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公开(公告)号：US20090169494A1
公开(公告)日：2009-07-02
申请号：US11991350
申请日：2006-09-29
申请人： Koji Abe , Nozomi Oguchi , Isao Yajima , Hidefumi Araki , Hiroyuki Kakoki
发明人： Koji Abe , Nozomi Oguchi , Isao Yajima , Hidefumi Araki , Hiroyuki Kakoki
IPC分类号： A61K8/49
CPC分类号： A61K8/4966 , A61K8/496 , A61K8/585 , A61Q17/04
摘要： The present invention is a sunscreen cosmetic comprising 2,4-bis[[4-(2-ethylhexyloxy)-2-hydroxy]phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine and a specific benzotriazole derivative.Also, the present invention is a sunscreen cosmetic comprising a specific benzotriazole derivative and a specific alkylaryl 1,3-propanedione silicone derivative.An object of the present invention is to provide a sunscreen cosmetic that exhibits superior UV-A absorption capacity and excellent stability and also sufficiently dissolves 2,4-bis[[4-(2-ethylhexyloxy)-2-hydroxy]phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine, which has low solubility and crystallizes easily.Another object is to provide a sunscreen cosmetic that can synergistically improve the ultraviolet absorption capacity of conventional ultraviolet absorbents.
摘要翻译： 本发明是包含2,4-双[[4-（2-乙基己氧基）-2-羟基]苯基] -6-（4-甲氧基苯基）-1,3,5-三嗪和特定苯并三唑衍生物的防晒化妆品 。 此外，本发明是包含特定的苯并三唑衍生物和特定的烷基芳基-1,3-丙二酮硅氧烷衍生物的防晒化妆品。 本发明的目的是提供一种防紫外线化妆品，其具有优异的UV-A吸收能力和优异的稳定性，并且还充分溶解2,4-双[[4-（2-乙基己氧基）-2-羟基]苯基] -6 - （4-甲氧基苯基）-1,3,5-三嗪，其溶解度低，结晶容易。 另一个目的是提供可协同地提高常规紫外线吸收剂的紫外线吸收能力的防晒化妆品。
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公开(公告)号：US20100221199A1
公开(公告)日：2010-09-02
申请号：US12095713
申请日：2006-12-19
申请人： Hidefumi Araki , Koji Abe , Isao Yajima , Hiroyuki Kakoki , Nozomi Oguchi
发明人： Hidefumi Araki , Koji Abe , Isao Yajima , Hiroyuki Kakoki , Nozomi Oguchi
CPC分类号： A61K8/496 , A61K2800/26 , A61Q17/04
摘要： The present invention is a sunscreen cosmetic comprising 4-(1,1-dimethylethyl)-4′-methoxydibenzoylmethane, a benzotriazole derivative represented by the following general formula (I), and ethylhexyl 2-cyano-3,3-diphenylacrylate.The present invention is a sunscreen cosmetic comprising hexyl diethylaminohydroxybenzoylbenzoate and a benzotriazole derivative represented by the following general formula (I). (In this formula, R′=a straight chain alkyl group of C1-C6 and R″=a straight chain alkyl group of C1-C3.)The object of the present invention is to provide a sunscreen cosmetic that prevents staining due to secondary adhesion to clothing.
摘要翻译： 本发明是包含4-（1,1-二甲基乙基）-4'-甲氧基二苯甲酰甲烷，由以下通式（I）表示的苯并三唑衍生物和2-氰基-3,3-二苯基丙烯酸乙基己酯的防晒化妆品。 本发明是一种包含二乙基氨基羟基苯甲酰基苯甲酸己酯和由以下通式（I）表示的苯并三唑衍生物的防晒化妆品。 （在该式中，R'= C1-C6的直链烷基，R“= C1-C3的直链烷基。）本发明的目的是提供防止二次染色的防晒化妆品 对衣服的粘附。
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公开(公告)号：US08691191B2
公开(公告)日：2014-04-08
申请号：US13125982
申请日：2009-10-27
摘要： The present invention provides an O/W emulsified composition which contains an organic UV absorber in an oil state such as octocrylene and a solid organic UV absorber, and is excellent in UV protection ability, formulation stability, and feeling in use. The composition according to the present invention is an O/W emulsified composition, comprising: (a) an organic UV absorber in an oil state at 20° C., comprising (a1) octocrylene; (b) an organic UV absorber in a solid state at 20° C., selected from (b1) bis-ethylhexyloxyphenol methoxyphenyl triazine and (b2) methylene bis-benzotriazolyl tetramethylbutylphenol; and (c) a polyoxyethylene/polyoxyalkylene alkyl ether block polymer represented by formula (1) or (2): R1O—(PO)m-(EO)n-H (1) wherein R1 is a hydrocarbon group having 16 to 18 carbon atoms; PO is an oxypropylene group, EU is an oxyethylene group, and PO and EO are added to each other in block form; and m and n respectively represent average addition mole number of PO and EO, 70>m>4, 70>n>10, and n>m; R2O-(AO)p-(EO)q-R3 (2) wherein R2 and R3 are either identical to or different from each other, and each of them is a hydrocarbon group having 1 to 4 carbon atoms; AO is an oxyalkylene group having 3 to 4 carbon atoms, EO is an oxyethylene group, and AO and EO are added to each other in block form; and p and q respectively represent average addition mole number of AO and EO, 1≦p≦70, 1≦q≦70, and 0.2
