Method for preparation of hematite iron oxide with different nanostructures and hematite iron oxide prepared thereby
    1.
    发明授权
    Method for preparation of hematite iron oxide with different nanostructures and hematite iron oxide prepared thereby 有权
    制备具有不同纳米结构的赤铁矿氧化铁和由此制备的赤铁矿氧化铁的方法

    公开(公告)号:US08865116B2

    公开(公告)日:2014-10-21

    申请号:US13670907

    申请日:2012-11-07

    摘要: Disclosed is a method for preparing hematite iron oxide having various nanostructures, including: preparing a mixture solution by adding iron chloride and caffeine to a solvent and magnetically stirring; and performing hydrothermal synthesis, wherein the solvent is selected from water, ethanol, propanol and methanol. In accordance with the present disclosure, hematite iron oxide (α-Fe2O3) superstructures of various shapes, including grape, cube, dumbbell and microsphere shapes, can be synthesized in different solvents using caffeine. The shapes can be controlled variously via a simple one-step synthesis route without using a growth-inducing agent and without separation based on size. The prepared hematite iron oxide exhibits high coercivity at room temperature owing to its fine crystal structures and anisotropic shapes. The hematite iron oxide nanoparticles having different nanostructures prepared according to the present disclosure may be widely useful in biological and biochemical applications as a material having peroxidase mimic activity and thus capable of replacing natural enzymes.

    摘要翻译: 公开了一种制备具有各种纳米结构的赤铁矿氧化铁的方法,包括:通过向溶剂中加入氯化铁和咖啡因并进行磁力搅拌来制备混合溶液; 并进行水热合成,其中溶剂选自水,乙醇,丙醇和甲醇。 根据本公开,可以使用咖啡因在不同溶剂中合成各种形状的赤铁矿氧化铁(α-Fe2O3)上层结构,包括葡萄,立方体,哑铃和微球形状。 可以通过简单的一步合成路线,不使用生长诱导剂并且基于尺寸不分离,可以不同地控制形状。 由于其精细的晶体结构和各向异性的形状,所制备的赤铁矿氧化铁在室温下表现出高的矫顽力。 根据本公开制备的具有不同纳米结构的赤铁矿氧化铁纳米粒子可广泛用于生物和生物化学应用中,作为具有过氧化物酶模拟活性并因此能够替代天然酶的材料。