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公开(公告)号：US06280026B1
公开(公告)日：2001-08-28
申请号：US09364335
申请日：1999-07-30
IPC分类号： G01D1100
CPC分类号： B41M5/5272
摘要： An ink jet printing process for improving the dye density and fixability of an ink jet image comprising: a) providing an ink jet recording element comprising a support having thereon an image-recording layer comprising a mixture of an anionic, water-dispersible polyester ionomer and a hydrophilic polymer; and b) applying droplets of a liquid ink on the image-recording layer in an image-wise manner, the ink comprising water, humectant and a water-soluble cationic or basic dye.
摘要翻译： 一种用于改善喷墨图像的染料密度和定影性的喷墨印刷方法，包括：a）提供喷墨记录元件，其包含其上具有阴离子，水分散性聚酯离聚物和 亲水性聚合物; 和b）以图像方式将液体墨滴施加到图像记录层上，该油墨包含水，湿润剂和水溶性阳离子或碱性染料。
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公开(公告)号：US5804531A
公开(公告)日：1998-09-08
申请号：US995728
申请日：1997-12-22
IPC分类号： B41M5/035 , B41M5/00 , B41M5/382 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/50 , B41M5/52 , B41M5/38
CPC分类号： B41M5/385 , B41M5/3854 , B41M5/3856 , B41M5/388 , B41M5/39 , B41M5/52 , B41M5/5227 , B41M5/5272 , Y10S428/913 , Y10S428/914 , Y10T428/31786
摘要： A thermal dye transfer assemblage comprising: (a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being: I) an electrically neutral, deprotonated, delocalized cationic dye precursor; II) a pendant basic dye of the formula D-(L-E).sub.m wherein D represents the residue of a dye, L represents a covalent linking group, E represents a moiety with basic properties and m is an integer of 1-3; or III) a cationic dye precursor having the following structure: ##STR1## (b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the dye image-receiving layer, the dye image-receiving layer comprising a polyester ionomer comprising a polyester backbone containing units of a salt of a sulfonic acid or sulfonimide and a basic nitrogen-containing compound which has a pKa of its conjugate acid in the range from about 6 to about 10.
摘要翻译： 一种热染料转移组合物，包括：（a）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料层的载体，所述染料为：I）电中性，去质子化的离域阳离子染料前体; II）式D-（L-E）m的侧基碱性染料，其中D表示染料的残基，L表示共价连接基团，E表示具有碱性的部分，m表示1-3的整数; 或III）具有以下结构的阳离子染料前体：（b）染料接收元件，其包含其上具有聚合染料影像接收层的载体，所述染料接收元件与染料接收元件处于重叠关系， 供体元件，使得染料层与染料影像接收层接触，染料影像接收层包含聚酯离聚物，其包含含有磺酸或磺酰亚胺盐和含碱性含氮化合物的单元的聚酯骨架 其共轭酸的pKa在约6至约10的范围内。
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公开(公告)号：US06206517B1
公开(公告)日：2001-03-27
申请号：US09216350
申请日：1998-12-18
IPC分类号： B41J201
CPC分类号： B41M7/0018 , B41M5/508 , B41M5/52 , B41M5/5218 , B41M5/5236 , B41M5/5254 , B41M5/5272
摘要： An ink jet printing process for improving the light stability of an ink jet image comprising: providing an ink jet recording element comprising a support having thereon an image-recording layer comprising a cross-linkable polymer of gelatin or acetoacetylated poly(vinyl alcohol) and a mordant; applying liquid ink droplets of a dye on the image-recording layer in an image-wise manner, the dye being a water-soluble deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N—H group which is part of a conjugated system; and applying an aqueous solution of a multivalent inorganic salt to the image to cross-link the polymer.
