公开(公告)号：US09647294B2

公开(公告)日：2017-05-09

申请号：US13576182

申请日：2011-02-02

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

IPC分类号： H01M10/056 ,  C07C309/70 ,  C07C309/68 ,  C07C309/67 ,  H01M10/0567 ,  H01M10/052 ,  C07F9/113 ,  C07F9/32

CPC分类号： H01M10/0567 ,  C07C309/67 ,  C07F9/113 ,  C07F9/327 ,  H01M10/052 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

摘要： The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it.The nonaqueous electrolytic solution of the present invention comprises containing at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. R1(O)n—X1—R2  (I) (In the formula, X1 represents a group —C(═O)—, a group —C(═O)—C(═O)—, a group —S(═O)2—, a group —P(═O) (—R3)—, or a group —X3—S(═O)2O—. R1 represents an alkenyl group, a formyl group, an alkyl group, an acyl group, an arylcarbonyl, an alkanesulfonyl group, an alkynyloxysulfonyl group, an arylsulfonyl group, a dialkylphosphoryl group, an alkyl(alkoxy)phosphoryl group, or a dialkoxyphosphoryl group; R2 represents an alkynyl group or an alkynyloxy group; R3 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, or an aryloxy group; n indicates 0 or 1.

公开(公告)号：US09384906B2

公开(公告)日：2016-07-05

申请号：US14111015

申请日：2012-04-12

申请人： Koji Abe ,  Kei Shimamoto

发明人： Koji Abe ,  Kei Shimamoto

IPC分类号： H01M10/0567 ,  H01G11/54 ,  H01G11/58 ,  H01M10/0525 ,  H01M10/056 ,  H01G11/64 ,  C07F9/53 ,  C07F9/6571 ,  C07F9/32 ,  C07F9/40 ,  H01M10/0569 ,  H01G11/60 ,  H01M10/0568

CPC分类号： H01G11/54 ,  C07F9/3211 ,  C07F9/4006 ,  C07F9/5304 ,  C07F9/657181 ,  H01G11/58 ,  H01G11/60 ,  H01G11/64 ,  H01M10/0525 ,  H01M10/056 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  Y02E60/122 ,  Y02E60/13

摘要： The present invention provides a nonaqueous electrolytic solution capable of improving electrochemical characteristics at high temperatures, which comprises at least one organic phosphorus compound represented by the following general formula (I), an energy storage device using the nonaqueous electrolytic solution, and a specific organic phosphorus compound. (In the formula, R1 and R2 each independently represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an alkoxy group, a cycloalkoxy group, an alkenyloxy group, an alkynyloxy group, a halogenoalkyl group, a halogenoalkoxy group, an aryl group, or an aryloxy group; R3 and R4 each independently represent a hydrogen atom, a halogen atom, or an alkyl group; m is an integer of from 1 to 4, n is 0 or 1, q is 1 or 2. When q is 1 and n is 0, X represents an alkoxy group, an alkynyloxy group, an alkyloxyalkoxy group, an aryloxy group, etc.; when q is 1 and n is 1, X represents an alkyl group, an alkynyl group, an alkoxy group, an alkynyloxy group, an alkyloxyalkoxy group, etc.; and when q is 2, X represents —O-L3-O—, —OC(═O)—C(═O)O—, or a single bond.)

摘要翻译： 本发明提供一种能够改善高温电化学特性的非水电解液，其包含至少一种由以下通式（I）表示的有机磷化合物，使用该非水电解液的储能装置和特定的有机磷 复合。 （式中，R 1和R 2各自独立地表示烷基，环烷基，烯基，炔基，烷氧基，环烷氧基，链烯氧基，炔氧基，卤代烷基，卤代烷氧基 ，芳基或芳氧基; R 3和R 4各自独立地表示氢原子，卤素原子或烷基; m为1〜4的整数，n为0或1，q为1或2 当q为1且n为0时，X表示烷氧基，炔氧基，烷氧基烷氧基，芳氧基等;当q为1且n为1时，X表示烷基，炔基， 烷氧基，炔氧基，烷氧基烷氧基等;当q为2时，X表示-O-L3-O-，-OC（= O）-C（= O）O-或单键 。）

