公开(公告)号：US5440024A

公开(公告)日：1995-08-08

申请号：US90311

申请日：1993-07-13

申请人： Kiyoshi Himeno ,  Toshio Hihara ,  Wataru Shimizu

发明人： Kiyoshi Himeno ,  Toshio Hihara ,  Wataru Shimizu

IPC分类号： C09B29/00 ,  C09B29/42 ,  C09B67/22 ,  D06P3/54 ,  C09B29/033 ,  C09B29/33 ,  C09B29/36 ,  D06P1/18

CPC分类号： C09B67/0051 ,  C09B29/0059 ,  C09B29/3639

摘要： A monoazo disperse dye for dyeing polyester fibers of the following formula (I): ##STR1## wherein one of R.sup.1 and R.sup.2 is ##STR2## wherein W is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl or alkoxy, the other of R.sup.1 and R.sup.2 is C.sub.1 -C.sub.4 alkyl, or C.sub.2 -C.sub.4 alkyl substituted by cyano, halogen, hydroxy, hydroxyalkoxy, C.sub.1 -C.sub.4 alkoxy, hydroxyalkoxyalkoxy, acetoxalkoxy, acyloxyalkoxyalkoxy alkoxyalkoxy, alkoxycarbonyloxy or acetoxy, and Y is hydrogen or halogen.

摘要翻译： 用于染色下式（I）的聚酯纤维的单偶氮分散染料：其中R 1和R 2之一是其中W是氢，卤素，C 1 -C 2烷基或烷氧基，R 1中的另一个 或被氰基，卤素，羟基，羟基烷氧基，C 1 -C 4烷氧基，羟基烷氧基烷氧基，乙酰氧基烷氧基，酰氧基烷氧基烷氧基烷氧基，烷氧基羰基氧基或乙酰氧基取代的C 2 -C 4烷基，Y为氢或卤素。

公开(公告)号：USRE37004E

公开(公告)日：2000-12-26

申请号：US916366

申请日：1997-08-22

申请人： Yousuke Takahashi ,  Yukihara Shimizu ,  Toshio Hihara ,  Kiyoshi Himeno

发明人： Yousuke Takahashi ,  Yukihara Shimizu ,  Toshio Hihara ,  Kiyoshi Himeno

IPC分类号： C09B62/51 ,  C09B62/44 ,  C09B62/028 ,  C09B62/085 ,  C09B62/245

CPC分类号： C09B62/4413 ,  C09B62/4424 ,  C09B62/51

摘要： A water-soluble monoazodye having the following formula (I) in its free acid form: ##STR1## wherein X is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 W wherein W is a leaving group removable by alkali; R.sup.1 is methyl, --NHCONH.sub.2 or --NHCOT.sup.1 wherein T.sup.1 is methyl, ethyl, --CH.sub.2 CH.sub.2 COOH or --CH.dbd.CHCOOH; R.sup.2 is hydrogen, lower alkyl or lower alkoxy; and Z is ##STR2## wherein P is cyano or halogen, each of Q and U which are independent of each other, is halogen, V is halogen or ##STR3## and Y is halogen or a group of the following formula (1) or (2): ##STR4## wherein R.sup.3, A, R.sup.4 and E are as defined in the disclosure and G is as defined above, has a moderate yellow to orange color and is particularly suitable for dyeing cellulose fibers or nitrogen-containing fibers.

摘要翻译： 具有游离酸形式的具有下式（I）的水溶性一抗体：其中X是-CH = CH 2或-CH 2 CH 2 W，其中W是可以被碱除去的离去基团; 乙烯基，-CH 2 CH 2 COOH或-CH = CHCOOH; R 1为甲基，-NHCONH 2或-NHCOT 1，其中T 1为甲基， R2是氢，低级烷基或低级烷氧基; 和Z是其中P是氰基或卤素，Q和U各自彼此独立，是卤素，V是卤素或Y是卤素或下式（1）或（2）的基团：其中R3 A，R4和E如本文所定义，G如上所定义，具有中等的黄色至橙色，并且特别适用于染色纤维素纤维或含氮纤维。

