公开(公告)号：US06559151B2

公开(公告)日：2003-05-06

申请号：US09735126

申请日：2000-12-12

申请人： Klaus Jüergen Pees ,  Frank Schieweck ,  Jordi Tormo I Blasco ,  Hubert Sauter ,  Oliver Cullman ,  Bernd Müller ,  Thomas Grote ,  Andreas Gypser ,  Joachim Rheinheimer ,  Ingo Rose ,  Peter Schäfer ,  Eberhard Ammermann ,  Siegried Strathmann ,  Gisela Lorenz ,  Rheinhard Stierl

发明人： Klaus Jüergen Pees ,  Frank Schieweck ,  Jordi Tormo I Blasco ,  Hubert Sauter ,  Oliver Cullman ,  Bernd Müller ,  Thomas Grote ,  Andreas Gypser ,  Joachim Rheinheimer ,  Ingo Rose ,  Peter Schäfer ,  Eberhard Ammermann ,  Siegried Strathmann ,  Gisela Lorenz ,  Rheinhard Stierl

IPC分类号： A01N4390

CPC分类号： C07D487/04

摘要： 6-(2-Trifluoromethyl-phenyl)-triazolopyrimidines of formula I in which R1 and R2 independently denote hydrogen or alkyl, alkenyl, alkynyl, alkadienyl, or haloalkyl, cycloalkyl, bicycloalkyl, phenyl, naphthyl, or 5- or 6-membered heterocyclyl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or 5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or where R1 and R2 radicals may be unsubstituted or substituted as defined in the specification; or R1 and R2 together with the interjacent nitrogen atom represents a 5- or 6-membered heterocyclic ring, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, which may be substituted as defined in the specification; R3 is hydrogen, halogen, alkyl, alkoxy and haloalkyl; and X is halogen; processes and intermediates for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic fungi are described.

摘要翻译： 具有式Iin的6-（2-三氟甲基 - 苯基） - 三唑并嘧啶，其中R1和R2独立地表示氢或烷基，烯基，炔基，链二烯基或卤代烷基，环烷基，二环烷基，苯基，萘基或5-或6-元杂环基， 至四个氮原子或一至三个氮原子和一个硫或氧原子，或5-或6-元杂芳基，其含有1-4个氮原子或1-3个氮原子和一个硫或氧原子，或其中R1和R2基团可以 如说明书中所定义; 或R 1和R 2与中间的氮原子一起表示含有1至4个氮原子或1至3个氮原子和1个硫或氧原子的5或6元杂环，其可以如说明书中所定义而被取代; R3 是氢，卤素，烷基，烷氧基和卤代烷基; 和X是卤素;描述了制备这些化合物的方法和中间体，包含它们的组合物及其用于控制​​植物病原真菌的用途。

公开(公告)号：US20060241128A1

公开(公告)日：2006-10-26

申请号：US10532719

申请日：2003-11-04

申请人： Jordi Tormo I Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Andreas Gypser ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

发明人： Jordi Tormo I Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Andreas Gypser ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

IPC分类号： A01N43/90 ,  C07D487/04

CPC分类号： C07C69/65 ,  A01N43/90 ,  C07D487/04

摘要： Substituted 6-(2-halogenphenyl)-triazolopyrimidines of formula I in which R1 denote alkyl, alkenyl, alkynyl, alkadienyl, haloalkyl, haloalkenyl, cycloalkyl, phenyl, naphthyl, or a 5- or 6-membered saturated, unsaturated, or aromatic heterocycle, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, wherein R1 and R2 radicals may be substituted as defined in the description, R2 denote hydrogen, or a group mentioned for R1; or R1 and R2 together with the interjacent nitrogen atom represent a 5- or 6-membered heterocycle, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, which ring may be substituted as defined in the description; Hal is halogen; L1, L3 independently denote hydrogen, halogen, or alkyl; L2 is hydrogen, halogen, haloalkyl, or NH2, NHRb, or N(Rb)2, wherein Rb is as defined in the description, wherein at least one from L1, L2, and L3 is not hydrogen; X is halogen, cyano, alkyl, alkoxy, haloalkoxy or alkenyloxy. processes for their preparation, compositions containing them and to their use for combating phytopathogenic fungi.