摘要翻译： 一种用于改善喷墨图像的光稳定性的喷墨印刷方法，包括：提供一种喷墨记录元件，其包括其上具有明胶或乙酰乙酰化聚（乙烯醇）的可交联聚合物的图像记录层的载体和 媒染剂 以成像方式将图像记录层上的染料的液体墨滴施加到图像记录层上，该染料是水溶性去质子化阳离子染料，其能够被再赋色为具有NH基团的阳离子染料，所述NH基团是共轭 系统; 并将多价无机盐的水溶液施加到图像上以交联聚合物。
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公开(公告)号：US06276791B1
公开(公告)日：2001-08-21
申请号：US09216288
申请日：1998-12-18
IPC分类号： B41J217
CPC分类号： B41M5/52 , B41M5/508 , B41M5/5236 , B41M5/5254 , B41M5/5272 , B41M7/0018 , B41M7/0027 , C09D11/30
摘要： An ink jet printing process for improving the light stability and wet abrasion resistance of an ink jet image comprising: a) providing an ink jet recording element comprising a support having thereon an image-recording layer comprising a cross-linkable polymer of gelatin or acetoacetylated poly(vinyl alcohol) and a mordant; b) applying liquid ink droplets of a dye on the image-recording layer in an image-wise manner, the dye being a water-soluble deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N—H group which is part of a conjugated system; and c) applying an aqueous solution of an organic hardener to the image to cross-link the polymer.
摘要翻译： 一种用于改善喷墨图像的光稳定性和耐湿磨损性的喷墨印刷方法，包括：a）提供喷墨记录元件，其包含其上具有明胶或乙酰乙酰化聚合物的可交联聚合物的图像记录层的载体 （乙烯醇）和媒染剂; b）以成像方式将染料的液体墨滴施加在图像记录层上，该染料是能够被再赋色至阳离子染料的水溶性去质子化阳离子染料 具有作为共轭体系的一部分的NH基团; 和c）将有机硬化剂的水溶液施加到图像上以交联聚合物。
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公开(公告)号：US06352341B2
公开(公告)日：2002-03-05
申请号：US09216653
申请日：1998-12-18
IPC分类号： B41J201
CPC分类号： B41M5/52 , B41M5/508 , B41M5/5218 , B41M5/5227 , B41M5/5236 , B41M5/5254 , B41M5/5272 , B41M7/0018 , Y10T428/31725
摘要： An ink jet printing process for improving the wet abrasion resistance of an ink jet image comprising: providing an ink jet recording element comprising a support having thereon an image-recording layer comprising a cross-linkable polymer of gelatin or acetoacetylated poly(vinyl alcohol) and a mordant; applying liquid ink droplets of a cationic, water-soluble dye on the image-recording layer in an image-wise manner; and applying an aqueous solution of an organic hardener or a sulfate of a trivalent metal to the image to cross-link the polymer.
摘要翻译： 一种用于改善喷墨图像的湿耐磨性的喷墨印刷方法，包括：提供喷墨记录元件，其包括其上具有明胶或乙酰乙酰化聚（乙烯醇）的可交联聚合物的图像记录层的载体和 媒染剂 以图像方式将阳离子性水溶性染料的液体墨滴施加在图像记录层上; 并将有机硬化剂或三价金属硫酸盐的水溶液施加到图像上以交联聚合物。
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公开(公告)号：US6137514A
公开(公告)日：2000-10-24
申请号：US216304
申请日：1998-12-18
CPC分类号： C09D11/30
摘要： A method of ink jet printing, wherein an ink jet composition comprising water, a cationic, water soluble dye and from about 0.1% to about 10% by weight of a hardener is ejected onto an image recording element. The recording element is formed of a support and an ink receptive layer, formed on the support, wherein the ink receptive layer comprises a cross linkable polymer.
摘要翻译： 一种喷墨印刷方法，其中包含水，阳离子，水溶性染料和约0.1％至约10％重量的硬化剂的喷墨组合物喷射到图像记录元件上。 记录元件由支撑体和形成在支撑体上的油墨接收层形成，其中油墨接受层包括可交联聚合物。
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公开(公告)号：US6139611A
公开(公告)日：2000-10-31
申请号：US216147
申请日：1998-12-18
IPC分类号： C09D11/00
CPC分类号： C09D11/30
摘要： An ink jet ink composition which provides an image having improved wet abrasion resistance comprising water, a cationic, water-soluble dye and from about 0.1 to about 10% by weight of a hardener.
摘要翻译： 一种喷墨油墨组合物，其提供具有改善的耐湿磨损性的图像，其包含水，阳离子，水溶性染料和约0.1至约10重量％的硬化剂。
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公开(公告)号：US06554418B2
公开(公告)日：2003-04-29
申请号：US09771251
申请日：2001-01-26
IPC分类号： B41J201
CPC分类号： B41M5/5245
摘要： An ink jet printing method, comprising the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink-receptive elements comprising a support having thereon an image-receiving layer comprising a graft copolymer comprising a backbone copolymer and at least one branch copolymer, the backbone polymer comprising structural units capable of being oxidized by a transition metal catalyst and the branch copolymer comprising cationic units and neutral hydrophilic units; C) loading the printer with an ink jet ink composition comprising water, a humectant, and a water-soluble anionic dye; and D) printing on the image-receiving layer using the ink jet ink in response to the digital data signals.
