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公开(公告)号：US07989580B2
公开(公告)日：2011-08-02
申请号：US12260378
申请日：2008-10-29
CPC分类号： C07F15/0046 , C07F15/0033 , C07F15/06 , Y10S428/917
摘要： Metal complexes of formula I and IA and polymers derived from the complexes are useful in optoelectronic devices wherein M is Ir, Co or Rh; is a cyclometallated ligand; R1 is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, or substituted arylalkyl; R2 is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl; and at least one of R1 and R2 is other than hydrogen; R1a is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, or substituted arylalkyl; R2a is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl; and at least one of R1a and R2a is substituted alkyl, substituted aryl, substituted arylalkyl, and at least one substitutent of the substituted alkyl, substituted aryl, or substituted arylalkyl is a polymerizable group.
摘要翻译： 式I和IA的金属络合物和衍生自络合物的聚合物可用于其中M为Ir，Co或Rh的光电器件; 是环金属配体; R 1是氢，烷基，取代的烷基，芳基，取代的芳基，芳基烷基或取代的芳基烷基; R2是氢，烷基，取代的烷基，芳基，取代的芳基，芳基烷基，取代的芳基烷基; 并且R 1和R 2中的至少一个不是氢; R 1a是氢，烷基，取代的烷基，芳基，取代的芳基，芳基烷基或取代的芳基烷基; R2a是氢，烷基，取代的烷基，芳基，取代的芳基，芳基烷基，取代的芳烷基; 并且R 1a和R 2a中的至少一个是取代的烷基，取代的芳基，取代的芳烷基，并且取代的烷基，取代的芳基或取代的芳烷基的至少一个取代基是可聚合基团。
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公开(公告)号：US20100105852A1
公开(公告)日：2010-04-29
申请号：US12260378
申请日：2008-10-29
IPC分类号： C07F15/00 , C08F230/04
CPC分类号： C07F15/0046 , C07F15/0033 , C07F15/06 , Y10S428/917
摘要： Metal complexes of formula I and IA and polymers derived from the complexes are useful in optoelectronic devices wherein M is Ir, Co or Rh; is a cyclometallated ligand; R1 is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, or substituted arylalkyl; R2 is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl; and at least one of R1 and R2 is other than hydrogen; R1a is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, or substituted arylalkyl; R2a is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl; and at least one of R1a and R2a is substituted alkyl, substituted aryl, substituted arylalkyl, and at least one substitutent of the substituted alkyl, substituted aryl, or substituted arylalkyl is a polymerizable group.
摘要翻译： 式I和IA的金属络合物和衍生自络合物的聚合物可用于其中M为Ir，Co或Rh的光电器件; 是环金属配体; R 1是氢，烷基，取代的烷基，芳基，取代的芳基，芳基烷基或取代的芳基烷基; R2是氢，烷基，取代的烷基，芳基，取代的芳基，芳基烷基，取代的芳基烷基; 并且R 1和R 2中的至少一个不是氢; R 1a是氢，烷基，取代的烷基，芳基，取代的芳基，芳基烷基或取代的芳基烷基; R2a是氢，烷基，取代的烷基，芳基，取代的芳基，芳基烷基，取代的芳基烷基; 并且R 1a和R 2a中的至少一个是取代的烷基，取代的芳基，取代的芳烷基，并且取代的烷基，取代的芳基或取代的芳烷基的至少一个取代基是可聚合基团。
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公开(公告)号：US07718087B2
公开(公告)日：2010-05-18
申请号：US11504552
申请日：2006-08-14
CPC分类号： C09K11/06 , C08L65/00 , C09K2211/1007 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092 , C09K2211/185 , H01L51/0039 , H01L51/0043 , H01L51/0085 , H01L51/5012 , H01L51/5016 , H01L51/5048 , H01L51/5088 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要： The present invention provides compositions comprising at least one novel polymeric organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The polymeric organic iridium compositions of the present invention are referred to as Type (2) organic iridium compositions and are constituted such that at least one ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (2) organic iridium compositions are referred to herein as comprising “polymeric organic iridium complexes”. The novel organic iridium compositions are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel organic iridium compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译： 本发明提供包含至少一种包含至少一种环金属配体和至少一种酮吡咯配体的新型聚合有机铱化合物的组合物。 本发明的聚合有机铱组合物称为（2）型有机铱组合物，其构成为使得新型有机铱化合物的至少一种配位体的数均分子量为2000克/摩尔或更高（如 通过凝胶渗透色谱法测定）。 类型（2）有机铱组合物在本文中被称为包含“聚合有机铱络合物”。 新型有机铱组合物可用于诸如OLED器件和光电器件的光电子器件。 一方面，本发明提供了用于制备具有增强的颜色特性和光输出效率的OLED器件的新型有机铱组合物。