摘要翻译： 其中R 1表示烷基，烯基，炔基，链二烯基，卤代烷基，卤代烯基，环烷基，苯基，萘基或5-或6-元的取代的6-（2-卤代苯基） - 三唑并嘧啶， 含有1至4个氮原子或1至3个氮原子和1个硫或氧原子的饱和，不饱和或芳族杂环，其中R 1和R 2可以是 如说明书中所定义，R 2表示氢或R 1所提及的基团; 或R 1和R 2连同中间的氮原子代表含有1-4个氮原子或一至三个氮原子的一个或多个六元杂环，一个 硫或氧原子，该环可以如说明书中所定义取代; 卤素是卤素; L 1，L 3独立地表示氢，卤素或烷基; L 2是氢，卤素，卤代烷基或NH 2，NHR b或/或N（R b） 其中R b如描述中所定义，其中至少一个L 1，L 2， ，而L 3不是氢; X是卤素，氰基，烷基，烷氧基，卤代烷氧基或烯氧基。 其制备方法，含有它们的组合物及其用于对抗植物病原真菌的用途。

公开(公告)号：US07501383B2

公开(公告)日：2009-03-10

申请号：US10590368

申请日：2005-03-08

申请人： Jordi Tormo I Blasco ,  Carsten Blettner ,  Bernd Müller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Joachim Rheinheimer ,  Peter Schäfer ,  Frank Schieweck ,  Anja Schwögler ,  Oliver Wagner ,  Matthias Niedenbruck ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schöfl ,  Reinhard Stierl

发明人： Jordi Tormo I Blasco ,  Carsten Blettner ,  Bernd Müller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Joachim Rheinheimer ,  Peter Schäfer ,  Frank Schieweck ,  Anja Schwögler ,  Oliver Wagner ,  Matthias Niedenbruck ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schöfl ,  Reinhard Stierl

IPC分类号： C07D487/04 ,  A01N25/02 ,  A01N25/08 ,  A01N25/26 ,  A01N43/90

CPC分类号： C07D487/04

摘要： The invention relates to 5,6-dialkyl-7-amino-triazolopyrimidines of formula (I), in which the substituents are defined as follows: R1 represents alkyl or alkoxyalkyl; R2 represents alkyl, R1 and/or R2 being substituted according to the description. The invention also relates to a method for producing said compounds, to agents containing the latter and to their use for controlling plant-pathogenic fungi.

摘要翻译： 本发明涉及式（I）的5,6-二烷基-7-氨基 - 三唑并嘧啶，其中取代基定义如下：R1代表烷基或烷氧基烷基; 根据描述，R 2表示烷基，R 1和/或R 2被取代。 本发明还涉及一种生产所述化合物的方法，含有后者的药剂及其用于控制​​植物致病真菌的用途。

公开(公告)号：US20060058326A1

公开(公告)日：2006-03-16

申请号：US10541386

申请日：2004-01-28

申请人： Bernd Muller ,  Thomas Grote ,  Carsten Blettner ,  Markus Gewehr ,  Wassilios Grammenos ,  Andreas Gypser ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Jordi Tormo I Blasco ,  Oliver Wagner ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

发明人： Bernd Muller ,  Thomas Grote ,  Carsten Blettner ,  Markus Gewehr ,  Wassilios Grammenos ,  Andreas Gypser ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Jordi Tormo I Blasco ,  Oliver Wagner ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

IPC分类号： A61K31/513

CPC分类号： C07D239/56 ,  A01N43/54 ,  A01N43/56 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  A01N43/707 ,  A01N43/78 ,  A01N43/82 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D403/04

摘要： Pyrimidines of the formula I in which Ln is as defined in the description and the substituents R1, R2 and R3 are as defined below: R1 is C1-C10-alkyl, C2-C10-alkenyl, C2-C10-alkynyl, C3-C12-cycloalkyl, C3-C10-cycloalkenyl, phenyl or a five- to ten-membered saturated, partially unsaturated or aromatic heterocycle which is attached via carbon and contains one to four heteroatoms from the group consisting of O, N and S; R2 is halogen, cyano, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-alkoxy, C3-C4-alkenyloxy or C3-C4-alkynyloxy, where the alkyl, alkenyl and alkynyl radicals of R2 may be substituted by halogen, cyano, nitro, C1-C2-alkoxy or C1-C4-alkoxycarbonyl; R3 is a five- or six-membered saturated, partially unsaturated or aromatic mono- or bicyclic heterocycle which contains one to four heteroatoms from the group consisting of O, N and S; and processes and intermediates for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic harmful fungi are described.

