公开(公告)号：US07699924B2

公开(公告)日：2010-04-20

申请号：US11860109

申请日：2007-09-24

申请人： Kumiko Mafune ,  Mikio Sanada ,  Kenji Moribe ,  Tomonari Watanabe ,  Daiji Okamura ,  Satoshi Kudo ,  Fumiharu Nakamura

发明人： Kumiko Mafune ,  Mikio Sanada ,  Kenji Moribe ,  Tomonari Watanabe ,  Daiji Okamura ,  Satoshi Kudo ,  Fumiharu Nakamura

IPC分类号： C09D11/02

CPC分类号： C09D11/322

摘要： Provided herein is an aqueous ink, which is excellent in both image density and fixing ability irrespective of the kind of a recording medium even when the volume of an ink droplet is small and has such excellent properties that white stripes are not caused even when high-speed recording is conducted. The aqueous ink comprises at least water, a water-soluble organic solvent, a water-insoluble coloring material, a surfactant and a poor medium for the water-insoluble coloring material and/or a salt. The dynamic surface tension of the aqueous ink at a lifetime of 50 milliseconds determined by a maximum bubble pressure method is higher than 47 mN/m, and the dynamic surface tension at a lifetime of 5,000 milliseconds determined by the maximum bubble pressure method is 38 mN/m or lower.

摘要翻译： 本发明提供一种水性油墨，即使在墨滴体积小的情况下即使是高分辨率的白色条纹也具有优异的图像浓度和定影能力，与记录介质的种类无关， 进行速度记录。 水性油墨至少包含水，水溶性有机溶剂，水不溶性着色材料，表面活性剂和用于水不溶性着色材料和/或盐的不良介质。 通过最大气泡压力法确定的50毫秒的寿命的水性油墨的动态表面张力高于47mN / m，通过最大气泡压力法确定的5000毫秒的寿命的动态表面张力为38mN / m以下。

公开(公告)号：US07682433B2

公开(公告)日：2010-03-23

申请号：US12116336

申请日：2008-05-07

申请人： Satomi Yanagimachi ,  Kumiko Mafune ,  Mikio Sanada ,  Kenji Moribe ,  Tomonari Watanabe ,  Daiji Okamura ,  Hideki Yamakami ,  Satoshi Kudo ,  Fumiharu Nakamura

发明人： Satomi Yanagimachi ,  Kumiko Mafune ,  Mikio Sanada ,  Kenji Moribe ,  Tomonari Watanabe ,  Daiji Okamura ,  Hideki Yamakami ,  Satoshi Kudo ,  Fumiharu Nakamura

IPC分类号： C09D11/02

CPC分类号： C09D11/40

摘要： In an ink set having a plurality of inks, the ink set has at least a pigment ink and a dye ink. The pigment ink contains at least water, a surfactant, a self-dispersion pigment, and a poor medium for self-dispersion pigment and/or a salt; a dynamic surface tension of the pigment ink at a lifetime of 50 milliseconds is higher than 47 mN/m. The dye ink contains at least water, a surfactant and a dye. An ink set is provided which can obtain images having a high image density and a superior bleeding resistance without regard to the types of recording mediums.

摘要翻译： 在具有多种油墨的油墨组中，油墨组至少具有颜料油墨和染料油墨。 颜料墨水至少含有水，表面活性剂，自分散颜料和用于自分散颜料和/或盐的不良介质; 在50毫秒的寿命期间颜料墨水的动态表面张力高于47mN / m。 染料墨水至少含有水，表面活性剂和染料。 提供一种油墨组，其可以获得具有高图像密度和优异的耐渗色性的图像，而不考虑记录介质的类型。

公开(公告)号：US20080280042A1

公开(公告)日：2008-11-13

申请号：US12116336

申请日：2008-05-07

申请人： Satomi Yanagimachi ,  Kumiko Mafune ,  Mikio Sanada ,  Kenji Moribe ,  Tomonari Watanabe ,  Daiji Okamura ,  Hideki Yamakami ,  Satoshi Kudo ,  Fumiharu Nakamura

发明人： Satomi Yanagimachi ,  Kumiko Mafune ,  Mikio Sanada ,  Kenji Moribe ,  Tomonari Watanabe ,  Daiji Okamura ,  Hideki Yamakami ,  Satoshi Kudo ,  Fumiharu Nakamura

IPC分类号： C09D11/02 ,  B05D5/06 ,  G01D11/00 ,  B41J2/175

CPC分类号： C09D11/40

摘要： In an ink set having a plurality of inks, the ink set has at least a pigment ink and a dye ink. The pigment ink contains at least water, a surfactant, a self-dispersion pigment, and a poor medium for self-dispersion pigment and/or a salt; a dynamic surface tension of the pigment ink at a lifetime of 50 milliseconds is higher than 47 mN/m. The dye ink contains at least water, a surfactant and a dye. An ink set is provided which can obtain images having a high image density and a superior bleeding resistance without regard to the types of recording mediums.