公开(公告)号：US4985545A

公开(公告)日：1991-01-15

申请号：US243310

申请日：1988-08-15

申请人： Kiyoshi Himeno ,  Toshio Hihara ,  Kanzi Shimizu ,  Yukiharu Shimizu

发明人： Kiyoshi Himeno ,  Toshio Hihara ,  Kanzi Shimizu ,  Yukiharu Shimizu

IPC分类号： C09B62/503 ,  D06P1/384

CPC分类号： C09B62/5036

摘要： A water-soluble formazan colorant, which is represented by the following general formula (I) in the form of free acid: ##STR1## (where: R represents a hydrogen atom or a lower alkyl group which may be substituted; X denotes a phenylene group or a naphthylene group which may be substituted; Y indicates --SO.sub.2 CH.dbd.CH.sub.2 group or --SO.sub.2 C.sub.2 H.sub.4 W group wherein W represents a group to be eliminated by the action of alkali; and Z designates a lower alkylamino group, a phenylamino group or a naphthylamino group, having one or two water-soluble groups selected from the group consisting of hydroxyl group, sulfonic acid group and carboxylic acid group); and a method of dyeing by use of the colorant. The colorant is used to dye cellulosic and nitrogen-containing fibers in blue shades with excellent reactive fixing properties.

公开(公告)号：US4801696A

公开(公告)日：1989-01-31

申请号：US65184

申请日：1987-06-22

申请人： Toshio Niwa ,  Kiyoshi Himeno ,  Toshio Hihara ,  Shuichi Maeda

发明人： Toshio Niwa ,  Kiyoshi Himeno ,  Toshio Hihara ,  Shuichi Maeda

IPC分类号： C09B31/043 ,  D06P3/60 ,  C09B33/02 ,  D06P1/18 ,  D06P3/36

CPC分类号： C09B31/043 ,  D06P3/6041

摘要： Disazo dyes for dyeing cellulose-containing fibers represented by the following general formula: ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom, a halogen atom, a nitro group, a cyano group, a thiocyanato group, a trifluoromethyl group, a formyl group, a lower alkoxycarbonyl group, a lower alkylsulfonyl group, a sulfamoyl group, an N-lower alkylsulfamoyl group or an N,N-di-lower alkylsulfamoyl group, R.sup.3 represents a hydrogen atom, a methyl group, a chlorine atom, a lower alkoxy group or an acylamino group, R.sup.4 represents a hydrogen atom, a methyl group, a chlorine atom or a lower alkoxy group, R.sup.5 represents a hydrogen atom, a lower alkyl group or a halogen atom, --X-- represents ##STR2## --SO.sub.2 -- or --CH.sub.2 --, and n represents 0 or 1. These dyes are capable of dyeing cellulose-containing fibers, particularly fiber blends composed of cellulose fibers and polyester fibers, blue to bluish green with good fastness properties.

摘要翻译： 用于染色含纤维素纤维的双偶氮染料，其由以下通式表示：其中R 1和R 2各自表示氢原子，卤素原子，硝基，氰基，硫氰酸酯基， 三氟甲基，甲酰基，低级烷氧基羰基，低级烷基磺酰基，氨磺酰基，N-低级烷基氨磺酰基或N，N-二低级烷基氨磺酰基，R 3表示氢原子，甲基， 氯原子，低级烷氧基或酰氨基，R4表示氢原子，甲基，氯原子或低级烷氧基，R5表示氢原子，低级烷基或卤素原子，-X-表示 -SO 2 - 或-CH 2 - ，并且n表示0或1.这些染料能够染色含纤维素的纤维，特别是由纤维素纤维和聚酯纤维组成的纤维混合物，蓝色至蓝绿色，具有良好的牢度特性。

公开(公告)号：US5734028A

公开(公告)日：1998-03-31

申请号：US732723

申请日：1996-10-18

申请人： Kiyoshi Himeno ,  Toshio Hihara ,  Ryouchi Sekioka

发明人： Kiyoshi Himeno ,  Toshio Hihara ,  Ryouchi Sekioka

IPC分类号： C09B67/22 ,  D06P1/18 ,  D06P1/20 ,  D06P3/54

CPC分类号： C09B67/0041 ,  D06P1/18 ,  D06P1/20 ,  Y10S534/01

摘要： A blue type disperse dye mixture comprising a monoazo dye of the formula (1) in an amount of 1.0 part by weight and at least one of anthraquinone dyes of the formulae (2) to (4) in a total amount of from 0.2 to 3.0 parts by weight: ##STR1##

摘要翻译： 一种蓝色分散染料混合物，其包含1.0重量份的式（1）的单偶氮染料和至少一种式（2）至（4）的蒽醌染料，其总量为0.2-3.0 （1）（2）（3）（4）

公开(公告)号：US5368612A

公开(公告)日：1994-11-29

申请号：US100294

申请日：1993-08-02

申请人： Kiyoshi Himeno ,  Toshio Hihara

发明人： Kiyoshi Himeno ,  Toshio Hihara

IPC分类号： C09B62/02 ,  D06P1/382

CPC分类号： C09B62/021 ,  Y10S8/922 ,  Y10S8/924 ,  Y10S8/926

摘要： Water-insoluble naphthalic acid imide dyestuffs of the following formula: ##STR1## wherein D is ##STR2## wherein R.sup.1 is C.sub.1 -C.sub.8 alkyl which may be substituted, R.sup.2 is hydrogen, halogen, lower alkyl, lower alkoxy or cyano, X is oxygen or sulfur, and m is 0 or 1; A is phenylene, alkylene, aralkylene or --C.sub.2 H.sub.4 OC.sub.2 H.sub.4 --; B is oxygen, sulfur or ##STR3## wherein R.sup.3 is hydrogen or lower alkyl; Y is a 6-membered nitrogen-containing heterocyclic ring having at least one active halogen atom; and n is 0 or 1.