摘要翻译： 式I的嘧啶

公开(公告)号：US20070105928A1

公开(公告)日：2007-05-10

申请号：US10582938

申请日：2004-12-14

申请人： Jordi Tormo I Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagner ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

发明人： Jordi Tormo I Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagner ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

IPC分类号： A61K31/41

CPC分类号： F02B43/04 ,  F02B19/14 ,  F02B43/10 ,  F02M25/10 ,  Y02T10/121 ,  Y02T10/125 ,  Y02T10/32

摘要： 6-Pentafluorophenyltriazolopyrimidines of the formula I in which the substituents are as defined below: R1 is alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, cycloalkenyl, halocycloalkenyl, alkinyl, haloalkinyl or phenyl, naphthyl, or a five- or six-membered saturated, partially unsaturated or aromatic heterocycle which contains one to four heteroatoms from the group consisting of O, N and S, R2 is hydrogen or one of the groups mentioned under R1, R1 and R2 together with the nitrogen atom to which they are attached may also form a five- or six-membered heterocyclyl or heteroaryl which is attached via N and may contain one to three further heteroatoms from the group consisting of O, N and S as ring members; R1 and/or R2 may be substituted as defined in the description; X is cyano, alkyl, alkoxy, alkenyloxy, haloalkoxy or haloalkenyloxy, processes for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic harmful fungi.

摘要翻译： 式I的6-五氟苯基三唑并嘧啶，其中取代基如下：R 1是烷基，卤代烷基，环烷基，卤代环烷基，烯基，卤代烯基，环烯基，卤代环烯基，炔基，卤代炔基或苯基，萘基， 或五元或六元饱和，部分不饱和或芳族杂环，其含有一至四个由O，N和S组成的组的杂原子，R 2是氢或下述基团之一 R 1，R 1和R 2与它们所连接的氮原子一起也可以形成五元或六元杂环基 或杂芳基，其通过N连接并且可以含有一个至三个由O，N和S组成的组的另外的杂原子作为环成员; R 1和/或R 2可以如说明书中所定义的取代; X是氰基，烷基，烷氧基，烯氧基，卤代烷氧基或卤代烯氧基，制备这些化合物的方法，包含它们的组合物及其用于控制​​植物病原性有害真菌的用途。

公开(公告)号：US20070078149A1

公开(公告)日：2007-04-05

申请号：US10580416

申请日：2004-12-16

申请人： Jordi Tormo I Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagner ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

发明人： Jordi Tormo I Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagner ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

IPC分类号： A01N43/90 ,  C07D487/04

CPC分类号： C07D487/04 ,  A01N43/90

摘要： Triazolopyrimidines of the formula I in which the substituents are as defined below: R1, R2 are hydrogen, alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, cycloalkenyl, halocycloalkenyl, alkynyl, haloalkynyl or phenyl, naphthyl, or a five- or six-membered saturated, partially unsaturated or aromatic heterocycle which contains one to four heteroatoms from the group consisting of O, N and S, R1 and R2 together with the nitrogen atom to which they are attached may also form a five- or six-membered heterocyclyl or heteroaryl which is attached via N and may contain a further heteroatom from the group consisting of O, N and S as ring member and may be substituted as defined in the description; L1, L2 are hydrogen, cyano, haloalkyl, alkoxy, alkenyloxy or C(═O)A, where at least one group L1 or L2 is not hydrogen; A is hydrogen, hydroxyl, alkyl, alkoxy, haloalkoxy, C1-C8-alkylamino or dialkylamino; L3 is hydrogen, halogen, cyano, nitro, haloalkyl, alkoxy or alkoxycarbonyl; X is halogen, cyano, alkyl, haloalkyl, alkoxy or haloalkoxy; processes and intermediates for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic harmful fungi.

摘要翻译： 其中取代基如下定义的式I的三唑并嘧啶：R 1，R 2是氢，烷基，卤代烷基，环烷基，卤代环烷基，烯基，卤代烯基，环烯基， 卤代环烯基，炔基，卤代炔基或苯基，萘基或五或六元饱和的部分不饱和或芳族杂环，其含有一至四个由O，N和S组成的组的杂原子，R 1 和R 2与它们所连接的氮原子一起也可以形成五元或六元杂环基或杂芳基，其通过N连接并且可以含有来自以下的另外的杂原子： O，N和S作为环成员，并且可以如说明书中所定义的取代; L 1，L 2是氢，氰基，卤代烷基，烷氧基，烯氧基或C（-O）A，其中至少一个基团L 1 >或L 2不是氢; A是氢，羟基，烷基，烷氧基，卤代烷氧基，C 1 -C 8烷基氨基或二烷基氨基; L 3是氢，卤素，氰基，硝基，卤代烷基，烷氧基或烷氧基羰基; X是卤素，氰基，烷基，卤代烷基，烷氧基或卤代烷氧基; 制备这些化合物的方法和中间体，包含它们的组合物及其用于控制​​植物病原性有害真菌的用途。