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公开(公告)号：US07695640B2
公开(公告)日：2010-04-13
申请号：US11506001
申请日：2006-08-17
CPC分类号： H05B33/14 , C08L65/00 , C09K11/06 , C09K2211/1007 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1088 , C09K2211/185 , H01L51/0039 , H01L51/0043 , H01L51/0085 , H01L51/5016 , H01L51/5048 , H01L51/5088 , Y02E10/549 , Y10S428/917
摘要： The present invention provides novel polymer compositions comprising a polymeric component and a novel organic iridium compound comprising at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compounds used in the polymer compositions are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising “organic iridium complexes”. In one aspect, the polymeric component may be an electroactive polymer. The novel polymer compositions of the invention are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel polymer compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译： 本发明提供了包含聚合物组分和包含至少一种环金属配体和至少一种酮吡咯配体的新型有机铱化合物的新型聚合物组合物。 在聚合物组合物中使用的有机铱化合物被称为类型（1）有机铱组合物，并且构成为使得新的有机铱化合物的配体的数均分子量为每摩尔或更大2000克（如通过 凝胶渗透色谱）。 类型（1）有机铱组合物在本文中被称为包含“有机铱络合物”。 在一个方面，聚合物组分可以是电活性聚合物。 本发明的新型聚合物组合物可用于诸如OLED器件和光伏器件的光电子器件。 在一个方面，本发明提供了可用于制备具有增强的颜色特性和光输出效率的OLED器件的新型聚合物组合物。
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公开(公告)号：US20080026250A1
公开(公告)日：2008-01-31
申请号：US11507051
申请日：2006-08-18
申请人： Kelly Scott Chichak , James Anthony Cella , Kyle Erik Litz , Joseph John Shiang , Qing Ye , Kevin Henry Janora , Gautam Parthasarathy
发明人： Kelly Scott Chichak , James Anthony Cella , Kyle Erik Litz , Joseph John Shiang , Qing Ye , Kevin Henry Janora , Gautam Parthasarathy
CPC分类号： H01L51/0085 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/1037 , C09K2211/1088 , C09K2211/1416 , C09K2211/1425 , C09K2211/185 , H01L51/0039 , H01L51/0043 , H01L51/5016 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要： The present invention provides electronic devices comprising novel polymer compositions which provide for enhanced device performance. The polymer compositions employed comprise a polymeric component and a novel organic iridium compound comprising at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compounds used in the polymer compositions are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). In one aspect, the polymeric component may be an electroactive polymer. In one aspect, the present invention provides optoelectronic devices, such as OLED devices and photovoltaic devices. In another aspect, the invention provides OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译： 本发明提供了包括提供增强的器件性能的新型聚合物组合物的电子器件。 使用的聚合物组合物包含聚合物组分和包含至少一种环金属化配体和至少一种酮吡咯配体的新型有机铱化合物。 在聚合物组合物中使用的有机铱化合物被称为类型（1）有机铱组合物，并且构成为使得新的有机铱化合物的配体的数均分子量为每摩尔或更大2000克（如通过 凝胶渗透色谱）。 在一个方面，聚合物组分可以是电活性聚合物。 在一个方面，本发明提供了诸如OLED器件和光伏器件之类的光电器件。 在另一方面，本发明提供具有增强的颜色特性和光输出效率的OLED器件。
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公开(公告)号：US07718277B2
公开(公告)日：2010-05-18
申请号：US11504870
申请日：2006-08-16