摘要翻译： 在具有多种油墨的油墨组中，油墨组至少具有颜料油墨和染料油墨。 颜料墨水至少含有水，表面活性剂，自分散颜料和用于自分散颜料和/或盐的不良介质; 在50毫秒的寿命期间颜料墨水的动态表面张力高于47mN / m。 染料墨水至少含有水，表面活性剂和染料。 提供一种油墨组，其可以获得具有高图像密度和优异的耐渗色性的图像，而不考虑记录介质的类型。

公开(公告)号：US20080018722A1

公开(公告)日：2008-01-24

申请号：US11860109

申请日：2007-09-24

申请人： Kumiko Mafune ,  Mikio Sanada ,  Kenji Moribe ,  Tomonari Watanabe ,  Daiji Okamura ,  Satoshi Kudo ,  Fumiharu Nakamura

发明人： Kumiko Mafune ,  Mikio Sanada ,  Kenji Moribe ,  Tomonari Watanabe ,  Daiji Okamura ,  Satoshi Kudo ,  Fumiharu Nakamura

IPC分类号： G01D11/00 ,  C09D11/00 ,  C09D11/02

CPC分类号： C09D11/322

摘要： Provided herein is an aqueous ink, which is excellent in both image density and fixing ability irrespective of the kind of a recording medium even when the volume of an ink droplet is small and has such excellent properties that white stripes are not caused even when high-speed recording is conducted. The aqueous ink comprises at least water, a water-soluble organic solvent, a water-insoluble coloring material, a surfactant and a poor medium for the water-insoluble coloring material and/or a salt. The dynamic surface tension of the aqueous ink at a lifetime of 50 milliseconds determined by a maximum bubble pressure method is higher than 47 mN/m, and the dynamic surface tension at a lifetime of 5,000 milliseconds determined by the maximum bubble pressure method is 38 mN/m or lower.

摘要翻译： 本发明提供一种水性油墨，即使在墨滴体积小的情况下即使是高分辨率的白色条纹也具有优异的图像浓度和定影能力，与记录介质的种类无关， 进行速度记录。 水性油墨至少包含水，水溶性有机溶剂，水不溶性着色材料，表面活性剂和用于水不溶性着色材料和/或盐的不良介质。 通过最大气泡压力法确定的50毫秒的寿命的水性油墨的动态表面张力高于47mN / m，通过最大气泡压力法确定的5000毫秒的寿命的动态表面张力为38mN / m以下。

公开(公告)号：US07753515B2

公开(公告)日：2010-07-13

申请号：US11269730

申请日：2005-11-09

申请人： Yui Tokuda ,  Tomonari Watanabe ,  Mikio Sanada ,  Masashi Ogasawara

发明人： Yui Tokuda ,  Tomonari Watanabe ,  Mikio Sanada ,  Masashi Ogasawara

IPC分类号： G01D11/00

CPC分类号： C09D11/40

摘要： In an ink set, which is an ink set (A) obtained by combining a plurality of aqueous inks (a) and used together with an aqueous ink (B) containing a water-insoluble coloring material, respective aqueous inks constituting the ink set (A) contain at least one water-soluble organic solvent serving as a poor solvent for the water-insoluble coloring material contained in the aqueous ink (B), and among the water-soluble organic solvents which are respectively contained in the aqueous ink (a) and serve as a poor solvent, at least one water-soluble organic solvent has a vapor pressure at 20° C. that is lower than the vapor pressure of water at 20° C. The ink set can form a full-color image in which occurrence of bleeding at boundaries between different adjacent color regions of the image has been suppressed.