公开(公告)号：US20060100220A1

公开(公告)日：2006-05-11

申请号：US10532769

申请日：2003-11-14

申请人： Jordi Tormo I Blasco ,  Thomas Grote ,  Eberhard Ammermann ,  Reinhard Stierl ,  Siegfried Strathmann ,  Ulrich Schofl

发明人： Jordi Tormo I Blasco ,  Thomas Grote ,  Eberhard Ammermann ,  Reinhard Stierl ,  Siegfried Strathmann ,  Ulrich Schofl

IPC分类号： A01N43/90 ,  A01N43/80 ,  A01N43/50

CPC分类号： A01N43/90 ,  A01N2300/00

摘要： Fungicidal mixtures, comprising A) the triazolopyrimidine of the formula I and B) imidazole derivatives of the formula II where X1 and X2 are halogen and phenyl which may be substituted by halogen or alkyl or X1 and X2 together with the bridging C═C double bond form a difluoromethylenedioxyphenyl group; X3 is cyano or halogen, and X4 is dialkylamino or isoxazol-4-yl which may carry two alkyl radicals, in a synergistically effective amount, methods for controlling harmful fungi using mixtures of the compounds I and II, compositions comprising these compounds and the use of the compounds I and II for preparing such mixtures are described.

摘要翻译： 杀真菌混合物，其包含A）式I的三唑并嘧啶和B）式II的咪唑衍生物，其中X 1和X 2是卤素和可以被 卤素或烷基或X 1和X 2连同桥连CC双键形成二氟亚甲二氧基苯基; X 3是氰基或卤素，X 4是可以以协同有效量存在两个烷基的二烷基氨基或异恶唑-4-基，用于控制有害真菌的方法 描述了使用化合物I和II的混合物，包含这些化合物的组合物和化合物I和II用于制备这些混合物的用途。

公开(公告)号：US20060063786A1

公开(公告)日：2006-03-23

申请号：US10532841

申请日：2003-11-14

申请人： Jordi Tormo I Blasco ,  Thomas Grote ,  Eberhard Ammermann ,  Reinhard Stierl ,  Siegfried Strathman ,  Ulrich Schofl

发明人： Jordi Tormo I Blasco ,  Thomas Grote ,  Eberhard Ammermann ,  Reinhard Stierl ,  Siegfried Strathman ,  Ulrich Schofl

IPC分类号： A01N43/90 ,  A01N37/18

CPC分类号： A01N43/90 ,  A01N37/50 ,  A01N2300/00

摘要： Fungicidal mixtures for controlling rice pathogens, comprising, as active components, 1) the compound of the formula I, and 2) the compound of the formula II, in a synergistically effective amount, methods for controlling harmful fungi using mixtures of the compound I with the compound II, the use of the compounds I and II for preparing such mixtures and compositions comprising these mixtures are described.

摘要翻译： 用于防治水稻病原体的杀真菌混合物，包括作为活性成分

公开(公告)号：US20070197557A1

公开(公告)日：2007-08-23

申请号：US11596468

申请日：2005-05-11

申请人： Jordi Tormo I Blasco ,  Thomas Grote ,  Maria Scherer ,  Reinhard Stierl ,  Siegfried Strathmann ,  Ulrich Schofl ,  Joachim Rheinheimer

发明人： Jordi Tormo I Blasco ,  Thomas Grote ,  Maria Scherer ,  Reinhard Stierl ,  Siegfried Strathmann ,  Ulrich Schofl ,  Joachim Rheinheimer

IPC分类号： A01N43/54 ,  A01N43/90

CPC分类号： A01N43/90 ,  A01N43/86 ,  A01N43/54 ,  A01N43/16 ,  A01N43/42 ,  A01N2300/00

摘要： Fungicidal mixtures comprising, as active components, 1) the triazolopyrimidine derivative of the formula I and 2) at least one compound of the formula II, in which the variables are as defined below: A is O or N; B is N or a direct bond; G is C or N; R1 alkyl; R2 alkoxy; and R3 is halogen; in a synergistically effective amount, methods for controlling harmful fungi using mixtures of the compound I with compounds II and the use of the compound I with compounds II for preparing such mixtures, and also compositions comprising these mixtures.