摘要翻译： 下式的水不溶性萘二甲酰亚胺染料：其中D是其中R 1是可被取代的C 1 -C 8烷基，R 2是氢，卤素，低级烷基，低级烷氧基或氰基， X是氧或硫，m是0或1; A是亚苯基，亚烷基，亚芳基或-C 2 H 4 OC 2 H 4 - ; B是氧，硫或者其中R 3是氢或低级烷基; Y是具有至少一个活性卤素原子的6元含氮杂环; n为0或1。

公开(公告)号：US4743684A

公开(公告)日：1988-05-10

申请号：US766312

申请日：1985-08-16

申请人： Toshio Niwa ,  Kiyoshi Himeno ,  Toshio Hihara ,  Kanzi Shimizu

发明人： Toshio Niwa ,  Kiyoshi Himeno ,  Toshio Hihara ,  Kanzi Shimizu

IPC分类号： C09B47/04 ,  C09B62/10 ,  C09B62/523 ,  D06P1/382

CPC分类号： D06P1/382 ,  C09B62/10

摘要： A reactive phthalocyanine dye having a specific substituent capable of dyeing cellulose fibers or a mixed fibers of polyester fibers and cellulose fibers to provide Turkish blue-dyed fibers excellent in color fastness to light and color fastness to washing is disclosed, which is represented by general formula [I] ##STR1##

摘要翻译： 公开了具有能够染色纤维素纤维的特定取代基的反应性酞菁染料或聚酯纤维和纤维素纤维的混合纤维，以提供具有优异的耐色牢度和耐洗色牢度的土耳其蓝染色纤维，其通式为 [I] [I]

公开(公告)号：US4707546A

公开(公告)日：1987-11-17

申请号：US822680

申请日：1986-01-23

申请人： Toshio Niwa ,  Kiyoshi Himeno ,  Toshio Hihara

发明人： Toshio Niwa ,  Kiyoshi Himeno ,  Toshio Hihara

IPC分类号： C09B62/085 ,  C09B62/343 ,  D06P1/382 ,  D06P3/85

CPC分类号： C09B62/085

摘要： A reactive monoazo dyestuff of the general formula [I]: ##STR1## wherein R.sup.1 and R.sup.2 each represents substituted or unsubstituted alkyl, cyclohexyl, aralkyl or substituted or unsubstituted aryl, Z represents hydrogen, chlorine, methyl or acylamino, (A) represents substituted or unsubstituted alkylene, (B) represents oxygen or --NH--, X represents fluorine or chlorine, and Y represents --NR.sup.4 R.sup.5 or --OR.sup.6 wherein R.sup.4, R.sup.5 and R.sup.6 each represents hydrogen, substituted or unsubstituted alkyl, alkenyl, cyclohexyl, aryl or aralkyl, or --NR.sup.4 R.sup.5 represents a 5- or 6-membered nitrogen-containing heterocyclic ring formed by combining R.sup.4 and R.sup.5.

摘要翻译： 通式[I]的反应性单偶氮染料：其中R 1和R 2各自表示取代或未取代的烷基，环己基，芳烷基或取代或未取代的芳基，Z表示氢，氯，甲基或酰氨基，（A ）表示取代或未取代的亚烷基，（B）表示氧或-NH-，X表示氟或氯，Y表示-NR4R5或-OR6，其中R4，R5和R6各自表示氢，取代或未取代的烷基，烯基，环己基， 芳基或芳烷基，或-NR4R5表示通过组合R4和R5形成的5-或6-元含氮杂环。