摘要翻译： 本发明提供一种O / W乳化组合物，其含有油状态的有机紫外线吸收剂，如辛酸和固体有机紫外线吸收剂，并且具有优异的紫外线防护能力，制剂稳定性和使用感。 根据本发明的组合物是O / W乳化组合物，其包含：（a）在20℃的油状态的有机UV吸收剂，包含（a1） （b）在20℃下为固态的有机紫外线吸收剂，选自（b1）双 - 乙基己氧基苯酚甲氧基苯基三嗪和（b2）亚甲基双苯并三唑基四甲基丁基苯酚; 和（c）由式（1）或（2）表示的聚氧乙烯/聚氧化烯烷基醚嵌段聚合物：R1O-（PO）m-（EO）n-H（1）其中R1是具有16-18个碳原子的烃基; PO是氧化亚丙基，EU是氧化乙烯基，PO和EO以嵌段形式彼此相加; m和n分别表示PO和EO的平均加成摩尔数，70> m> 4，70> n> 10，n> m; R2O-（AO）对（EO）q-R3（2）其中R2和R3彼此相同或不同，并且它们各自是具有1至4个碳原子的烃基; AO是具有3〜4个碳原子的氧化烯基，EO是氧化乙烯基，AO和EO以嵌段形式彼此相加; 和p和q分别表示AO和EO的平均加成摩尔数，1＆nlE; p＆nlE; 70,1＆nlE; q＆nlE; 70和0.2（q /（p + q））<0.8， 包含组分（a）的相是700nm或更小。
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公开(公告)号：US20130004553A1
公开(公告)日：2013-01-03
申请号：US13583659
申请日：2011-01-19
申请人： Tomiko Takakura , Takafumi Kurosawa , Isao Yajima
发明人： Tomiko Takakura , Takafumi Kurosawa , Isao Yajima
摘要： An O/W emulsion composition which is excellent in UV protection ability, formulation stability, and feeling in use. The O/W emulsion composition includes the following components (a) and (b): (a) organic UV absorbers comprising the following components (a1), (a2), and (a3): (a1) octocrylene, (a2) ethylhexyl methoxycinnamate, (a3) 4-t-butyl-4′-methoxydibenzoylmethane; and (b) a polyoxyethylene/polyoxyalkylene alkyl ether block polymer represented by the following formula (1) or (2); —R1O—(PO)m-(EO)n-H (1); R2O-(AO)p-(EO)q-R3 (2).
摘要翻译： 具有优异的紫外线防护能力，配方稳定性和使用感的O / W乳液组合物。 O / W乳液组合物包括以下组分（a）和（b）：（a）包含以下组分（a1），（a2）和（a3）的有机UV吸收剂：（a1）辛格林，（a2） 甲氧基肉桂酸甲酯，（a3）4-叔丁基-4'-甲氧基二苯甲酰甲烷; 和（b）由下式（1）或（2）表示的聚氧乙烯/聚氧化烯烷基醚嵌段聚合物; -R 10 - （PO）m - （EO）n -H（1）; R2O-（AO）p-（EO）q-R3（2）。
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公开(公告)号：US20110206628A1
公开(公告)日：2011-08-25
申请号：US13125982
申请日：2009-10-27
摘要： The present invention provides an O/W emulsified composition which contains an organic UV absorber in an oil state such as octocrylene and a solid organic UV absorber, and is excellent in UV protection ability, formulation stability, and feeling in use. The composition according to the present invention is an O/W emulsified composition, comprising: (a) an organic UV absorber in an oil state at 20° C., comprising (a1) octocrylene; (b) an organic UV absorber in a solid state at 20° C., selected from (b1) bis-ethylhexyloxyphenol methoxyphenyl triazine and (b2) methylene bis-benzotriazolyl tetramethylbutylphenol; and (c) a polyoxyethylene/polyoxyalkylene alkyl ether block polymer represented by formula (1) or (2): R1O—(PO)m-(EO)n-H (1) wherein R1 is a hydrocarbon group having 16 to 18 carbon atoms; PO is an oxypropylene group, EU is an oxyethylene group, and PO and EO are added to each other in block form; and m and n respectively represent average addition mole number of PO and EO, 70>m>4, 70>n>10, and n>m; R2O-(AO)p-(EO)q-R3 (2) wherein R2 and R3 are either identical to or different from each other, and each of them is a hydrocarbon group having 1 to 4 carbon atoms; AO is an oxyalkylene group having 3 to 4 carbon atoms, EO is an oxyethylene group, and AO and EO are added to each other in block form; and p and q respectively represent average addition mole number of AO and EO, 1≦p≦70, 1≦q≦70, and 0.2
