公开(公告)号：US07196194B2

公开(公告)日：2007-03-27

申请号：US10679466

申请日：2003-10-07

申请人： Kiyoshi Takeuchi ,  Shigeki Uehira ,  Mario Aoki ,  Jun Ogasawara ,  Yasuhiro Shimada ,  Seiji Ichijima ,  Yasuaki Deguchi ,  Naoto Matsuda ,  Akira Ikeda ,  Hisashi Mikoshiba ,  Masaharu Sugai ,  Taiji Katsumata

发明人： Kiyoshi Takeuchi ,  Shigeki Uehira ,  Mario Aoki ,  Jun Ogasawara ,  Yasuhiro Shimada ,  Seiji Ichijima ,  Yasuaki Deguchi ,  Naoto Matsuda ,  Akira Ikeda ,  Hisashi Mikoshiba ,  Masaharu Sugai ,  Taiji Katsumata

IPC分类号： C09B55/00 ,  C07D239/88 ,  C07D285/18 ,  C07D285/20 ,  C07D285/24 ,  C07D403/06 ,  C07D417/06 ,  C07D513/04

CPC分类号： C09B55/00 ,  C07D239/90 ,  C07D285/18 ,  C07D285/24 ,  C07D403/06 ,  C07D417/06 ,  C07D417/12 ,  C07D513/04 ,  C09B55/003 ,  G03C7/30535 ,  G03C7/36

摘要： A yellow dye-forming coupler represented by formula (I): wherein Q represents a group of nonmetallic atoms that form a 5- to 7-membered ring in combination with the —N═C—N(R1)—; R1 and R2 each represent a substituent; R4 represents an alkyl group; m represents an integer of 0 to 4; and X represents a hydrogen atom, or a group capable of being split-off upon a coupling reaction with an oxidized product of a developing agent; and when R4 represents a primary alkyl group, R1 represents —(CH2)3O—R101 in which R101 is an alkyl group having 4 to 8 carbon atoms. A silver halide color photographic light-sensitive material having at least one yellow dye-forming coupler represented by formula (I) in at least one layer provided on a support.

摘要翻译： 由式（I）表示的黄色成色剂：

公开(公告)号：US06727053B2

公开(公告)日：2004-04-27

申请号：US10106373

申请日：2002-03-27

申请人： Kiyoshi Takeuchi ,  Shigeki Uehira ,  Mario Aoki ,  Jun Ogasawara ,  Yasuhiro Shimada ,  Seiji Ichijima ,  Yasuaki Deguchi ,  Naoto Matsuda ,  Akira Ikeda ,  Hisashi Mikoshiba ,  Masaharu Sugai ,  Taiji Katsumata

发明人： Kiyoshi Takeuchi ,  Shigeki Uehira ,  Mario Aoki ,  Jun Ogasawara ,  Yasuhiro Shimada ,  Seiji Ichijima ,  Yasuaki Deguchi ,  Naoto Matsuda ,  Akira Ikeda ,  Hisashi Mikoshiba ,  Masaharu Sugai ,  Taiji Katsumata

IPC分类号： G03C108

CPC分类号： G03C1/08 ,  C07D239/90 ,  C07D285/18 ,  C07D285/24 ,  C07D403/06 ,  C07D417/06 ,  C07D417/12 ,  C07D513/04 ,  C09B55/002 ,  C09B55/003 ,  G03C7/30535 ,  G03C7/36

摘要： A dye-forming coupler of formula (I), a silver halide photographic light-sensitive material containing the coupler, and an azomethine dye that can be derived from the dye-forming coupler: wherein Q is a group —C(—R11)═C(—R12)—SO2—; R11 and R12 bond with each other to form, together with the —C═C— moiety, a 5- to 7-membered ring, or they each represent a hydrogen atom or a substituent; R1, R3 and R4 each represent a substituent; m is an integer of 0 to 4; and X represents a hydrogen atom or a group that splits off upon a coupling reaction with an oxidized product of a developing agent; with the proviso that the following compound (I-A) is excluded from the dye-forming coupler of formula (I).