公开(公告)号：US09130244B2

公开(公告)日：2015-09-08

申请号：US13395660

申请日：2010-09-14

申请人： Koji Abe ,  Shoji Shikita ,  Kazuyuki Kawabe ,  Masahide Kondo ,  Tatsuo Fujino

发明人： Koji Abe ,  Shoji Shikita ,  Kazuyuki Kawabe ,  Masahide Kondo ,  Tatsuo Fujino

IPC分类号： H01M10/0567 ,  H01M6/16 ,  C07F7/18 ,  H01M10/052 ,  H01M10/0569 ,  H01M10/0566

CPC分类号： H01M10/0567 ,  C07C69/67 ,  C07C69/96 ,  C07C255/16 ,  C07C255/19 ,  C07C309/66 ,  C07F7/1804 ,  C07F9/11 ,  H01M6/168 ,  H01M10/052 ,  H01M10/0566 ,  H01M10/0569 ,  H01M2300/0017 ,  Y02E60/122 ,  Y02T10/7011

摘要： A nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, which contains a carboxylate represented by the following general formula (8) in an amount of from 0.01 to 5% by mass of the nonaqueous electrolytic solution: wherein X31 represents -A2-C≡Y2, -A2-C(═O)O-A3-C≡Y2 or -A2-C(═O)O-A4; A1, A2 and A3 each independently represent an alkylene group having from 1 to 6 carbon atoms; A4 represents an alkyl group having from 1 to 6 carbon atoms; Y1 and Y2 each independently represent CH or N.

摘要翻译： 溶解在非水溶剂中的电解质盐的非水电解液，其含有下述通式（8）表示的羧酸盐，其量为非水电解液的0.01〜5质量％：其中X31表示-A2- C≡Y2，-A2-C（= O）O-A3-C≡Y2或-A2-C（= O）O-A4; A1，A2和A3各自独立地表示具有1至6个碳原子的亚烷基; A4表示具有1至6个碳原子的烷基; Y1和Y2各自独立地表示CH或N.

公开(公告)号：US09029024B2

公开(公告)日：2015-05-12

申请号：US13386841

申请日：2010-08-12

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Kazuyuki Kawabe

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Kazuyuki Kawabe

IPC分类号： H01M10/052 ,  H01M6/16 ,  H01M10/0569 ,  H01M10/0568 ,  H01M4/505 ,  H01M4/52 ,  H01M10/0567 ,  H01M4/02 ,  H01M10/0525

CPC分类号： H01M10/052 ,  H01M4/505 ,  H01M4/52 ,  H01M6/164 ,  H01M6/166 ,  H01M6/168 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/027 ,  H01M2004/028 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

摘要： Disclosed are a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, which contains a sulfonate compound having a specific structure in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution, and an electrochemical device containing the nonaqueous electrolytic solution. The nonaqueous electrolytic solution is excellent in the effect of improving the storage property of primary batteries and improving the cycle property of secondary batteries in use thereof at high temperatures and the low-temperature property thereof after high-temperature cycles.

摘要翻译： 公开了溶解在非水溶剂中的电解质盐的非水电解液，其含有非水电解液的0.01〜10质量％的特定结构的磺酸盐化合物，含有非水电解质的电化学装置 解。 非水电解液在高温下的一次电池的储存性提高，二次电池的循环性提高，高温循环后的低温性优异。