摘要翻译： 本发明提供一种O / W乳化组合物，其含有油状态的有机紫外线吸收剂，如辛酸和固体有机紫外线吸收剂，并且具有优异的紫外线防护能力，制剂稳定性和使用感。 根据本发明的组合物是O / W乳化组合物，其包含：（a）在20℃的油状态的有机UV吸收剂，包含（a1） （b）在20℃下为固态的有机紫外线吸收剂，选自（b1）双 - 乙基己氧基苯酚甲氧基苯基三嗪和（b2）亚甲基双苯并三唑基四甲基丁基苯酚; 和（c）由式（1）或（2）表示的聚氧乙烯/聚氧化烯烷基醚嵌段聚合物：R1O-（PO）m-（EO）n-H（1）其中R1是具有16-18个碳原子的烃基; PO是氧化亚丙基，EU是氧化乙烯基，PO和EO以嵌段形式彼此相加; m和n分别表示PO和EO的平均加成摩尔数，70> m> 4，70> n> 10，n> m; R2O-（AO）对（EO）q-R3（2）其中R2和R3彼此相同或不同，并且它们各自是具有1至4个碳原子的烃基; AO是具有3〜4个碳原子的氧化烯基，EO是氧化乙烯基，AO和EO以嵌段形式彼此相加; 和p和q分别表示AO和EO的平均加成摩尔数，1＆nlE; p＆nlE; 70,1＆nlE; q＆nlE; 70和0.2（q /（p + q））<0.8， 包含组分（a）的相是700nm或更小。
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公开(公告)号：US20100288296A1
公开(公告)日：2010-11-18
申请号：US12747607
申请日：2008-11-20
申请人： Motoki Takata , Isao Yajima
发明人： Motoki Takata , Isao Yajima
IPC分类号： A45D40/26
CPC分类号： A45D40/262 , A46B9/021 , A46B9/028 , A46B2200/106
摘要： An object of the present invention is to provide a mascara applicator capable of being fitted to the curved bases of eyelashes to lift up eyelashes, providing voluminousness to the eyelashes by adhering a mascara to the bases of the eyelashes, widely applying the mascara so that the eyelashes expand in the form of a fan, properly and widely applying the mascara to detailed parts such as the tail and inner corner of the eye, as well as lower eyelashes, and also obtaining an all direction expansion mascara application result. A mascara applicator (1), which has a long core member (2), and an application part configured by an upper application part (5) and a lower application part (6) that are supported by the core member (2), extend from the core member to the outside in a horizontal sectional direction, carry a mascara thereon, and apply the mascara to eyelashes, the lower application part being set to be shorter than the upper application part in the horizontal section, wherein a cross section of the upper application part along a longitudinal direction of an axis of the core member is shaped into a series of crests with one and half crests along the longitudinal direction between a base end part and tip part of the core member.
摘要翻译： 本发明的一个目的是提供一种睫毛膏涂抹器，其能够被装配到睫毛的弯曲基部以提起睫毛，通过将睫毛膏粘附到睫毛的基部上来广泛地施加睫毛，从而提供睫毛的体积，从而使睫毛膏 睫毛以风扇的形式扩展，适当地广泛地将睫毛膏应用到眼睛的尾部和内角以及下睫毛等细节部分，并且还获得全方向扩张睫毛膏的应用结果。 具有长芯构件（2）的睫毛膏涂敷器（1）和由所述芯构件（2）支撑的上施加部（5）和下施加部（6）构成的施加部延伸 在水平剖面方向从芯部件到外部，在其上携带睫毛膏，并将睫毛膏施加到睫毛上，下部施加部被设定为比水平部分中的上部施加部分短，其中， 沿着芯构件的轴线的纵向的上部施加部分被成形为在芯构件的基端部分和尖端部分之间沿着纵向方向具有一个和一个顶部的一系列顶部。
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公开(公告)号：US08291920B2
公开(公告)日：2012-10-23
申请号：US12747607
申请日：2008-11-20
申请人： Motoki Takata , Isao Yajima
发明人： Motoki Takata , Isao Yajima
IPC分类号： A45D40/26
CPC分类号： A45D40/262 , A46B9/021 , A46B9/028 , A46B2200/106
摘要： An object of the present invention is to provide a mascara applicator capable of being fitted to the curved bases of eyelashes to lift up eyelashes, providing voluminousness to the eyelashes by adhering a mascara to the bases of the eyelashes, widely applying the mascara so that the eyelashes expand in the form of a fan, properly and widely applying the mascara to detailed parts such as the tail and inner corner of the eye, as well as lower eyelashes, and also obtaining an all direction expansion mascara application result. A mascara applicator (1), which has a long core member (2), and an application part configured by an upper application part (5) and a lower application part (6) that are supported by the core member (2), extend from the core member to the outside in a horizontal sectional direction, carry a mascara thereon, and apply the mascara to eyelashes, the lower application part being set to be shorter than the upper application part in the horizontal section, wherein a cross section of the upper application part along a longitudinal direction of an axis of the core member is shaped into a series of crests with one and half crests along the longitudinal direction between a base end part and tip part of the core member.