摘要翻译： 式（I）的染料形成成色剂，含有偶合剂的卤化银照相感光材料和可衍生自染料形成成色剂的偶氮甲碱染料：其中Q为基团-C（-R 11）= C（ - R 12）-SO 2 - ; R 11和R 12彼此键合，与-C = C-部分一起形成5-至7-元环，或它们各自表示氢原子或取代基; R1，R3和R4各自表示取代基; m为0〜4的整数。 X表示氢原子或与显影剂的氧化物偶合反应时分裂的基团; 条件是从式（I）的染料形成成色剂除去下列化合物（I-A）。

公开(公告)号：US06803181B2

公开(公告)日：2004-10-12

申请号：US10270055

申请日：2002-10-15

申请人： Shigeki Uehira ,  Jun Ogasawara ,  Kiyoshi Takeuchi ,  Yasuhiro Shimada ,  Yasuaki Deguchi

发明人： Shigeki Uehira ,  Jun Ogasawara ,  Kiyoshi Takeuchi ,  Yasuhiro Shimada ,  Yasuaki Deguchi

IPC分类号： G03C108

CPC分类号： G03C7/38

摘要： A dye-forming coupler of the formula (I). A silver halide photographic light-sensitive material that contains at least one dye-forming coupler of the formula (I). A method for producing an azomethine dye, which method comprises using a compound of the formula (I): wherein E is an aryl, heterocyclic, or —C(═O)W group, in which W is a nitrogen-containing heterocyclic group, Z is an aryl or heterocyclic group, and X and Y each independently are ═O, ═S or ═N—R, in which R is a substituent, with the proviso that when E is an aryl or heterocyclic group, X and Y each are ═O, and that when E is a —C(═O)W group, Z is a substituted aryl group.

摘要翻译： 式（I）的染料形成成色剂。 含有至少一种式（I）的染料形成成色剂的卤化银照相感光材料。 一种制备偶氮甲碱染料的方法，该方法包括使用式（I）的化合物：其中E是芳基，杂环或-C（= O）W基，其中W是含氮杂环基， Z是芳基或杂环基，X和Y各自独立地为= O，= S或= NR，其中R是取代基，条件是当E是芳基或杂环基时，X和Y各自为= 且当E为-C（= O）W基时，Z为取代的芳基。

公开(公告)号：US20050020821A1

公开(公告)日：2005-01-27

申请号：US10912122

申请日：2004-08-06

申请人： Shigeki Uehira ,  Jun Ogasawara ,  Kiyoshi Takeuchi ,  Yasuhiro Shimada ,  Yasuaki Deguchi

发明人： Shigeki Uehira ,  Jun Ogasawara ,  Kiyoshi Takeuchi ,  Yasuhiro Shimada ,  Yasuaki Deguchi

IPC分类号： G03C7/38 ,  C09B45/00

CPC分类号： G03C7/38

摘要： A dye-forming coupler of the formula (I). A silver halide photographic light-sensitive material that contains at least one dye-forming coupler of the formula (I). A method for producing an azomethine dye, which method comprises using a compound of the formula (I): wherein E is an aryl, heterocyclic, or —C(═O)W group, in which W is a nitrogen-containing heterocyclic group, Z is an aryl or heterocyclic group, and X and Y each independently are ═O, ═S or ═N—R, in which R is a substituent, with the proviso that when E is an aryl or heterocyclic group, X and Y each are ═O, and that when E is a —C(═O)W group, Z is a substituted aryl group.

摘要翻译： 式（I）的染料形成成色剂。 含有至少一种式（I）的染料形成成色剂的卤化银照相感光材料。 一种制备偶氮甲碱染料的方法，该方法包括使用式（I）的化合物：其中E是芳基，杂环或-C（= O）W基，其中W是含氮杂环基， Z是芳基或杂环基，X和Y各自独立地为= O，= S或= NR，其中R是取代基，条件是当E是芳基或杂环基时，X和Y各自为= 且当E为-C（= O）W基时，Z为取代的芳基。

公开(公告)号：US07009048B2

公开(公告)日：2006-03-07

申请号：US10912122

申请日：2004-08-06

申请人： Shigeki Uehira ,  Jun Ogasawara ,  Kiyoshi Takeuchi ,  Yasuhiro Shimada ,  Yasuaki Deguchi

发明人： Shigeki Uehira ,  Jun Ogasawara ,  Kiyoshi Takeuchi ,  Yasuhiro Shimada ,  Yasuaki Deguchi

IPC分类号： C07D263/44 ,  C07D403/06 ,  C07D413/04 ,  C07D417/04 ,  C09B55/00

CPC分类号： G03C7/38

摘要： A dye-forming coupler of the formula (I). A silver halide photographic light-sensitive material that contains at least one dye-forming coupler of the formula (I). A method for producing an azomethine dye, which method comprises using a compound of the formula (I): wherein E is an aryl, heterocyclic, or —C(═O)W group, in which W is a nitrogen-containing heterocyclic group, Z is an aryl or heterocyclic group, and X and Y each independently are ═O, ═S or ═N—R, in which R is a substituent, with the proviso that when E is an aryl or heterocyclic group, X and Y each are ═O, and that when E is a —C(═O)W group, Z is a substituted aryl group.