CPC分类号： H01L51/0085 , H01L51/0035 , H01L51/004 , H01L51/0043 , H01L51/5016 , Y02E10/549 , Y10S428/917
摘要： The present invention provides electronic devices comprising novel polymeric organic iridium compositions which provide for enhanced device performance. The polymeric organic iridium compositions employed comprise a polymeric organic iridium compound comprising at least one cyclometallated ligand and at least one ketopyrrole ligand. The polymeric organic iridium compositions employed are referred to as Type (2) organic iridium compositions and are constituted such that at least one ligand of the polymeric organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (2) organic iridium compositions are referred to herein as comprising “polymeric organic iridium complexes”. In one aspect, the present invention provides optoelectronic devices, such as OLED devices and photovoltaic devices. In another aspect, the invention provides OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译： 本发明提供了包含新型聚合物有机铱组合物的电子器件，其提供增强的器件性能。 所用的聚合有机铱组合物包括含有至少一个环金属配体和至少一个酮基吡咯配体的聚合有机铱化合物。 所使用的聚合有机铱组合物称为类型（2）有机铱组合物，并且构成为使得聚合有机铱化合物的至少一种配体的数均分子量为每摩尔或更大2000克（通过凝胶测量） 渗透色谱）。 类型（2）有机铱组合物在本文中被称为包含“聚合有机铱络合物”。 在一个方面，本发明提供了诸如OLED器件和光伏器件之类的光电器件。 在另一方面，本发明提供具有增强的颜色特性和光输出效率的OLED器件。
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公开(公告)号：US20080026249A1
公开(公告)日：2008-01-31
申请号：US11506002
申请日：2006-08-17
申请人： Kelly Scott Chichak , James Anthony Cella , Kyle Erik Litz , Joseph John Shiang , Qing Ye , Kevin Henry Janora , Gautam Parthasarathy
发明人： Kelly Scott Chichak , James Anthony Cella , Kyle Erik Litz , Joseph John Shiang , Qing Ye , Kevin Henry Janora , Gautam Parthasarathy
CPC分类号： H01L51/0085 , C09K11/06 , C09K2211/1029 , C09K2211/1037 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092 , C09K2211/1466 , C09K2211/1475 , C09K2211/185 , H01L51/0035 , H01L51/0039 , H01L51/0043 , H01L51/5016 , H01L51/5048 , H01L51/5088 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要： The present invention provides electronic devices comprising novel organic iridium compositions which provide for enhanced device performance. The novel iridium compositions employed comprise at least one novel organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compositions employed are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising “organic iridium complexes”. In one aspect, the present invention provides optoelectronic devices, such as OLED devices and photovoltaic devices. In another aspect, the invention provides OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译： 本发明提供了包含新型有机铱组合物的电子器件，其提供增强的器件性能。 所用的新型铱组合物包含至少一种包含至少一种环金属配体和至少一种酮基吡咯配体的新型有机铱化合物。 使用的有机铱组合物称为类型（1）有机铱组合物，并且构成为使得新型有机铱化合物的配体的数均分子量为每摩尔或更大2000克（通过凝胶渗透色谱法测量） 。 类型（1）有机铱组合物在本文中被称为包含“有机铱络合物”。 在一个方面，本发明提供了诸如OLED器件和光伏器件之类的光电器件。 在另一方面，本发明提供具有增强的颜色特性和光输出效率的OLED器件。
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公开(公告)号：US20100090586A1
公开(公告)日：2010-04-15
申请号：US11504870
申请日：2006-08-16
IPC分类号： H01J1/62
CPC分类号： H01L51/0085 , H01L51/0035 , H01L51/004 , H01L51/0043 , H01L51/5016 , Y02E10/549 , Y10S428/917