摘要翻译： 一种喷墨打印方法，包括以下步骤：A）提供对数字数据信号作出响应的喷墨打印机; B）将印刷机装载在容纳元件的油墨接受元件上，所述油墨接受元件包括其上具有载体的载体，所述图像接收层包含接枝共聚物 包括骨架共聚物和至少一种分支共聚物，所述主链聚合物包含能够被过渡金属催化剂氧化的结构单元和包含阳离子单元和中性亲水单元的支链共聚物; C）用喷墨油墨组合物装载打印机，所述喷墨油墨组合物包含 水，保湿剂和水溶性阴离子染料; 和D）响应于数字数据信号使用喷墨油墨在图像接收层上进行打印。
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公开(公告)号：US5928990A
公开(公告)日：1999-07-27
申请号：US995825
申请日：1997-12-22
申请人： Robert A. Guistina , Elizabeth G. Burns , Teh-Ming Kung , Kristine B. Lawrence , Richard C. VanHanehem
发明人： Robert A. Guistina , Elizabeth G. Burns , Teh-Ming Kung , Kristine B. Lawrence , Richard C. VanHanehem
IPC分类号： B41M5/385 , B41M5/382 , B41M5/388 , B41M5/39 , B41M5/395 , B41M5/50 , B41M5/52 , C08L67/02 , B41M5/035 , B41M5/38
CPC分类号： B41M5/5218 , B41M5/5272 , B41M5/38207 , Y10S428/913 , Y10S428/914 , Y10T428/31786
摘要： A thermal dye transfer assemblage comprising:(I) a dye-donor element comprising a support having thereon sequentially repeating dye layer patches of a dye dispersed in a polymeric binder, at least one of the dye patches containing a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N-H group which is part of a conjugated system; and(II) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer comprising a polyester polymer which itself does not significantly reprotonate deprotonated cationic dyes which may be transferred from the dye-donor element, to which has been added a hydrated transition metal or metalloid salt of a strong acid;the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer.
摘要翻译： 一种热染料转移组合物，其包含：（I）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料顺序重复染料层贴片的载体，至少一种含有去质子化阳离子染料的染色剂，其能够 被染色成具有作为共轭体系的一部分的NH基团的阳离子染料; 和（II）染料接收元件，其包含其上具有聚合物染料影像接收层的聚合物染料影像接收层的载体，聚合物聚合物本身不会显着地再生可能从染料供体元件转移的去质子化的阳离子染料， 强酸的水合过渡金属或准金属盐; 染料接收元件与染料供体元件处于重叠关系，使得染料层与聚合染料影像接收层接触。
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10.发明授权
公开(公告)号：US5786299A
公开(公告)日：1998-07-28
申请号：US878565
申请日：1997-06-19
IPC分类号： B41M5/382 , B41M5/00 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/50 , B41M5/52 , B41M5/035 , B41M5/38
CPC分类号： B41M5/5245 , B41M5/38207 , B41M5/385 , B41M5/52 , B41M5/5254 , Y10S428/913 , Y10S428/914 , Y10T428/31855
摘要： A thermal dye transfer assemblage comprising: (I) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N-H group which is part of a conjugated system, and (II) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer, the polymeric dye image-receiving layer comprising a mixture of a) a polymer having a Tg of less than about 19.degree. C. and having no or only slight acidity; and b) a water-soluble, multifunctional carboxylic acid with at least two carboxylic acid groups attached.
摘要翻译： 一种热染料转移组合物，其包含：（I）染料供体元件，其包含其上具有染料层的载体，所述染料层包含分散在聚合物粘合剂中的染料，所述染料是去质子化的阳离子染料，其能够被再赋色为阳离子染料， 作为共轭系统的一部分的NH基，和（II）染料接收元件，其包含其上具有聚合染料影像接收层的载体，染料接收元件与染料供体元件重叠关系，因此 染料层与聚合染料影像接收层接触，聚合染料影像接收层包含a）Tg小于约19℃并且没有或仅有轻微酸度的聚合物的混合物; 和b）具有连接至少两个羧酸基团的水溶性多官能羧酸。
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