摘要:
The present invention relates to a vinyl chloride polymer having good thermal stability due to the restraint of dehydrochlorination by heat or ultraviolet rays, and a method of preparing the same. The generation of the dehydrochlorination of the vinyl chloride polymer due to heat or ultraviolet rays may be markedly restrained, the thermal stability thereof may be improved, and the discoloration thereof or the modification of the physical properties thereof may be prevented. In addition, a modifier may be introduced to a polymerization process at the end of the polymerization, and high thermal stability may be attained without generating the transformation of the vinyl chloride polymer.
摘要:
The present invention provides a post-treatment method of a vinyl chloride-based polymer including: (a) preparing a stream containing vinyl chloride-based polymer powder and unreacted vinyl chloride-based monomers by drying a vinyl chloride-based polymer latex in a drying unit; (b) filtering the stream containing the vinyl chloride-based polymer powder and the unreacted vinyl chloride-based monomers in a filtering unit; and (c) recirculating a gas containing the unreacted vinyl chloride-based monomers discharged from the filtering unit to a latex storage unit.
摘要:
The present disclosure provides a method for preparing a polymerization initiator composition, including (a) a step of mixing water and a water-soluble initiator to prepare an aqueous initiator solution having a concentration of 1 to 10%; and (b) a step of activating the aqueous initiator solution, wherein the step of activating is performed by (b-1) a step of heat treating the aqueous initiator solution for 0.5 to 4.5 hours at a temperature of 48 to 62° C.; and (b-2) a step of treating the aqueous initiator solution to achieve pH of 1 to 7, where the steps above are performed in no particular order.
摘要:
Provided is a method of producing a vinyl chloride-based polymer composite, which includes: forming particle nuclei by bulk polymerizing vinyl chloride-based monomers; producing a vinyl chloride-based polymer by bulk polymerizing vinyl chloride-based monomers in the presence of the particle nuclei; and producing a vinyl chloride-based polymer composite including the vinyl chloride-based polymer and a cellulose-based compound.
摘要:
The present invention relates to a vinyl chloride-based polymer composition and a method for producing the same, and more particularly, to a vinyl chloride-based polymer composition including a vinyl chloride-based polymer and a plasticizer, wherein the vinyl chloride-based polymer includes a higher fatty acid having 10 to 18 carbon atoms in an amount of more than 0.05 parts by weight to less than 2.0 parts by weight, based on 100 parts by weight of the vinyl chloride-based polymer.
摘要:
The present invention relates to a method for preparing a vinyl chloride-based polymer, including: bulk polymerizing a vinyl chloride-based monomer in a polymerization reactor to prepare a vinyl chloride-based polymer; and adding water and vapor to the polymerization reactor, and heating to remove an unreacted vinyl chloride-based monomer, wherein an addition amount of the water is 0.500 to 5.000 parts by weight based on 100 parts by weight of the vinyl chloride-based polymer.
摘要:
Provided is a method of preparing a vinyl chloride-based polymer composite, which includes: bulk-polymerizing vinyl chloride-based monomers to prepare a vinyl chloride-based polymer; and preparing a vinyl chloride-based polymer composite including the vinyl chloride-based polymer and polyvinylpyrrolidone.
摘要:
The present invention relates to a vinyl chloride-based polymer which has improved thermal stability and a method for preparing the same. The vinyl chloride-based polymer includes silicate compound derived units, and a dehydrochloric acid (dehydrochlorination) reaction due to heat or ultraviolet rays may be suppressed, and thus, thermal stability may be improved, and discoloration and deformation of physical properties may be prevented. Accordingly, the vinyl chloride-based polymer and the method for preparing the same may be readily applied to industries requiring a vinyl chloride-based polymer, for example, industries related to a vinyl chloride-based resin and molded articles thereof.
摘要:
The present invention relates to a method of preparing a vinyl chloride polymer having good thermal stability by restraining a dehydrochlorination reaction due to heat or ultraviolet rays, and a vinyl chloride polymer prepared thereby. According to the preparation method, the adding point of a modifier is controlled, and a vinyl chloride polymer markedly restraining the generation of dehydrochloric acid due to heat or ultraviolet rays may be prepared. Therefore, the preparation method of the vinyl chloride polymer via the emulsion polymerization and the vinyl chloride polymer prepared thereby in the present invention may be readily applied to industries requiring the vinyl chloride polymer such as industries concerning a vinyl chloride resin and a molded article.
摘要:
Provided are a method of preparing a vinyl chloride-based polymer composite, a vinyl chloride-based polymer composite, and a vinyl chloride-based polymer composite composition including the composite, the method including: a first step of performing bulk polymerization of vinyl chloride-based monomers; and a second step of recovering unreacted vinyl chloride-based monomers after the completion of the bulk polymerization and obtaining a vinyl chloride-based polymer composite, wherein polyvinyl alcohol is added in at least one step of the first step and the second step, and the polyvinyl alcohol is added in an amount of 0.003 parts by weight to 0.500 parts by weight based on a total of 100 parts by weight of the vinyl chloride-based monomers.