摘要翻译： 本发明的目的是提供一种睫毛膏涂抹器，其能够被装配到睫毛的弯曲的基部以提起睫毛，通过将睫毛膏粘附到睫毛的基部，从而提供睫毛的大量，从而广泛应用睫毛膏，使得 睫毛以风扇的形式扩展，适当地广泛地将睫毛膏应用到眼睛的尾部和内角以及下睫毛等细节部分，并且还获得全方向扩张睫毛膏的应用结果。 具有长芯构件（2）的睫毛膏涂敷器（1）和由所述芯构件（2）支撑的上施加部（5）和下施加部（6）构成的施加部延伸 在水平剖面方向从芯部件到外部，在其上携带睫毛膏，并将睫毛膏施加到睫毛上，下部施加部被设定为比水平部分中的上部施加部分短，其中， 沿着芯构件的轴线的纵向的上部施加部分被成形为在芯构件的基端部分和尖端部分之间沿着纵向方向具有一个和一个顶部的一系列顶部。
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8.发明申请WATER-SOLUBLE METAL ALCOHOLATE DERIVATIVES, PRODUCTION METHODS THEREOF, AND SOLID GELATINOUS EXTERNAL PREPARATIONS CONTAINING THE SAME 审中-公开水溶性金属醇盐衍生物，其生产方法和含有其的固体外消旋制剂公开(公告)号：US20090149554A1
公开(公告)日：2009-06-11
申请号：US12063275
申请日：2006-08-11
申请人： Yuko Ishikawa , Katzutami Sakamoto , Toshikhiko Seki , Isao Yajima , Shun Takahashi , Kei Watanabe
发明人： Yuko Ishikawa , Katzutami Sakamoto , Toshikhiko Seki , Isao Yajima , Shun Takahashi , Kei Watanabe
CPC分类号： C07F7/045 , A61K9/0014 , A61K47/10 , C07C31/20
摘要： The object of the present invention is to provide a production method of water-soluble silane derivatives, the separation and purification of which are easy, and the reaction for which can be conducted under an industrially practicable temperature condition (under the temperature condition of 90° C. or lower) and to provide compounds with which solid gelatinous external preparations, with excellent stability against a temperature change and against an effect of additives and with excellent usability, can be prepared. The water-soluble silane derivative could be formed by the substitution reaction of a metal alkoxide with a polyhydric alcohol under the presence of a solid catalyst. According to this production method, the separation of the catalyst from the product is very easy, and the reaction can be carried out under the temperature condition of 90° C. or lower. The obtained water-soluble metal alcoholate derivative can satisfactory solidify an aqueous formulation of an external preparation by its blending thereinto. The obtained solid gelatinous external preparation has excellent stability against a temperature change and against the effect of additives. In addition, the external preparation is easily disintegrated during use; thus the usability such as easiness to be scooped up with fingers and spreadability during application is excellent.
摘要翻译： 本发明的目的是提供一种水溶性硅烷衍生物的制造方法，其分离纯化容易，其反应可以在工业上可行的温度条件下（在90℃的温度条件下进行） C.或更低），并且可以制备具有优异的耐温度变化稳定性和抗添加剂效果以及优异可用性的固体胶状外用制剂的化合物。 水溶性硅烷衍生物可以通过金属醇盐与多元醇在固体催化剂存在下的取代反应形成。 根据该制造方法，催化剂与产物的分离非常容易，反应可以在90℃以下的温度条件下进行。 所得到的水溶性金属醇化物衍生物可以通过其混合来使外用制剂的水性制剂充分固化。 所得固体凝胶状外用制剂对温度变化和添加剂的效果具有优异的稳定性。 此外，外用制剂在使用过程中容易分解; 因此在使用时易于用手指舀起的可用性和铺展性优异。
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