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公开(公告)号:US20180155507A1
公开(公告)日:2018-06-07
申请号:US14900043
申请日:2015-08-31
申请人: LG CHEM, LTD.
发明人: Min Cheol JU , Min Seung SHIN , Won Seok LEE , Hyung Sub LEE , Seok Goo JANG , Jeong Su CHOI , Sung Won HONG , In Soo KIM , Ho Hoon KIM , Sang Hoo PARK , Keun Hoon YOO , Roo Da LEE
IPC分类号: C08J3/16 , C08F279/02 , B01J19/18
CPC分类号: C08J3/16 , B01J19/1812 , C08C1/15 , C08F6/18 , C08F6/22 , C08F279/02 , C08F279/06 , C08J2309/10 , C08J2351/04 , C08L9/10 , C08L51/04 , C08F220/44
摘要: Disclosed are a method of preparing a resin powder and an integrated reactor for the same. When a coagulation process is performed using an acidic coagulant in the integrated coagulator for latex coagulation and aging according to the present invention, a remaining acidic coagulant is also removed from a reactor through neutralization, and thus, a resin powder having enhanced moist-heat resistance and thermal stability may be prepared.
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公开(公告)号:US20220204666A1
公开(公告)日:2022-06-30
申请号:US17606710
申请日:2020-10-27
申请人: LG CHEM, LTD.
发明人: Min Cheol JU , Min Seung SHIN , Sung Won HONG , In Soo KIM , Hyung Sub LEE
IPC分类号: C08F212/12
摘要: The present invention relates to a method for producing a copolymer, the method for producing a copolymer including: step (S10) for adding aromatic vinyl-based monomers substituted with alkyl groups and vinyl cyan-based monomers to perform polymerization in the presence of a polymerization initiator, wherein the vinyl cyan-based monomers are collectively added before initiation of the polymerization in step (S10), monomer droplets are continuously divisionally added during the polymerization in step (S10), and the monomer droplets contain part or all of the aromatic vinyl-based monomers substituted with alkyl groups, and relates to a copolymer produced therefrom, and a thermoplastic resin composition including the same.
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公开(公告)号:US20210403621A1
公开(公告)日:2021-12-30
申请号:US16469546
申请日:2018-12-19
申请人: LG CHEM, LTD.
发明人: In Soo KIM , Min Cheol JU , Min Seung SHIN , Sung Won HONG , Hyung Sub LEE
IPC分类号: C08F212/10
摘要: Provided is a method of preparing a copolymer which includes 1) initiating polymerization by batch-adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer to a reactor; and 2) performing polymerization by continuously adding an aromatic vinyl-based monomer to the reactor at a predetermined rate after the initiation of polymerization, wherein the continuous addition of the aromatic vinyl-based monomer is initiated when a polymerization conversion rate is 10% or less and terminated when a polymerization conversion rate is between 80 and 90%, and step 2) includes a first temperature phase and a second temperature phase, each of which maintains a constant temperature, wherein a temperature of the second temperature phase is higher than that of the first temperature phase, and thereby a copolymer with a small standard deviation for a vinyl cyan-based unit composition and excellent transparency may be prepared.
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公开(公告)号:US20240150504A1
公开(公告)日:2024-05-09
申请号:US18280845
申请日:2023-01-17
申请人: LG CHEM, LTD.
发明人: Sung Won HONG , Hyung Sub LEE , Dae Woo LEE , Woo Ri KIM , Min Cheol JU , Min Seung SHIN , In Soo KIM
IPC分类号: C08F212/10 , C08F2/18
CPC分类号: C08F212/10 , C08F2/18
摘要: The present disclosure relates to a method of preparing a polymer, which includes: adding an alkyl-substituted aromatic vinyl-based monomer and a vinyl cyanide-based monomer to a reactor and initiating polymerization; and performing polymerization while continuously adding an alkyl-substituted aromatic vinyl-based monomer and a multifunctional initiator to the reactor, wherein the continuous addition of the alkyl-substituted aromatic vinyl-based monomer and the multifunctional initiator is initiated when a polymerization conversion rate is 10 to 30%, and the continuous addition of the alkyl-substituted aromatic vinyl-based monomer and the multifunctional initiator is terminated when a polymerization conversion rate is 70 to 80%.
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公开(公告)号:US20230039916A1
公开(公告)日:2023-02-09
申请号:US17783184
申请日:2021-10-18
申请人: LG CHEM, LTD.
发明人: In Soo KIM , Hyung Sub LEE , Dae Woo LEE , Min Cheol JU , Min Seung SHIN , Sung Won HONG
IPC分类号: C08F2/18 , C08F212/08 , C08F220/44 , C08F222/40
摘要: Provided is a polymer production method including: batch-adding a reaction solution including a monomer mixture including a maleimide-based monomer, a vinyl aromatic monomer, and a vinyl cyanide-based monomer and an aqueous solvent to a reactor and initiating polymerization; and carrying out the polymerization while continuously adding the maleimide-based monomer and the aqueous solvent to the reactor, wherein the reaction solution satisfies the above Formula 1.
