Process for removing carbon dioxide from combustion gases
    1.
    发明授权
    Process for removing carbon dioxide from combustion gases 失效
    从燃烧气体中除去二氧化碳的方法

    公开(公告)号:US5603908A

    公开(公告)日:1997-02-18

    申请号:US651501

    申请日:1996-05-22

    IPC分类号: B01D53/14 C01B32/50 B01D53/62

    摘要: A process for removing CO.sub.2 from a combustion gas which comprises removing CO.sub.2 from the combustion gas through contact of an aqueous hindered amine solution used as a CO.sub.2 absorbent solution with the combustion gas at atmospheric pressure and then, in a regeneration column, liberating CO.sub.2 from the absorbent solution that has absorbed CO.sub.2 by heating it and thereby regenerating the absorbent solution. The process further comprises a partial absorbent solution regeneration step in at least one stage wherein the absorbent solution that has absorbed CO.sub.2 is heated through heat exchange with a high-temperature regenerated absorbent solution and part of the CO.sub.2 that is liberated is separated from the absorbent solution. Following this, according to the necessity, part of the partially regenerated absorbent solution thus obtained is returned to the step of removing CO.sub.2 from the combustion gas for use as part of the CO.sub.2 absorbent solution while the rest or all of the absorbent solution is heated and fed to a regeneration column further to liberate CO.sub.2 and regenerate the absorbent solution.

    摘要翻译: 一种用于从燃烧气体中除去CO 2的方法,其包括通过在大气压下与用作CO 2吸收剂溶液的水性受阻胺溶液和燃烧气体接触而从燃烧气体中除去CO 2,然后在再生塔中将CO 2从 吸收剂溶液通过加热而吸收CO 2,从而再生吸收剂溶液。 该方法还包括在至少一个阶段中的部分吸收溶液再生步骤,其中吸收了CO 2的吸收剂溶液通过与高温再生吸收剂溶液进行热交换而被加热,并且部分释放的CO 2与吸收剂溶液分离 。 然后,根据需要,由此获得的部分再生的吸收剂溶液的一部分返回到从燃烧气体中除去CO 2作为CO 2吸收剂溶液的一部分的步骤,同时其余部分或全部吸收剂溶液被加热, 进料到再生塔以释放CO 2并再生吸收剂溶液。

    Method for removing carbon dioxide from combustion exhaust gas
    2.
    发明授权
    Method for removing carbon dioxide from combustion exhaust gas 失效
    从燃烧废气中除去二氧化碳的方法

    公开(公告)号:US6036931A

    公开(公告)日:2000-03-14

    申请号:US867988

    申请日:1997-06-03

    IPC分类号: B01D53/14 B01D53/62

    摘要: There are disclosed a method for removing CO.sub.2 from a combustion exhaust gas which comprises the step of bringing the combustion exhaust gas under atmospheric pressure into contact with an aqueous solution of a hindered amine selected from the group consisting of 2-amino-2-methyl-1-propanol, 2-methylaminoethanol, 2-ethylaminoethanol and 2-piperidineethanol; and another method for removing carbon dioxide from a combustion exhaust gas which comprises the step of bringing the combustion exhaust gas under atmospheric pressure into contact with a mixed aqueous solution of 100 parts by weight of an amine compound (X) selected from the group consisting of 2-amino-2-methyl-1,3-propanediol, 2-amino-2-methyl-1-propanol, 2-amino-2-ethyl-1,3-propanediol, t-butyldiethanolamine and 2-amino-2-hydroxymethyl-1,3-propanediol; and 1-25 parts by weight of an amine compound (Y) selected from the group consisting of piperazine, piperidine, morpholine, glycine, 2-methylaminoethanol, 2-piperidineethanol and 2-ethylaminoethanol.

    摘要翻译: 公开了一种从燃烧废气中除去CO 2的方法,其包括使大气压下的燃烧废气与受阻胺的水溶液接触的步骤,所述受阻胺的水溶液选自2-氨基-2-甲基 - 1-丙醇,2-甲基氨基乙醇,2-乙基氨基乙醇和2-哌啶乙醇; 以及从燃烧废气中除去二氧化碳的另一种方法,其包括使大气压下的燃烧废气与100重量份选自以下的胺化合物(X)的混合水溶液接触的步骤: 2-氨基-2-甲基-1,3-丙二醇,2-氨基-2-甲基-1-丙醇,2-氨基-2-乙基-1,3-丙二醇,叔丁基二乙醇胺和2-氨基-2-甲基-1-丙醇, 羟甲基-1,3-丙二醇; 和1-25重量份选自哌嗪,哌啶,吗啉,甘氨酸,2-甲基氨基乙醇,2-哌啶乙醇和2-乙基氨基乙醇的胺化合物(Y)。

    Method for removing carbon dioxide from combustion exhaust gas
    3.
    发明授权
    Method for removing carbon dioxide from combustion exhaust gas 失效
    从燃烧废气中除去二氧化碳的方法

