摘要:
Provided is a film-forming method based on an LB method by which a uniform alignment film using a helical polyacetylene can be obtained. The method based on the LB method includes: developing a helical polyacetylene onto a liquid surface; and transferring a monolayer film of the helical polyacetylene formed on the liquid surface onto a substrate to form a film, in which a compressibility P represented by the following formula (1) at a time of the film formation is 1×10−2 m/mN or less: P=(1/(dH/dS))×(1/S) (1), where H represents a surface pressure (mN/m) of the monolayer film of the helical polyacetylene, and S represents an area (m2) of the monolayer film of the helical polyacetylene developed onto the liquid surface.
摘要:
Provided is a film-forming method based on an LB method by which a uniform alignment film using a helical polyacetylene can be obtained. The method based on the LB method includes: developing a helical polyacetylene onto a liquid surface; and transferring a monolayer film of the helical polyacetylene formed on the liquid surface onto a substrate to form a film, in which a compressibility P represented by the following formula (1) at a time of the film formation is 1×10−2 m/mN or less: P=(1/(dH/dS))×(1/S) (1), where H represents a surface pressure (mN/m) of the monolayer film of the helical polyacetylene, and S represents an area (m2) of the monolayer film of the helical polyacetylene developed onto the liquid surface.
摘要:
A helical-polyacetylene whose main chain has a helical structure includes a carbon double bond constituting the main chain and a side chain composed of an aromatic five- or six-membered ring that binds to one carbon atom of the carbon double bond. In the atoms constituting the five- or six-membered ring, two atoms binding to the atom that directly binds to the carbon atom of the main chain bind only any of five or six atoms constituting the five- or six-membered ring, and in the atoms constituting the five- or six-membered ring, at least one atom located most distant from the atom that directly binds to the carbon atom of the main chain is carbon.
摘要:
The invention provides a block polymer capable of being used as a molecular wire facilitating injection of carriers between itself and an electrode, and a device in which electrodes are bridged by one molecule. The block polymer has a main chain composed of polyacetylene having a spiral structure, and includes a coating insulating block and a conductive block. The coating insulating block has a polyacetylene unit structure having alkyl chains at its side chains through functional groups, the alkyl chains being arranged in a direction parallel to the major axis of the main chain. The conductive block has a polyacetylene unit structure having hydrogen atoms at its side chains through functional groups, the hydrogen atoms being arranged in a direction parallel to the major axis of the main chain. The device has the above-mentioned block polymer, and two or more electrodes.
摘要:
A method and an apparatus for easily making a continuous oriented structure of a polymer are provided. In making a polymer assembly, single crystals are bonded to each other, an external force, such as an electrical field or a magnetic field, is applied to the single crystals, or a solution of the polymer is applied on a substrate such that the applied solution is linear in shape.
摘要:
A method and an apparatus for easily making a continuous oriented structure of a polymer are provided. In making a polymer assembly, single crystals are bonded to each other, an external force, such as an electrical field or a magnetic field, is applied to the single crystals, or a solution of the polymer is applied on a substrate such that the applied solution is linear in shape.
摘要:
The invention provides a novel block polymer applicable to a light-emitting device. The block polymer has an electron-transporting block and a hole-transporting block, wherein the main chain backbone of the block polymer is polyacetylene.
摘要:
A device is provided by use of a helical substituted polyacetylene. The device comprises a structure comprised of a helical substituted polyacetylene having a helical main chain, and a pair of electrodes for applying a voltage or electric current to the structure, wherein the molecule of the helical substituted polyacetylene has a length larger than the distance between the pair of the electrodes.
摘要:
The invention provides a block polymer capable of being used as a molecular wire facilitating injection of carriers between itself and an electrode, and a device in which electrodes are bridged by one molecule. The block polymer has a main chain composed of polyacetylene having a spiral structure, and includes a coating insulating block and a conductive block. The coating insulating block has a polyacetylene unit structure having alkyl chains at its side chains through functional groups, the alkyl chains being arranged in a direction parallel to the major axis of the main chain. The conductive block has a polyacetylene unit structure having hydrogen atoms at its side chains through functional groups, the hydrogen atoms being arranged in a direction parallel to the major axis of the main chain. The device has the above-mentioned block polymer, and two or more electrodes.
摘要:
A substituted polyacetylene having an organic functional group bondable to the surface of a metal, a metal oxide or an alloy at least one of the polymer terminals, and a device structure having the substituted polyacetylene and two or more independent electrodes. A helical substituted polyacetylene having a helical structure with a periodic main chain. The organic functional group is at least one selected from the group consisting of a thiol group, a sulfide group, a disulfide group, a thioacetyl group, an isocyanide group, a carboxylic acid group and a phosphoric acid group.