摘要翻译： 在通过组合多种水性油墨（a）并与含有水不溶性着色材料的水性油墨（B））一起使用的油墨组（A）的油墨组中，构成油墨组的各个水性油墨 A）含有至少一种用作水性油墨（B）中所含的水不溶性着色材料的不良溶剂的水溶性有机溶剂，以及分别包含在水性油墨（a）中的水溶性有机溶剂 ），并且用作不良溶剂，至少一种水溶性有机溶剂的蒸气压在20℃时低于20℃下的水蒸气压。油墨组可以形成全色图像 已经抑制了在图像的不同相邻颜色区域之间的边界处的出血发生。

公开(公告)号：US07605192B2

公开(公告)日：2009-10-20

申请号：US11297431

申请日：2005-12-09

申请人： Mikio Sanada ,  Yoshihisa Takizawa ,  Katsuhiko Takahashi ,  Masashi Ogasawara ,  Yoichi Takada ,  Tomonari Watanabe ,  Yui Tokuda

发明人： Mikio Sanada ,  Yoshihisa Takizawa ,  Katsuhiko Takahashi ,  Masashi Ogasawara ,  Yoichi Takada ,  Tomonari Watanabe ,  Yui Tokuda

IPC分类号： C09D11/00

CPC分类号： C09D11/324 ,  C09D11/322

摘要： The present invention relates to an aqueous ink, particularly an aqueous ink suitable for ink jet recording. The ink is an aqueous ink comprising a modified pigment having organic groups chemically attached to the surface of a particle of the pigment and an aqueous medium which is a dispersant of the pigment, wherein the above-described organic group includes a reaction product of a functional group chemically attached to the surface of the pigment directly or via another atomic group with a copolymer of an ionic monomer and a hydrophobic monomer.

摘要翻译： 本发明涉及一种水性油墨，特别涉及一种适用于喷墨记录的水性油墨。 油墨是一种水性油墨，其包含具有化学连接到颜料颗粒表面的有机基团和作为颜料分散剂的水性介质的改性颜料，其中上述有机基团包括官能团的反应产物 通过离子性单体和疏水性单体的共聚物，直接或通过另一原子团化学连接到颜料的表面上。

公开(公告)号：US07160376B2

公开(公告)日：2007-01-09

申请号：US10833111

申请日：2004-04-28

申请人： Tomonari Watanabe ,  Mikio Sanada ,  Masashi Ogasawara ,  Yui Tokuda

发明人： Tomonari Watanabe ,  Mikio Sanada ,  Masashi Ogasawara ,  Yui Tokuda

IPC分类号： C09D11/00 ,  G01D11/00

CPC分类号： C09D11/324 ,  C09D11/322

摘要： An aqueous ink comprising at least water, a water-soluble organic solvent and a colorant.The colorant comprises a pigment containing a pigment particle having at least one ionic group bonded to a surface of the pigment particle directly or via another atomic group.The organic solvent undergoes completely or substantially no solvation with the pigment and the ionic group of the pigment particle undergoes completely or substantially no ion dissociation in the organic solvent.

摘要翻译： 至少包含水，水溶性有机溶剂和着色剂的水性油墨。 着色剂包含含有至少一个离子基团的颜料的颜料，其直接或通过另一个原子团与颜料颗粒的表面键合。 有机溶剂与颜料完全或基本上不溶剂化，颜料颗粒的离子基团在有机溶剂中完全或基本上不离子离解。

公开(公告)号：US20050024458A1

公开(公告)日：2005-02-03

申请号：US10874347

申请日：2004-06-24

申请人： Mikio Sanada ,  Katsuhiko Takahashi ,  Masashi Ogasawara ,  Tomonari Watanabe ,  Yui Tokuda

发明人： Mikio Sanada ,  Katsuhiko Takahashi ,  Masashi Ogasawara ,  Tomonari Watanabe ,  Yui Tokuda

IPC分类号： C09D11/00

CPC分类号： B41J2/211 ,  B41J2/2107 ,  C09D11/32

摘要： A water-based ink of the present invention comprises water, a plurality of different water-soluble organic solvents, and a water-insoluble coloring material, wherein the above water-soluble organic solvents consist of a good solvent to the above water-insoluble coloring material and a poor solvent to the above water-insoluble coloring material, and the total amount (% by mass) of the good solvents in the ink is represented by A and the total amount (% by mass) of the poor solvent in the ink is represented by B, the ratio of A to B ranges from 10:5 to 10:30 both inclusive, and when the respective Ka values of the above water-soluble organic solvents are determined by the Bristow method and compared with each other, a water-soluble organic solvent having the largest Ka value is the poor solvent. The pigment ink has a sufficiently large area factor even with a small amount of ink and provides an image of high OD.