公开(公告)号：US20140093787A1

公开(公告)日：2014-04-03

申请号：US14113722

申请日：2012-04-25

申请人： Koji Abe ,  Shoji Shikita

发明人： Koji Abe ,  Shoji Shikita

IPC分类号： H01M10/056 ,  H01M10/0525

CPC分类号： H01M10/056 ,  C07D327/04 ,  C07D327/06 ,  H01M10/0525 ,  H01M10/0567 ,  Y02T10/7011

摘要： An object of the present invention is to provide a nonaqueous electrolytic solution capable of improving electrochemical characteristics in a broad temperature range, an energy storage device using it.A nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, which comprises at least one cyclic sulfonic acid ester compound represented by the following general formula (I), and an energy storage device. (wherein R1 and R2 may be the same or different, each representing a hydrogen atom, an alkyl group in which at least one hydrogen atom may be substituted with a halogen atom, orahalogenatom; L represents a divalent hydrocarbon group of an alkylene group in which at least one hydrogen atom is substituted with OR3, or a divalent hydrocarbon group of an alkylene group in which at least one methylene (CH2) is substituted with C(═O); R3 represents a formyl group, an alkylcarbonyl group, an alkenylcarbonyl group, an alkynylcarbonyl group, an arylcarbonyl group, an alkoxycarbonyl group, an alkenyloxycarbonyl group, an alkynyloxycarbonyl group, an aryloxycarbonyl group, a 2,2-dioxide-1,2-oxathiolan-4-yloxycarbonyl group, a 2,2-dioxide-1,2-oxathian-4-yloxycarbonyl group, an alkanesulfonyl group, an arylsulfonyl group, a dialkylphosphoryl group, an alkoxy(alkyl)phosphoryl group, a dialkoxyphosphoryl group, —S(O)—OR4, or —C(O)CH2P(O)(OR5)2; R4 represents an alkyl group, a 2,2-dioxide-1,2-oxathiolan-4-yl group, or a 2,2-dioxide-1,2-oxathian-4-yl group; R5 represents an alkyl group; further, in R3, at least one hydrogen atom may be substituted with a halogen atom, and L may be further substituted with any of an alkyl group, a haloalkyl group or a halogen atom).

摘要翻译： 本发明的目的是提供一种能够在宽温度范围内改善电化学特性的非水电解溶液，即使用它的储能装置。 溶解在非水溶剂中的电解质盐的非水电解液，其包含至少一种由以下通式（I）表示的环状磺酸酯化合物和能量储存装置。 （其中R 1和R 2可以相同或不同，各自表示氢原子，其中至少一个氢原子可以被卤素原子取代的烷基或ah原子; L表示亚烷基的二价烃基，其中 至少一个氢原子被OR 3取代，或亚烷基的二价烃基，其中至少一个亚甲基（CH 2）被C（= O）取代; R 3表示甲酰基，烷基羰基，烯基羰基 ，炔基羰基，芳基羰基，烷氧基羰基，烯氧基羰基，炔氧基羰基，芳氧基羰基，2,2-二氧化物-1,2-氧硫杂环戊烷-4-基氧基羰基，2,2-二氧化物 - 1,2-氧硫杂环戊烷-4-基氧基羰基，烷基磺酰基，芳基磺酰基，二烷基磷酰基，烷氧基（烷基）磷酰基，二烷氧基磷酰基，-S（O）-OR4或-C（O）CH2P （O）（OR 5）2; R 4表示烷基，2,2-二氧代-1,2- 氧硫杂环戊烷-4-基或2,2-二氧化-1,2-氧硫杂-4-基; R5表示烷基; 此外，在R3中，至少一个氢原子可以被卤素原子取代，L可以进一步被烷基，卤代烷基或卤素原子中的任何一个取代）。

公开(公告)号：US20140093276A1

公开(公告)日：2014-04-03

申请号：US14095200

申请日：2013-12-03

申请人： Koji Abe ,  Junichi Hashimoto

发明人： Koji Abe ,  Junichi Hashimoto

IPC分类号： G03G21/18

CPC分类号： G03G21/1803 ,  G03G21/18 ,  G03G21/1828 ,  G03G21/1864 ,  G03G2221/1609

摘要： A process cartridge and an image forming apparatus are provided. The process cartridge is detachably mountable in an apparatus body of the image forming apparatus, and includes a plurality of photosensitive drums, a first outer side plate which is provided on one side of the photosensitive drums in an axial direction of the photosensitive drum, a second outer side plate which is provided on the other side of the photosensitive drums in the axial direction, and opposes the first outer side plate with the photosensitive drums interposed therebetween, and a plurality of input parts which are provided on ends of the photosensitive drums at the one side, respectively. An end face of each of the input parts being provided inward with respect to the outer surface of the first outer side plate.