摘要翻译： 式（I）的染料形成成色剂。 含有至少一种式（I）的染料形成成色剂的卤化银照相感光材料。 一种制备偶氮甲碱染料的方法，该方法包括使用式（I）的化合物：其中E是芳基，杂环或-C（-O）W基，其中W是含氮杂环基， Z是芳基或杂环基，X和Y各自独立地是-O，-S或-NR，其中R是取代基，条件是当E是芳基或杂环基时，X和Y各自为 - 并且当E是-C（-O）W基时，Z是取代的芳基。

公开(公告)号：US6068969A

公开(公告)日：2000-05-30

申请号：US235548

申请日：1999-01-22

申请人： Hisashi Mikoshiba ,  Shin Soejima ,  Yasuhiro Shimada ,  Osamu Takahashi ,  Yasuaki Deguchi

发明人： Hisashi Mikoshiba ,  Shin Soejima ,  Yasuhiro Shimada ,  Osamu Takahashi ,  Yasuaki Deguchi

IPC分类号： G03C7/30 ,  G03C7/392 ,  G03E1/295

CPC分类号： G03C7/3008 ,  G03C7/39232

摘要： There is disclosed a silver halide color photographic light-sensitive material, which comprises a compound of formula (I): wherein, in formula (I), R.sup.11 is a hydrogen atom, an alkyl group having 1 to 30 carbon atoms, an alkenyl group having 2 to 30 carbon atoms, or an aryl group; R.sup.12, R.sup.13, R.sup.14, R.sup.15, R.sup.16, and R.sup.17, each independently represent a hydrogen atom or an alkyl group having 1 to 30 carbon atoms, and n is 0 or 1. This color photographic light-sensitive material is excellent in fastness of dye image.

摘要翻译： 公开了一种卤化银彩色照相感光材料，其包含式（I）化合物：其中，在式（I）中，R 11为氢原子，具有1至30个碳原子的烷基，烯基 具有2至30个碳原子或芳基; R 12，R 13，R 14，R 15，R 16和R 17各自独立地表示氢原子或碳原子数1〜30的烷基，n为0或1.该彩色摄影感光材料的染色牢度优异 图片。

公开(公告)号：US07125988B2

公开(公告)日：2006-10-24

申请号：US10669414

申请日：2003-09-25

申请人： Kiyoshi Takeuchi ,  Nobuo Seto ,  Hiroyuki Yoneyama ,  Shigeki Uehira ,  Satoshi Sano ,  Yasuhiro Shimada

发明人： Kiyoshi Takeuchi ,  Nobuo Seto ,  Hiroyuki Yoneyama ,  Shigeki Uehira ,  Satoshi Sano ,  Yasuhiro Shimada

IPC分类号： C07D285/34 ,  G03C1/06 ,  G03C7/26 ,  G03C7/32

CPC分类号： C07D417/06 ,  C07D285/24 ,  C07D417/12 ,  C07D417/14 ,  G03C7/36 ,  G03C2200/33

摘要： A yellow dye-forming coupler represented by formula (I): wherein Q represents a group of nonmetallic atoms that form a 5- to 7-membered ring in combination with the —N═C—N(R1)—; R1 and R2 each represent a substituent; R4 represents an alkyl group; m represents an integer of 0 to 4; and X represents a hydrogen atom, or a group capable of being split-off upon a coupling reaction with an oxidized product of a developing agent; and when R4 represents a primary alkyl group, R1 represents —(CH2)3O—R101 in which R101 is an alkyl group having 4 to 8 carbon atoms. A silver halide color photographic light-sensitive material having at least one yellow dye-forming coupler represented by formula (I) in at least one layer provided on a support.

摘要翻译： 由式（I）表示的形成黄色染料的成色剂：其中Q表示与-N-C-N（R 1'） - 组合形成5-至7-元环的一组非金属原子; R 1和R 2各自表示取代基; R 4表示烷基; m表示0〜4的整数， X表示氢原子或与显影剂的氧化物进行偶联反应时可分离的基团; 并且当R 4代表伯烷基时，R 1表示 - （CH 2 CH 2）3 - 或 _{101其中R 101是具有4至8个碳原子的烷基。 一种卤化银彩色摄影感光材料，其在至少一层设置在载体上的至少一种由式（I）表示的形成黄色染料的成色剂。}

公开(公告)号：US20050079456A1

公开(公告)日：2005-04-14

申请号：US10669414

申请日：2003-09-25

申请人： Kiyoshi Takeuchi ,  Nobuo Seto ,  Hiroyuki Yoneyama ,  Shigeki Uehira ,  Satoshi Sano ,  Yasuhiro Shimada