    公开(公告)号:US06500397B1

    公开(公告)日:2002-12-31

    申请号:US09187168

    申请日:1998-11-06

    IPC分类号: B01D5362

    摘要: There are disclosed a method for removing CO2 from a combustion exhaust gas which comprises the step of bringing the combustion exhaust gas under atmospheric pressure into contact with an aqueous solution of a hindered amine selected from the group consisting of 2-amino-2-methyl-1-propanol, 2-methylaminoethanol, 2-ethylamino-ethanol and 2-piperidineethanol; and another method for removing carbon dioxide from a combustion exhaust gas which comprises the step of bringing the combustion exhaust gas under atmospheric pressure into contact with a mixed aqueous solution of 100 parts by weight of an amine compound (X) selected from the group consisting of 2-amino-2-methyl-1, 3-propanediol, 2-amino-2-methyl-1-propanol, 2-amino-2-ethyl-1, 3-propanediol, t-butyldiethanolamine and 2-amino-2-hydroxymethyl-1,3-propanediol; and 1-25 parts by weight of an amine compound (Y) selected from the group consisting of piperazine, piperidine, morpholine, glycine, 2-methylamino-ethanol, 2-piperidineethanol and 2-ethylaminoethanol.

    摘要翻译: 公开了一种从燃烧废气中除去CO 2的方法,其包括使大气压下的燃烧废气与受阻胺的水溶液接触的步骤,所述受阻胺的水溶液选自2-氨基-2-甲基 - 1-丙醇,2-甲基氨基乙醇,2-乙基氨基 - 乙醇和2-哌啶乙醇; 以及从燃烧废气中除去二氧化碳的另一种方法,其包括使大气压下的燃烧废气与100重量份选自以下的胺化合物(X)的混合水溶液接触的步骤: 2-氨基-2-甲基-1,3-丙二醇,2-氨基-2-甲基-1-丙醇,2-氨基-2-乙基-1,3-丙二醇,叔丁基二乙醇胺和2-氨基-2-丙醇, 羟甲基-1,3-丙二醇; 和1-25重量份选自哌嗪,哌啶,吗啉,甘氨酸,2-甲基氨基 - 乙醇,2-哌啶乙醇和2-乙基氨基乙醇的胺化合物(Y)。

    Process for removing carbon dioxide from combustion gases
    6.
    发明授权
    Process for removing carbon dioxide from combustion gases 失效
    从燃烧气体中除去二氧化碳的方法

    公开(公告)号:US06689332B1

    公开(公告)日:2004-02-10

    申请号:US08603186

    申请日:1996-02-20

    IPC分类号: B01D5362

    摘要: A process for removing CO2 from a combustion gas which comprises bringing a combustion gas containing oxygen and CO2 and a CO2 absorbent solution into contact at the atmospheric pressure, thereby allowing the CO2 absorbent solution to absorb CO2 from the combustion gas, and, in the ensuing step, heating the absorbent solution that has absorbed CO2 to liberate CO2 and regenerate the CO2 absorbent solution, and circulating the regenerated solution for reuse. An aqueous solution of a hindered amine selected from the group consisting of 2-amino-2-methyl-1-propanol (AMP), 2-(ethylamino)-ethanol (EAE), 2-(methylamino)-ethanol (MAE), and 2-(diethylamino)-ethanol (DEAE) is used as the CO2 absorbent solution, and carbon steel is used in building the members of the equipment that contact the aqueous hindered amine solution. The absorbent solution contains cupric carbonate which is a corrosion inhibitor.

    摘要翻译: 一种从燃烧气体中除去CO 2的方法,该方法包括使含有氧和CO 2的燃烧气体和CO 2吸收剂溶液在大气压下接触,从而使CO 2吸收剂溶液从燃烧气体中吸收CO 2, 加热吸收了二氧化碳的吸收剂溶液以释放二氧化碳并再生二氧化碳吸收剂溶液,再循环再生溶液再利用。 选自2-氨基-2-甲基-1-丙醇(AMP),2-(乙基氨基) - 乙醇(EAE),2-(甲基氨基) - 乙醇(MAE), 和2-(二乙基氨基) - 乙醇(DEAE)用作CO 2吸收剂溶液,碳钢用于构建与受阻胺水溶液接触的设备的构件。 吸收剂溶液含有作为缓蚀剂的碳酸铜。

    Recovery of carbon dioxide from combustion exhaust gas
    8.
    发明授权
    Recovery of carbon dioxide from combustion exhaust gas 失效
    从燃烧废气中回收二氧化碳