摘要翻译： 提供处理盒和图像形成装置。 处理盒可拆卸地安装在图像形成装置的装置主体中，并且包括多个感光鼓，第一外侧板，其沿着感光鼓的轴向方向设置在感光鼓的一侧，第二外侧板 外侧板，其设置在所述感光鼓的另一侧的轴向方向上，并且与所述第一外侧板与所述感光鼓相对置;以及多个输入部，其设置在所述感光鼓的所述 一边分别。 每个输入部分的端面相对于第一外侧板的外表面向内设置。

公开(公告)号：US20140038060A1

公开(公告)日：2014-02-06

申请号：US14112778

申请日：2012-03-30

申请人： Koji ABE

发明人： Koji ABE

IPC分类号： H01M10/0567 ,  H01M10/0525

CPC分类号： H01M10/0567 ,  C07C69/96 ,  C07C309/66 ,  C07C309/73 ,  H01M4/505 ,  H01M4/525 ,  H01M4/583 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0034 ,  Y02E60/122 ,  Y02T10/7011

摘要： The present invention is to provide a nonaqueous electrolytic solution capable of enhancing electrochemical characteristics in a broad temperature range, an energy storage device using the nonaqueous electrolytic solution, and a specific trifluoromethylbenzene compound. There are provided a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, which comprises at least one halogenoalkylbenzene compound represented by the following general formula (I), an energy storage device using the nonaqueous electrolytic solution, and a specific trifluoromethylbenzene compound. (In the formula, Y1 represents an alkoxycarbonyl group having from 2 to 8 carbon atoms, an alkenyloxycarbonyl group having from 3 to 9 carbon atoms, an alkynyloxycarbonyl group having from 4 to 9 carbon atoms, an aryloxycarbonyl group having from 7 to 12 carbon atoms, an alkanesulfonyl group having from 1 to 6 carbon atoms, or an arylsulfonyl group having from 6 to 12 carbon atoms; RX represents a halogenoalkyl group having from 1 to 4 carbon atoms; n indicates an integer of from 1 to 5. However, when Y1 is an alkoxycarbonyl group having from 2 to 12 carbon atoms or an aryloxycarbonyl group having from 6 to 12 carbon atoms, the number of carbon atom of RX is 1. In the substituent represented by Y1, at least one hydrogen atom may be substituted with a halogen atom.)

摘要翻译： 本发明提供一种能够在宽温度范围内提高电化学特性的非水电解液，使用该非水电解液的储能装置和特定的三氟甲基苯化合物。 提供了溶解在非水溶剂中的电解质盐的非水电解液，其包含至少一种由以下通式（I）表示的卤代烷基苯化合物，使用非水电解液的储能装置和特定的三氟甲基苯化合物。 （式中，Y1表示碳原子数2〜8的烷氧基羰基，碳原子数3〜9的烯氧基羰基，碳原子数4〜9的炔氧基羰基，碳原子数7〜12的芳氧基羰基 具有1至6个碳原子的链烷磺酰基或具有6至12个碳原子的芳基磺酰基; RX表示具有1至4个碳原子的卤代烷基; n表示1至5的整数。然而，当 Y1是碳原子数为2〜12的烷氧基羰基或碳原子数6〜12的芳氧基羰基，RX的碳原子数为1.在由Y1表示的取代基中，至少一个氢原子可以被 卤素原子）

公开(公告)号：US08611785B2

公开(公告)日：2013-12-17

申请号：US12624982

申请日：2009-11-24

申请人： Koji Abe ,  Junichi Hashimoto

发明人： Koji Abe ,  Junichi Hashimoto

IPC分类号： G03G21/16

CPC分类号： G03G21/1803 ,  G03G21/18 ,  G03G21/1828 ,  G03G21/1864 ,  G03G2221/1609

摘要： A process cartridge and an image forming apparatus are provided. The process cartridge is detachably mountable in an apparatus body of the image forming apparatus, and includes a plurality of photosensitive drums, a first outer side plate which is provided on one side of the photosensitive drums in an axial direction of the photosensitive drum, a second outer side plate which is provided on the other side of the photosensitive drums in the axial direction, and opposes the first outer side plate with the photosensitive drums interposed therebetween, and a plurality of input parts which are provided on ends of the photosensitive drums at the one side, respectively. An end face of each of the input parts being provided inward with respect to the outer surface of the first outer side plate.

