摘要:
1. A non-aqueous electrolytic solution comprising an electrolytic salt in a non-aqueous solvent, which further contains a pentafluorophenoxy compound having the formula (I): in which R represents a substituting group such as an alkylcarbonyl group, an alkoxycarbonyl group, an aryloxy-carbonyl group, and an alkanesulfonyl group, under the condition that at least one hydrogen atom contained in the substituting group can be substituted with a halogen atom or an aryl group.
摘要:
1. A non-aqueous electrolytic solution comprising an electrolytic salt in a non-aqueous solvent, which further contains a pentafluorophenoxy compound having the formula (I): in which R represents a substituting group such as an alkylcarbonyl group, an alkoxycarbonyl group, an aryloxy-carbonyl group, and an alkanesulfonyl group, under the condition that at least one hydrogen atom contained in the substituting group can be substituted with a halogen atom or an aryl group.
摘要:
A lithium secondary battery comprising a positive electrode, a negative electrode of artificial graphite or natural graphite and a nonaqueous electrolytic solution having an electrolyte dissolved in a nonaqueous solvent, wherein 0.1 to 20 wt. % of a cyclohexylbenzene having a halogen atom bonded to a benzene ring thereof is contained in the nonaqueous electrolytic solution exhibits large electric capacity and excellent cycle performance.
摘要:
The invention provides a lithium secondary battery which is excellent in long-term cycle property and in battery characteristics, such as electric capacity and storage property, and a nonaqueous electrolytic solution usable for such a lithium secondary battery. The present invention relates to a lithium secondary battery including a positive electrode, a negative electrode, and a nonaqueous electrolytic solution containing an electrolyte salt dissolved in a nonaqueous solvent, characterized in that the positive electrode is made of a material including a lithium compound oxide, in that the negative electrode is made of a material including graphite, and in that the nonaqueous electrolytic solution contains dialkyl oxalate and further contains vinylene carbonate and/or 1,3-propanesultone, and a nonaqueous electrolytic solution for use in such a battery.
摘要:
The invention provides a lithium secondary battery which is excellent in long-term cycle property and in battery characteristics, such as electric capacity and storage property, and a nonaqueous electrolytic solution usable for such a lithium secondary battery. The present invention relates to a lithium secondary battery including a positive electrode, a negative electrode, and a nonaqueous electrolytic solution containing an electrolyte salt dissolved in a nonaqueous solvent, characterized in that the positive electrode is made of a material including a lithium compound oxide, in that the negative electrode is made of a material including graphite, and in that the nonaqueous electrolytic solution contains dialkyl oxalate and further contains vinylene carbonate and/or 1,3-propanesultone, and a nonaqueous electrolytic solution for use in such a battery.
摘要:
The present invention provides a lithium secondary battery which is improved in cycle characteristics and storage stability at an elevated temperature as well as protection from overcharge. In the battery, generation of a gas is also inhibited to prevent the battery from expansion. A non-aqueous electrolytic solution for the lithium secondary battery has an electrolyte in a non-aqueous solvent. The non-aqueous solvent is composed of a cyclic carbonate compound, a linear carbonate compound and a cyclohexylbenzene compound having a benzene ring to which one or two halogen atoms are attached. A volume ratio of the cyclic carbonate compound and the linear carbonate compound in the non-aqueous solvent is in the range of 20:80 to 40:60, or the non-aqueous solvent further contains a small amount of a branched alkylbenzene compound.
摘要:
The present invention provides a lithium secondary battery which is improved in cycle characteristics and storage stability at an elevated temperature as well as protection from overcharge. In the battery, generation of a gas is also inhibited to prevent the battery from expansion. A non-aqueous electrolytic solution for the lithium secondary battery has an electrolyte in a non-aqueous solvent. The non-aqueous solvent is composed of a cyclic carbonate compound, a linear carbonate compound and a cyclohexylbenzene compound having a benzene ring to which one or two halogen atoms are attached. A volume ratio of the cyclic carbonate compound and the linear carbonate compound in the non-aqueous solvent is in the range of 20:80 to 40:60, or the non-aqueous solvent further contains a small amount of a branched alkylbenzene compound.
摘要:
In order to manufacture a lithium secondary battery having excellent performances in safety under overcharge condition, cycle property, electric capacity, and storage endurance, 0.1 wt. % to 10 wt. of a tert-alkylbenzene compound is favorably incorporated into a non-aqueous electrolytic solution comprising a non-aqueous solvent and an electrolyte, preferably in combination with 0.1 wt. % to 1.5 wt. % of a biphenyl compound.
摘要:
An electrolysis solution for electrolytic capacitors including an aqueous organic solvent consisting of water and a water-compatible organic solvent and 1,6-decane-dicarboxylic acid or salt thereof dissolved therein. The solution further contains one or more additives selected from dinitriles, pivalic acid and salts thereof, diesters, alkylated lactones, cyanoalkanoic esters, monocarbboxylic acids each having a C3-7 alkyl chain and substituted with two C1-4 alkyl groups at the &bgr;-position to the carboxyl group and salts thereof, monocarboxylic acids each having C3-7 alkyl chain and substituted with one ethyl group at the &agr;-position to the carboxyl group and salts thereof, and monocarboxylic acids derived from cyclic saturated compounds each having five or six ring-constituting carbon atoms and salts thereof. When one or more compounds selected from among dinitriles, diesters, alkylated lactones and cyanoalkanoic esters are used as the additives, the 1,6-decanedicarboxylic acid may be replaced by other carboxylic acid.
摘要:
A non-aqueous electrolyte comprising (i) a non-aqueous solvent and (ii) an electrolyte salt dissolved therein and (iii) a disulfonate ester derivative having the formula (I): wherein R indicates a C1 to C6 alkyl group and X indicates a straight-chain alkylene group having a C2-C6 principal chain or a branched alkylene group having a C2-C6 principal chain with at least one side-chain composed of a. C1-C4 alkyl group, and also a lithium secondary battery using the same are disclosed.