    公开(公告)号:US5339633A

    公开(公告)日:1994-08-23

    申请号:US957185

    申请日:1992-10-07

    IPC分类号: B01D53/14 F01K13/00 F01K17/00

    摘要: An electric generating power plant and a method of operation thereof wherein the boiler (1) produces steam to a turbine driven-generator (2), carbon dioxide from combustion exhaust gas emitted from the boiler is simultaneously absorbed in an absorbing solution in an absorber (7), the absorbing solution with the absorbed carbon dioxide is passed through a regenerator (10) where the carbon dioxide is stripped from the absorbing solution, the regenerated absorbing solution is returned to the absorber (7), and steam from either the boiler (1) or turbine of the turbine-driven generator (2) is supplied to a reboiler (13) to provide heat for operation of the regenerator (10). During periods of high demand for electric power steam extraction from the boiler or turbine is discontinued, operation of the regenerator (10) is discontinued and the absorbing solution from the absorber (7) is stored in a first storage unit (15). During periods of low power demand steam is supplied to the reboiler (13) from the boiler (1) or turbine and absorbing solution from the first storage unit (15) is fed to the regenerator (10) for operation thereof, and absorbing solution stripped of carbon dioxide from the regenerator (10) is stored in a second storage unit (16). Absorbing solution from the second storage unit (16) is fed to the absorber (7) during periods of high power demand.

    摘要翻译: 一种发电厂及其操作方法,其中锅炉(1)向涡轮机驱动发电机(2)产生蒸汽,从锅炉排出的来自燃烧废气的二氧化碳同时吸收在吸收器中的吸收溶液中 如图7所示,吸收的二氧化碳的吸收溶液通过再生器(10),二氧化碳从吸收溶液中汽提出来,再生的吸收液返回吸收器(7),蒸汽从锅炉 1)或涡轮机驱动的发电机(2)的涡轮机被供应到再沸器(13)以提供用于再生器(10)的操作的热量。 在对来自锅炉或涡轮机的电力蒸汽提取的高需求期间,中止再生器(10)的运行,并且来自吸收器(7)的吸收溶液被存储在第一存储单元(15)中。 在低功率需求期间,从锅炉(1)向再沸器(13)供应蒸汽,或将来自第一储存单元(15)的涡轮机和吸收溶液供给到再生器(10)进行操作,并吸收溶液 来自再生器(10)的二氧化碳存储在第二存储单元(16)中。 在高功率需求期间,来自第二存储单元(16)的吸收溶液被供给到吸收器(7)。

    Apparatus and process for removing carbon dioxide from combustion
exhaust gas
    10.
    发明授权
    Apparatus and process for removing carbon dioxide from combustion exhaust gas 失效
    从燃烧废气中除去二氧化碳的设备和方法

    公开(公告)号:US5318758A

    公开(公告)日:1994-06-07

    申请号:US847733

    申请日:1992-03-09

    IPC分类号: B01D53/14 B01D53/62 B01D53/34

    摘要: An apparatus and a process for removing CO.sub.2 from a combustion exhaust gas, by effecting counterflow contact of aqueous alkanolamine solution with the combustion exhaust gas to absorb CO.sub.2 from the gas in the alkanolamine solution and effecting a further contact of the gas with either, condensate water formed by causing condensation of the gas after removal of CO.sub.2, or condensate water formed by causing condensation of the combustion exhaust gas directly after combustion of the fuel. The apparatus includes a tower (1), a first contact section (2) in the tower through which the exhaust gas flows upwardly in counterflow contact with the aqueous alkanolamine solution dispersed by a nozzle device (7) downstream of the first contact section (2), a second contact section (3) in the tower (1) downstream of the nozzle device (7) for effecting counterflow contact of reflux water from a spent absorbent liquor regenerating tower (28) with the gas after removal of CO.sub.2. The temperature of the aqueous alkanolamine solution to be supplied to the CO.sub.2 -removing tower (1) is adjusted in such a manner that the temperature of the exhaust gas at the entrance (4) of the CO.sub.2 -removing tower and that of the treated gas at the exit (5) of the CO.sub.2 -removing tower are the same.

    摘要翻译: 一种用于从燃烧废气中除去CO 2的装置和方法,其通过使烷基醇胺水溶液与燃烧废气逆流接触以从烷醇胺溶液中的气体吸收CO 2,并进一步接触气体与冷凝水 通过在除去CO 2之后使气体冷凝或通过在燃料燃烧之后直接使燃烧废气冷凝而形成的冷凝水形成。 该设备包括塔架(1),塔架中的第一接触部分(2),废气通过该塔架与第一接触部分(2)下游的喷嘴装置(7)与由烷基醇胺水溶液逆流接触而向上流动 ),在喷嘴装置(7)下游的塔(1)中的第二接触部分(3),用于在去除CO 2之后使来自废吸收剂液体再生塔(28)的回流水与气体逆流接触。 供给至二氧化碳除去塔(1)的烷醇胺水溶液的温度调节为使得除去CO 2塔的入口(4)的排气温度和处理气体的排气温度 在二氧化碳除去塔的出口(5)是相同的。