摘要： The present invention provides electronic devices comprising novel polymeric organic iridium compositions which provide for enhanced device performance. The polymeric organic iridium compositions employed comprise a polymeric organic iridium compound comprising at least one cyclometallated ligand and at least one ketopyrrole ligand. The polymeric organic iridium compositions employed are referred to as Type (2) organic iridium compositions and are constituted such that at least one ligand of the polymeric organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (2) organic iridium compositions are referred to herein as comprising “polymeric organic iridium complexes”. In one aspect, the present invention provides optoelectronic devices, such as OLED devices and photovoltaic devices. In another aspect, the invention provides OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译： 本发明提供了包含新型聚合物有机铱组合物的电子器件，其提供增强的器件性能。 所用的聚合有机铱组合物包括含有至少一个环金属配体和至少一个酮基吡咯配体的聚合有机铱化合物。 所使用的聚合有机铱组合物称为类型（2）有机铱组合物，并且构成为使得聚合有机铱化合物的至少一种配体的数均分子量为每摩尔或更大2000克（通过凝胶测量） 渗透色谱）。 类型（2）有机铱组合物在本文中被称为包含“聚合有机铱络合物”。 在一个方面，本发明提供了诸如OLED器件和光伏器件之类的光电器件。 在另一方面，本发明提供具有增强的颜色特性和光输出效率的OLED器件。
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公开(公告)号：US07691494B2
公开(公告)日：2010-04-06
申请号：US11506002
申请日：2006-08-17
申请人： Kelly Scott Chichak , James Anthony Cella , Kyle Erik Litz , Joseph John Shiang , Qing Ye , Kevin Henry Janora , Gautam Parthasarathy
发明人： Kelly Scott Chichak , James Anthony Cella , Kyle Erik Litz , Joseph John Shiang , Qing Ye , Kevin Henry Janora , Gautam Parthasarathy
CPC分类号： H01L51/0085 , C09K11/06 , C09K2211/1029 , C09K2211/1037 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092 , C09K2211/1466 , C09K2211/1475 , C09K2211/185 , H01L51/0035 , H01L51/0039 , H01L51/0043 , H01L51/5016 , H01L51/5048 , H01L51/5088 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要： The present invention provides electronic devices comprising novel organic iridium compositions which provide for enhanced device performance. The novel iridium compositions employed comprise at least one novel organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compositions employed are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising “organic iridium complexes”. In one aspect, the present invention provides optoelectronic devices, such as OLED devices and photovoltaic devices. In another aspect, the invention provides OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译： 本发明提供了包含新型有机铱组合物的电子器件，其提供增强的器件性能。 所用的新型铱组合物包含至少一种包含至少一种环金属配体和至少一种酮基吡咯配体的新型有机铱化合物。 使用的有机铱组合物称为类型（1）有机铱组合物，并且构成为使得新型有机铱化合物的配体的数均分子量为每摩尔或更大2000克（通过凝胶渗透色谱法测量） 。 类型（1）有机铱组合物在本文中被称为包含“有机铱络合物”。 在一个方面，本发明提供了诸如OLED器件和光伏器件之类的光电器件。 在另一方面，本发明提供具有增强的颜色特性和光输出效率的OLED器件。
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公开(公告)号：US07691292B2
公开(公告)日：2010-04-06
申请号：US11504871
申请日：2006-08-16
CPC分类号： C07F15/0033 , H01L51/0035 , H01L51/0043 , H01L51/0061 , H01L51/0085 , H01L51/5012 , Y02E10/549 , Y10S428/917
摘要： The present invention provides compositions comprising at least one novel organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compositions of the present invention are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising “organic iridium complexes”. The novel organic iridium compositions are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel organic iridium compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译： 本发明提供包含至少一种包含至少一种环金属配体和至少一种酮吡咯配体的新型有机铱化合物的组合物。 本发明的有机铱组合物被称为类型（1）有机铱组合物，并且构成为使得新的有机铱化合物的配体的数均分子量为每摩尔或更大2000克（通过凝胶测量） 渗透色谱）。 类型（1）有机铱组合物在本文中被称为包含“有机铱络合物”。 新型有机铱组合物可用于诸如OLED器件和光电器件的光电子器件。 一方面，本发明提供了用于制备具有增强的颜色特性和光输出效率的OLED器件的新型有机铱组合物。
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