摘要翻译： 本发明的水性油墨包含水，多种不同的水溶性有机溶剂和水不溶性着色材料，其中上述水溶性有机溶剂由上述水不溶性着色剂 材料和不良溶剂，并且油墨中的良溶剂的总量（质量％）由A表示，并且油墨中的不良溶剂的总量（质量％）表示为 由B表示，A与B的比例范围为10:5至10:30，并且当通过Bristow方法确定上述水溶性有机溶剂的各自的Ka值并相互比较时， Ka值最大的水溶性有机溶剂是不良溶剂。 颜料墨水即使用少量的油墨也具有足够大的面积因子，并提供高OD的图像。

公开(公告)号：US08672465B2

公开(公告)日：2014-03-18

申请号：US13191511

申请日：2011-07-27

申请人： Mikio Sanada ,  Katsuhiko Takahashi ,  Masashi Ogasawara ,  Tomonari Watanabe ,  Yui Tokuda

发明人： Mikio Sanada ,  Katsuhiko Takahashi ,  Masashi Ogasawara ,  Tomonari Watanabe ,  Yui Tokuda

IPC分类号： B41J2/01

CPC分类号： B41J2/211 ,  B41J2/2107 ,  C09D11/32

摘要： A water-based ink of the present invention includes water, a plurality of different water-soluble organic solvents, and a water-insoluble coloring material, wherein the above water-soluble organic solvents consist of a good solvent to the above water-insoluble coloring material and a poor solvent to the above water-insoluble coloring material, and the total amount (% by mass) of the good solvents in the ink is represented by A and the total amount (% by mass) of the poor solvent in the ink is represented by B, the ratio of A to B ranges from 10:5 to 7:9 both inclusive, and when the respective Ka values of the above water-soluble organic solvents are determined by the Bristow method and compared with each other, a water-soluble organic solvent having the largest Ka value is the poor solvent. The pigment ink has a sufficiently large area factor even with a small amount of ink and provides an image of high OD.

摘要翻译： 本发明的水性油墨包括水，多种不同的水溶性有机溶剂和水不溶性着色材料，其中上述水溶性有机溶剂由上述水不溶性着色剂 材料和不良溶剂，并且油墨中的良溶剂的总量（质量％）由A表示，并且油墨中的不良溶剂的总量（质量％）表示为 由B表示，A与B的比例范围为10：5至7：9，并且当上述水溶性有机溶剂的各自的Ka值由Bristow法确定并相互比较时， Ka值最大的水溶性有机溶剂是不良溶剂。 颜料墨水即使用少量的油墨也具有足够大的面积因子，并提供高OD的图像。

公开(公告)号：US08007097B2

公开(公告)日：2011-08-30

申请号：US11931985

申请日：2007-10-31

申请人： Mikio Sanada ,  Katsuhiko Takahashi ,  Masashi Ogasawara ,  Tomonari Watanabe ,  Yui Tokuda

发明人： Mikio Sanada ,  Katsuhiko Takahashi ,  Masashi Ogasawara ,  Tomonari Watanabe ,  Yui Tokuda

IPC分类号： G01D11/00

CPC分类号： B41J2/211 ,  B41J2/2107 ,  C09D11/32

摘要： A water-based ink of the present invention includes water, a plurality of different water-soluble organic solvents, and a water-insoluble coloring material, wherein the above water-soluble organic solvents consist of a good solvent to the above water-insoluble coloring material and a poor solvent to the above water-insoluble coloring material, and the total amount (% by mass) of the good solvents in the ink is represented by A and the total amount (% by mass) of the poor solvent in the ink is represented by B, the ratio of A to B ranges from 10:5 to 10:30 both inclusive, and when the respective Ka values of the above water-soluble organic solvents are determined by the Bristow method and compared with each other, a water-soluble organic solvent having the largest Ka value is the poor solvent. The pigment ink has a sufficiently large area factor even with a small amount of ink and provides an image of high OD.

摘要翻译： 本发明的水性油墨包括水，多种不同的水溶性有机溶剂和水不溶性着色材料，其中上述水溶性有机溶剂由上述水不溶性着色剂 材料和不良溶剂，并且油墨中的良溶剂的总量（质量％）由A表示，并且油墨中的不良溶剂的总量（质量％）表示为 由B表示，A与B的比例范围为10:5至10:30，并且当通过Bristow方法确定上述水溶性有机溶剂的各自的Ka值并相互比较时， Ka值最大的水溶性有机溶剂是不良溶剂。 颜料墨水即使用少量的油墨也具有足够大的面积因子，并提供高OD的图像。