Carbon electrode coated with porous metal film, its fabrication method and lithium secondary battery using the same
    2.
    发明授权
    Carbon electrode coated with porous metal film, its fabrication method and lithium secondary battery using the same 有权
    涂有多孔金属膜的碳电极,其制造方法和使用其的锂二次电池

    公开(公告)号:US06780541B2

    公开(公告)日:2004-08-24

    申请号:US09932940

    申请日:2001-08-21

    IPC分类号: H01M458

    摘要: A method for fabricating carbon electrode coated with a porous metal film includes the steps of: positioning a roll of carbon material within a vacuum chamber; winding the carbon material off the roll at a certain speed, winding the carbon material on a different roll while coating a porous metal to a thickness of a few Řa few &mgr;m on the carbon material between the two rolls from a metal evaporation source; and stabilizing the thusly coated carbon material under a vacuum. The coated porous metal film is of Li, Al, Sn, Bi, Si, Sb, Ni, Cu, Ti, V, Cr, Mn, Fe, Co, Zn, Mo, W, Ag, Au, Pt, Ru, Ir, In or their alloys. Since the stable film is formed on the surface of the carbon material, when the thusly coated carbon material is use for forming a cathode electrode of a secondary battery, the reversibility and high rate charging and discharging characteristics of the carbon electrode can be improved. In addition, when a lithium-ion secondary battery is fabricated using the carbon electrode coated with lithium or a lithium alloy, the capacity degradation due to the irreversible capacity of the conventional carbon electrode appearing at the initial state of charging can be prevented, so that the capacity can be increased.

    摘要翻译: 涂覆有多孔金属膜的碳电极的制造方法包括以下步骤:将碳材料卷定位在真空室内; 以一定的速度将碳材料从轧辊上卷绕,将碳材料卷绕在不同的辊上,同时在来自金属蒸发源的两个辊之间的碳材料上涂覆几微米厚度的多孔金属; 并在真空下稳定如此涂覆的碳材料。 涂层多孔金属膜为Li,Al,Sn,Bi,Si,Sb,Ni,Cu,Ti,V,Cr,Mn,Fe,Co,Zn,Mo,W,Ag,Au,Pt,Ru,Ir ,In或它们的合金。 由于在碳材料的表面上形成稳定的膜,所以当这样涂覆的碳材料用于形成二次电池的阴极时,可以提高碳电极的可逆性和高速充放电特性。 此外,当使用涂覆有锂或锂合金的碳电极制造锂离子二次电池时,可以防止由于在初始充电状态下出现的常规碳电极的不可逆容量导致的容量降低,使得 可以增加容量。

    Multi-layered, UV-cured polymer electrolyte and lithium secondary battery comprising the same
    3.
    发明授权
    Multi-layered, UV-cured polymer electrolyte and lithium secondary battery comprising the same 有权
    多层,紫外线固化的聚合物电解质和包含其的锂二次电池

    公开(公告)号:US07135254B2

    公开(公告)日:2006-11-14

    申请号:US10275383

    申请日:2001-01-31

    IPC分类号: H01M6/18

    摘要: The present invention relates to a multi-layered, UV-cured polymer electrolyte and lithium secondary battery comprising the same, wherein the polymer electrolyte comprises: A) a separator layer formed of polymer electrolyte, PP, PE, PVdF or non-woven fabric, wherein the separator layer having two surfaces; B) at least one gelled polymer electrolyte layer located on at least one surface of the separator layer comprising: a) polymer obtained by curing ethyleneglycoldi(meth)acrylate oligomer of the formula (I) by UV irradiation: CH2═CR1COO(CH2CH2O)nCOCR2═CH2 wherein, R1 and R2 are independently hydrogen or methyl group, and n is a integer of 3–20; and b) at least one polymer selected from the group consisting of PVdF-based polymer, PAN-based polymer, PMMA-based polymer and PVC-based polymer; and C) organic electrolyte solution in which lithium salt is dissolved in a solvent.

    摘要翻译: 本发明涉及包含该聚合物电解质的多层紫外线固化的聚合物电解质和锂二次电池,其中所述聚合物电解质包括:A)由聚合物电解质,PP,PE,PVdF或无纺布形成的隔离层, 其中所述隔离层具有两个表面; B)位于分离器层的至少一个表面上的至少一个胶凝聚合物电解质层,包括:a)通过UV照射固化式(I)的乙二醇二(甲基)丙烯酸酯低聚物获得的聚合物:CH 2 CO 2(CH 2 CH 2 CH 2)n CO 2 CH 2 CO 2(CH 2 CH 2 CH 2) 其中,R 1和R 2各自独立地为氢或甲基,n为3-20的整数; 和b)至少一种选自PVdF基聚合物,PAN基聚合物,基于PMMA的聚合物和基于PVC的聚合物的聚合物; 和C)其中锂盐溶解在溶剂中的有机电解质溶液。