发明人： Kiyoshi Takeuchi ,  Nobuo Seto ,  Hiroyuki Yoneyama ,  Shigeki Uehira ,  Satoshi Sano ,  Yasuhiro Shimada

IPC分类号： C07D285/24 ,  C07D417/06 ,  C07D417/12 ,  C07D417/14 ,  G03C7/36 ,  G03C1/06 ,  G03C7/26 ,  G03C7/32 ,  G03C1/005 ,  G03C1/494

CPC分类号： C07D417/06 ,  C07D285/24 ,  C07D417/12 ,  C07D417/14 ,  G03C7/36 ,  G03C2200/33

摘要： A dye-forming coupler and compound of formula (I): wherein Q represents a residue that forms, together with —N—C═N—, a nitrogen-containing 6-membered ring; RA represents an aryl, heterocyclic, or —(R1)r—(R4)m group; X represents an aryl group; Y represents a hydrogen atom, or a group capable of being split-off upon a coupling reaction with an oxidized product of a developing agent: wherein, when RA represents an —(R1)r—(R4)m group, R1 represents a methylene group, a methine group, or a carbon atom; r is 1 to 30; R4 represents a substituent except for a hydrogen atom; m is 1 to 30; and the —(R1)r—(R4)m group does not represent a straight-chain alkyl group.

摘要翻译： 染料形成成色剂和式（I）化合物：其中Q表示与-N-C = N-一起形成含氮6元环的残基; RA表示芳基，杂环或 - （R 1）r - （R 4）m基团; X表示芳基; Y表示氢原子或与显影剂的氧化产物偶联反应时能够分离的基团：其中，当RA表示 - （R 1）r - （R 4）m基团时，R 1表示亚甲基 基团，次甲基或碳原子; r为1〜30; R4代表除氢原子以外的取代基; m为1〜30; - （R 1）r - （R 4）m基团不表示直链烷基。

公开(公告)号：US4837136A

公开(公告)日：1989-06-06

申请号：US917133

申请日：1986-10-09

申请人： Seiji Ichijima ,  Yasuhiro Shimada ,  Jun Arakawa

发明人： Seiji Ichijima ,  Yasuhiro Shimada ,  Jun Arakawa

IPC分类号： C07C67/00 ,  C07C301/00 ,  C07C309/01 ,  C07C309/28 ,  G03C7/32

CPC分类号： G03C7/3212 ,  Y10S430/157 ,  Y10S430/158 ,  Y10S430/159

摘要： A silver halide photographic material is described comprising a support having coated thereon at least one silver halide emulsion layer, wherein at least one of the silver halide emulsion layer and other hydrophilic colloid layer contains a nondiffusible photographically useful compound having a sulfo group and a group represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each represents an aliphatic group having at least 2 carbon atoms and r represents 0 or 1.The compounds represented by the general formula (I) are photographically useful compounds which impart excellent photographic properties to silver halide photographic materials, including improved dispersibility.

摘要翻译： 描述了一种卤化银照相材料，其包括其上涂覆有至少一个卤化银乳剂层的载体，其中卤化银乳剂层和其它亲水胶体层中的至少一种含有具有磺基的非扩散性照相用化合物和表示的基团 通式（I）表示：其中R 1和R 2各自表示具有至少2个碳原子的脂族基团，r表示0或1.由通式（I）表示的化合物是照相的有用的 赋予卤化银照相材料优异照相性能的化合物，包括改进的分散性。

公开(公告)号：US5104783A

公开(公告)日：1992-04-14

申请号：US652478

申请日：1991-02-08

申请人： Yasuhiro Shimada ,  Seiji Ichijima

发明人： Yasuhiro Shimada ,  Seiji Ichijima

IPC分类号： G03C7/32 ,  C07D263/32 ,  C07D277/30 ,  C07D277/32 ,  G03C7/305 ,  G03C7/38

CPC分类号： C07D263/32 ,  C07D277/30 ,  C07D277/32 ,  G03C7/30511 ,  G03C7/38

摘要： The present invention relates to a silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide color photograph material contains a coupler represented by the following general formula (I): ##STR1## wherein X and Y each represents a nitrogen atom or a methine group; n represents 1 or 2, when n is 2, two X's and two Y's may be the same or different; Z represents a non-metallic atomic group necessary to form a heterocyclic ring or aromatic ring together with ##STR2## W represents a hydrogen atom or a group capable of being released upon a reaction with an oxidation product of a developing agent; and R.sub.1 and R.sub.2 each represents a substituent, and at least one of R.sub.1 and R.sub.2 represents an electron attractive sustituent.The silver halide color photographic material containing the cyan dye forming coupler represented by the general formula (I) provides color images excellent in sharpness and preservability.