摘要翻译： 提供处理盒和图像形成装置。 处理盒可拆卸地安装在图像形成装置的装置主体中，并且包括多个感光鼓，第一外侧板，其沿着感光鼓的轴向方向设置在感光鼓的一侧，第二外侧板 外侧板，其设置在所述感光鼓的另一侧的轴向方向上，并且与所述第一外侧板与所述感光鼓相对置;以及多个输入部，其设置在所述感光鼓的所述 一边分别。 每个输入部分的端面相对于第一外侧板的外表面向内设置。

公开(公告)号：US08597834B2

公开(公告)日：2013-12-03

申请号：US12801631

申请日：2010-06-17

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Akira Kinoshita ,  Shingo Tode ,  Ikuro Nakane ,  Shin Fujitani

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Akira Kinoshita ,  Shingo Tode ,  Ikuro Nakane ,  Shin Fujitani

IPC分类号： H01M4/13 ,  H01M6/16

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/485 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2010/4292 ,  H01M2300/0025

摘要： A nonaqueous electrolyte secondary battery including a negative electrode containing a graphite material as the negative active material, a positive electrode containing lithium cobalt oxide as a main component of the positive active material and a nonaqueous electrolyte solution, the battery being characterized in that the lithium cobalt oxide contains a group IVA element selected from the group consisting of Ti, Zr and Hf and a group IIA element of the periodic table, the nonaqueous electrolyte solution contains 0.2-1.5% by weight of a sulfonyl-containing compound and preferably further contains 0.5-4% by weight of vinylene carbonate.

摘要翻译： 包含含有作为负极活性物质的石墨材料的负极，含有钴酸锂作为正极活性物质的主要成分的正极和非水电解液的非水电解质二次电池，其特征在于，所述锂钴 氧化物含有选自Ti，Zr和Hf的IVA族元素和周期表的IIA族元素，非水电解质溶液含有0.2-1.5重量％的含磺酰基化合物，优选还含有0.5- 4重量％的碳酸亚乙烯酯。

公开(公告)号：US20130295467A1

公开(公告)日：2013-11-07

申请号：US13884448

申请日：2011-11-08

申请人： Koji Abe ,  Akikazu Ito

发明人： Koji Abe ,  Akikazu Ito

IPC分类号： B65D1/12 ,  H01M10/056

CPC分类号： B65D1/12 ,  B65D1/0207 ,  B65D41/28 ,  B65D51/18 ,  B65D2251/0015 ,  B65D2251/0075 ,  B65D2251/0078 ,  H01G11/58 ,  H01G11/78 ,  H01M10/052 ,  H01M10/056 ,  H01M10/0566 ,  H01M2300/0025 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

摘要： (1) A container for a nonaqueous electrolytic solution, containing a material containing an aluminum or aluminum alloy layer, and storing a nonaqueous electrolytic solution containing a nonaqueous solvent having dissolved therein an electrolyte salt, the container having a cap and a plug each formed of a resin, and maintaining the nonaqueous electrolytic solution to have a water content of 50 ppm or less after storing in the container for 30 days, (2) a nonaqueous electrolytic solution placed in the container, and (3) a method for storing a nonaqueous electrolytic solution. The container for a nonaqueous electrolytic solution is a light weight container that prevents the nonaqueous electrolytic solution from being decomposed on storing to maintain the high quality, and facilitates and ensures the handling of the nonaqueous electrolytic solution.

摘要翻译： （1）具有溶解的非水电解液包含含有铝或铝合金层，并且存储包含非水溶剂的非水电解液的材料的容器，其中的电解质盐，其具有一个盖和塞子的容器中的每个的形成 的树脂，和保持该非水电解液在容器储存30天之后，以具有50ppm或更低的水含量，（2），用于存储非水放置在容器中的非水电解液，以及（3）的方法 电解液。 用于非水电解液的容器是防止非水电解液在储存时分解以保持高质量的轻量容器，并且有助于并确保非水电解液的处理。