) (wherein R1 and R2 are each independently hydrogen, optionally substituted C1-C10 alkyl, C3-C14 hydrocarbyl bearing alicyclic skeleton, or the like) and initermediates thereof. Compounds of general formula (I) can be prepared by subjecting compounds of general formula (II) and/or salts thereof to cyclization hydrolysis in an aqueous basic solution. Further, compounds of general formula (II) can be prepared from industrially easily available diaminomaleonitrile in a high yield.
摘要翻译： 本发明提供有效制备通式（1）化合物（其中R 1和R 2各自独立地为氢，任选取代的C 1 -C 10烷基，C 3 -C 14烃基带有脂环骨架等）的化合物及其初始化物的新方法。 通式（I）的化合物可以通过使通式（II）的化合物和/或其盐在碱性水溶液中进行环化水解来制备。 此外，通式（II）的化合物可以从工业上容易获得的二氨基马来腈以高产率制备。
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