摘要翻译： 作为活性组分的杀真菌混合物包括1）式I的三唑并嘧啶衍生物和2）至少一种式II化合物，其中变量如下所定义：A是O或N; B是N或直接键; G为C或N; R 1烷基; R 2烷氧基; R 3是卤素; 协同有效量的方法，使用化合物I与化合物II的混合物来控制有害真菌，以及化合物I与化合物II用于制备这种混合物的用途，以及包含这些混合物的组合物。

公开(公告)号：US07601673B2

公开(公告)日：2009-10-13

申请号：US11579085

申请日：2005-04-23

申请人： Jordi Tormo I Blasco ,  Thomas Grote ,  Maria Scherer ,  Reinhard Stierl ,  Siegfried Strathmann ,  Ulrich Schöfl ,  Markus Gewehr ,  Bernd Müller ,  Miguel Octavio Suarez-Cervieri ,  Matthias Niedenbrück

发明人： Jordi Tormo I Blasco ,  Thomas Grote ,  Maria Scherer ,  Reinhard Stierl ,  Siegfried Strathmann ,  Ulrich Schöfl ,  Markus Gewehr ,  Bernd Müller ,  Miguel Octavio Suarez-Cervieri ,  Matthias Niedenbrück

IPC分类号： A01N25/00 ,  A01N59/04

CPC分类号： A01N43/653 ,  A01N35/04 ,  A01N37/20 ,  A01N37/24 ,  A01N37/34 ,  A01N37/36 ,  A01N37/52 ,  A01N43/16 ,  A01N43/40 ,  A01N43/42 ,  A01N43/54 ,  A01N43/78 ,  A01N43/86 ,  A01N43/90 ,  A01N47/04 ,  A01N47/12 ,  A01N47/18 ,  A01N47/20 ,  A01N47/38

摘要： Fungicidal mixtures, comprising, as active components, 1) a sulfamoyl compound of the formula I,  in which the substituents are as defined below: R1 is hydrogen, halogen, cyano, alkyl, haloalkyl, alkoxy, alkylthio, alkoxycarbonyl, phenyl, benzyl, formyl or CH═NOA; A is hydrogen, alkyl, alkylcarbonyl; R2 is hydrogen, halogen, cyano, alkyl, haloalkyl, alkoxycarbonyl; R3 is halogen, cyano, nitro, alkyl, haloalkyl, alkoxy, alkylthio, alkoxycarbonyl, formyl or CH═NOA; n is 0, 1, 2, 3 or 4; R4 is hydrogen, halogen, cyano, alkyl or haloalkyl; and 2) at least one active compound selected from the following groups: A) azoles; B) strobilurins; C) acylalanines; D) amine derivatives; E) anilinopyrimidines; F) dicarboximides; G) cinnamides and analogs; H) dithiocarbamates; I) heterocylic compounds; K) sulfur and copper fungicides; L) nitrophenyl derivatives; M) phenylpyrroles; N) sulfenic acid derivatives; O) other fungicides; according to the description; in a synergistically effective amount, methods for controlling harmful fungi using mixtures of a compound I with active compounds of groups A) to O) and the use of the compounds I with active compounds of groups A) to O) for preparing such mixtures, and also compositions comprising these mixtures.

摘要翻译： 作为活性组分的杀真菌混合物，1）式I的氨磺酰基化合物，其中取代基如下：R 1是氢，卤素，氰基，烷基，卤代烷基，烷氧基，烷硫基，烷氧基羰基，苯基，苄基， 甲酰基或CH-NOA; A是氢，烷基，烷基羰基; R2是氢，卤素，氰基，烷基，卤代烷基，烷氧基羰基; R3是卤素，氰基，硝基，烷基，卤代烷基，烷氧基，烷硫基，烷氧基羰基，甲酰基或CH-NOA; n为0,1,2,3或4; R4是氢，卤素，氰基，烷基或卤代烷基; 和2）至少一种选自以下组的活性化合物：A）唑类; B）嗜球果伞素 C）酰基丙氨酸; D）胺衍生物; E）苯胺嘧啶嘧啶; F）二羧酰亚胺; G）肉桂酸酯类似物; H）二硫代氨基甲酸盐; I）杂环化合物; K）硫和铜杀菌剂; L）硝基苯基衍生物; M）苯基吡咯; N）亚磺酸衍生物; O）其他杀菌剂; 根据说明; 协同有效量的方法，使用化合物I与基团A）至O）的活性化合物的混合物控制有害真菌的方法，以及将化合物I与基团A）至O）的活性化合物用于制备此类混合物的用途，以及 也包含这些混合物的组合物