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公开(公告)号:US20230144513A1
公开(公告)日:2023-05-11
申请号:US17919565
申请日:2021-11-18
申请人: LG CHEM, LTD.
发明人: Min Seung SHIN , Hyung Sub LEE , Dae Woo LEE , Min Cheol JU , Sung Won HONG , In Soo KIM
IPC分类号: C08F212/10 , C08L25/12
CPC分类号: C08F212/10 , C08L25/12
摘要: The present disclosure relates to a method for preparing a copolymer, a copolymer prepared therefrom, and a thermoplastic resin composition including the copolymer. The method includes introducing and polymerizing an aromatic vinyl-based monomer, a vinyl cyan-based monomer, and an imide-based monomer, wherein the imide-based monomer is introduced at once in an amount of 1 wt % to 24 wt % before the start of polymerization, and is continuously introduced in an amount of 76 wt % to 99 wt % from the start of the polymerization.
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公开(公告)号:US20220275127A1
公开(公告)日:2022-09-01
申请号:US17624561
申请日:2020-11-25
申请人: LG CHEM, LTD.
发明人: Min Seung SHIN , Min Cheol JU , Sung Won HONG , In Soo KIM , Hyung Sub LEE
IPC分类号: C08F222/40 , C08F212/08 , C08F220/44 , C08F2/18
摘要: Provided is a method of preparing a maleimide-based copolymer, which comprises adding a monomer mixture including an aromatic vinyl-based monomer and a maleimide-based monomer to an aqueous solution consisting of an aqueous solvent and a first vinyl cyanide-based monomer and performing polymerization.
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公开(公告)号:US20220235158A1
公开(公告)日:2022-07-28
申请号:US17607295
申请日:2020-10-27
申请人: LG CHEM, LTD.
发明人: Min Cheol JU , Min Seung SHIN , Sung Won HONG , In Soo KIM , Hyung Sub LEE
IPC分类号: C08F212/10
摘要: The present invention relates to a method for producing a copolymer, a copolymer produced therefrom, and a thermoplastic resin composition including the same, the method including step (S10) for adding aromatic vinyl-based monomers and vinyl cyan-based monomers to perform polymerization in the presence of polymerization initiators, wherein the polymerization initiators includes at least two different kinds of polymerization initiators, and part or all of the aromatic vinyl-based monomers are continuously divisionally added during the polymerization in step (S10).
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公开(公告)号:US20190085106A1
公开(公告)日:2019-03-21
申请号:US15528492
申请日:2016-09-08
申请人: LG CHEM, LTD.
发明人: Sung Won HONG , Hyung Sub LEE , Min Cheol JU , Min Seung SHIN , In Soo KIM
IPC分类号: C08F212/12 , C08J3/07 , C08K3/34 , C08L25/16
CPC分类号: C08F212/12 , C08F6/22 , C08F2800/10 , C08J3/07 , C08K3/10 , C08K3/34 , C08K2003/162 , C08K2003/3045 , C08K2003/343 , C08L25/16 , C08L25/12 , C08F220/44 , C08F212/08 , C08L55/02
摘要: The present invention relates to a method of preparing a thermoplastic resin. More particularly, the present invention relates to a method of preparing a thermoplastic resin, the method including a coagulation step of adding a water-soluble silicate compound and a metal salt coagulant to an α-methylstyrene-vinyl cyan compound copolymer latex, followed by coagulation. In accordance with the present invention, a method of preparing a thermoplastic resin having superior heat resistance by adding an additive during coagulation and aging of α-methylstyrene-vinyl cyan compound copolymer latex while controlling an addition time point of the additive is provided.
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公开(公告)号:US20230020924A1
公开(公告)日:2023-01-19
申请号:US17783682
申请日:2021-11-25
申请人: LG CHEM, LTD.
发明人: Sung Won HONG , Hyung Sub LEE , Dae Woo LEE , Min Cheol JU , Seong Jae SHIN , Min Seung SHIN , In Soo KIM
IPC分类号: C08F212/12 , C08F212/10 , C08F2/18 , C08F212/08 , C08F220/44
摘要: The present invention relates to a method of preparing a polymer, which includes: adding a first reaction solution including an aqueous solvent and a monomer mixture including an alkyl-substituted aromatic vinyl-based monomer, an alkyl-unsubstituted aromatic vinyl-based monomer, and a vinyl cyanide-based monomer to a reactor and initiating polymerization; and performing polymerization by continuously adding an alkyl-substituted aromatic vinyl-based monomer to the reactor, wherein the first reaction solution satisfies Expression 1 (see the description of the invention).
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