公开(公告)号：US4623719A

公开(公告)日：1986-11-18

申请号：US843927

申请日：1986-03-24

申请人： Toshio Niwa ,  Kiyoshi Himeno ,  Toshio Hihara

发明人： Toshio Niwa ,  Kiyoshi Himeno ,  Toshio Hihara

IPC分类号： C09B31/14 ,  C09B62/09 ,  D06P1/382 ,  C07C107/06

CPC分类号： D06P1/382 ,  C09B62/09

摘要： This invention relates to disazo dyestuffs for cellulose or cellulose-containing fibers represented by the formula: ##STR1## wherein R.sup.1 represents a hydrogen atom, a nitro group, a halogen atom, an alkyl group of 1 or 2 carbon atoms or an acetylamino group; R.sup.2 and R.sup.3 each represents a hydrogen atom, an alkyl group of 1 or 2 carbon atoms, and alkoxy group or an acetylamino group; Y.sup.1 and Y.sup.2 each represents a hydrogen atom or an alkyl group, and alkenyl group, a cyclohexyl group, an aryl group or an aralkyl group which group ma optionally be substituted by cyano, hydroxyl, lower alkoxy or dialkylamino, or NY.sup.1 Y.sup.2 represents a 5-membered or 6-membered nitrogen-containing heretocyclic ring formed by combination of Y.sup.1 and Y.sup.2, and the total carbon atoms in Y.sup.1 and Y.sup.2 is 18 or less.

摘要翻译： 本发明涉及由下式表示的纤维素或含纤维素纤维的双偶氮染料：其中R1表示氢原子，硝基，卤素原子，1或2个碳原子的烷基 或乙酰氨基; R2和R3各自表示氢原子，1或2个碳原子的烷基和烷氧基或乙酰氨基; Y1和Y2各自表示氢原子或烷基，以及基团任选被氰基，羟基，低级烷氧基或二烷基氨基取代的烯基，环己基，芳基或芳烷基，或者NY1Y2表示5- 通过Y1和Y2的组合形成的6-元或6元含氮杂环，Y1和Y2中的总碳原子数为18以下。

公开(公告)号：US5608042A

公开(公告)日：1997-03-04

申请号：US594487

申请日：1996-01-31

申请人： Kiyoshi Himeno ,  Toshio Hihara ,  Ryouichi Sekioka

发明人： Kiyoshi Himeno ,  Toshio Hihara ,  Ryouichi Sekioka

IPC分类号： C09B29/00 ,  C09B29/08 ,  D06P3/54 ,  C09B29/045 ,  C09B29/09

CPC分类号： C09B29/0813 ,  C09B29/0088 ,  D06P3/54 ,  Y10S8/922

摘要： A monoazo dye of the following formula (I): ##STR1## wherein R is phenyl, phenoxy or benzyl, and D is a group of the formula (D1), (D2), (D3) or (D4): ##STR2## wherein each of X.sup.1, X.sup.2 and X.sup.3, which are independent of one another, is hydrogen or chlorine, X.sup.4 is hydrogen, chlorine, methyl or --NHCOR.sup.1, wherein R.sup.1 is C.sub.1-4 alkyl or phenyl; ##STR3## wherein X.sup.4 is as defined above, Y.sup.1 is hydrogen, chlorine or C.sub.1-4 alkoxy; ##STR4## wherein X.sup.5 is hydrogen, halogen, methyl or --NHZ, wherein Z is C.sub.1-4 alkylsurfonyl, C.sub.1-4 alkylcarbonyl, phenylsulfonyl, phenylcarbonyl, C.sub.1-2 alkoxy C.sub.1-2 alkylcarbonyl or aminocarbonyl, Y.sup.2 is hydrogen, methyl or C.sub.1-2 alkoxy, and Q.sup.1 is cyano or C.sub.1-4 alkylcarbonyl; ##STR5## wherein P is formyl, nitro or cyano, Q.sup.2 is cyano or nitro, T is halogen, methyl, phenyl or methylsulfonyl, X.sup.5 is as defined above, and Y.sup.3 is hydrogen or C.sub.1-2 alkoxy.

摘要翻译： 下式（I）的单偶氮染料：其中R是苯基，苯氧基或苄基，D是式（D1），（D2），（D3）或（D4）的基团： （D1）其中X 1，X 2和X 3彼此独立地为氢或氯，X 4为氢，氯，甲基或-NHCOR 1，其中R 1为C 1-4烷基或苯基; （D2）其中X4如上所定义，Y 1是氢，氯或C 1-4烷氧基; （D3）其中X5是氢，卤素，甲基或-NHZ，其中Z是C1-4烷基磺酰基，C1-4烷基羰基，苯基磺酰基，苯基羰基，C1-2烷氧基C1-2烷基羰基或氨基羰基，Y2是氢， 甲基或C 1-2烷氧基，Q 1为氰基或C 1-4烷基羰基; （D4）其中P是甲酰基，硝基或氰基，Q2是氰基或硝基，T是卤素，甲基，苯基或甲基磺酰基，X5如上所定义，Y 3是氢或C 1-2烷氧基。