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公开(公告)号:US20240006645A1
公开(公告)日:2024-01-04
申请号:US18468035
申请日:2023-09-15
IPC分类号: H01M8/18 , C07D209/04 , C07D209/46 , C07D221/00 , C07D279/12 , C07F1/00 , C07F3/00 , H01M4/36 , H01M4/60
CPC分类号: H01M8/188 , C07D209/04 , C07D209/46 , C07D221/00 , C07D279/12 , C07F1/005 , C07F3/003 , H01M4/368 , H01M4/60
摘要: Flow batteries can include a first half-cell containing a first aqueous electrolyte solution. a second half-cell containing a second aqueous electrolyte solution, and a separator disposed between the first half-cell and the second half-cell, The first aqueous electrolyte solution contains a first redox-active material, and the second aqueous electrolyte solution contains a second redox-active material. At least one of the first redox-active material and the second redox-active material is a nitroxide compound or a salt thereof. Particular nitroxide compounds can include a doubly bonded oxygen contained in a ring bearing the nitroxide group, a doubly bonded oxygen appended to a ring bearing the nitroxide group, sulfate or phosphate groups appended to a ring bearing the nitroxide group, various heterocyclic rings bearing the nitroxide group, or acyclic nitroxide compounds.
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公开(公告)号:US11799117B2
公开(公告)日:2023-10-24
申请号:US17177845
申请日:2021-02-17
IPC分类号: H01M8/10 , H01M8/18 , C07D209/04 , C07D209/46 , C07D221/00 , C07D279/12 , C07F1/00 , C07F3/00 , H01M4/36 , H01M4/60
CPC分类号: H01M8/188 , C07D209/04 , C07D209/46 , C07D221/00 , C07D279/12 , C07F1/005 , C07F3/003 , H01M4/368 , H01M4/60
摘要: Flow batteries can include a first half-cell containing a first aqueous electrolyte solution. a second half-cell containing a second aqueous electrolyte solution, and a separator disposed between the first half-cell and the second half-cell. The first aqueous electrolyte solution contains a first redox-active material, and the second aqueous electrolyte solution contains a second redox-active material. At least one of the first redox-active material and the second redox-active material is a nitroxide compound or a salt thereof. Particular nitroxide compounds can include a doubly bonded oxygen contained in a ring bearing the nitroxide group, a doubly bonded oxygen appended to a ring bearing the nitroxide group, sulfate or phosphate groups appended to a ring bearing the nitroxide group, various heterocyclic rings bearing the nitroxide group, or acyclic nitroxide compounds.
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公开(公告)号:US20210135246A1
公开(公告)日:2021-05-06
申请号:US17147585
申请日:2021-01-13
IPC分类号: H01M4/90 , C07F7/28 , H01M8/04276 , H01M8/18 , H01M8/20
摘要: Electrolyte solutions for flow batteries and other electrochemical systems can contain an active material that is capable of transferring one or more electrons per molecule during an oxidation-reduction cycle. Doubly bridged aromatic groups or their coordination compounds can be particularly suitable active materials. Flow batteries can include a first half-cell containing a first electrolyte solution, and a second half-cell containing a second electrolyte solution, in which at least one of the first electrolyte solution and the second electrolyte solution contains an active material having at least two aromatic groups doubly bridged by a carbonyl moiety and a bridging moiety containing a bridging atom selected from carbon, nitrogen, oxygen, sulfur, selenium and tellurium. Such bridged compounds can directly function as the active material, or coordination compounds containing the bridged compounds as at least one ligand can serve as the active material.
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公开(公告)号:US10964966B2
公开(公告)日:2021-03-30
申请号:US16469766
申请日:2017-12-15
IPC分类号: H01M4/36 , H01M8/18 , C07D209/04 , C07D209/46 , C07D221/00 , C07D279/12 , C07F1/00 , C07F3/00 , H01M4/60
摘要: Flow batteries can include a first half-cell containing a first aqueous electrolyte solution, a second half-cell containing a second aqueous electrolyte solution, and a separator disposed between the first half-cell and the second half-cell. The first aqueous electrolyte solution contains a first redox-active material, and the second aqueous electrolyte solution contains a second redox-active material. At least one of the first redox-active material and the second redox-active material is a nitroxide compound or a salt thereof. Particular nitroxide compounds can include a doubly bonded oxygen contained in a ring bearing the nitroxide group, a doubly bonded oxygen appended to a ring bearing the nitroxide group, sulfate or phosphate groups appended to a ring bearing the nitroxide group, various heterocyclic rings bearing the nitroxide group, or acyclic nitroxide compounds.
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公开(公告)号:US10930937B2
公开(公告)日:2021-02-23
申请号:US15360918
申请日:2016-11-23
IPC分类号: H01M8/04276 , H01M4/90 , C07F7/28 , H01M8/18 , H01M8/20
摘要: Electrolyte solutions for flow batteries and other electrochemical systems can contain an active material that is capable of transferring one or more electrons per molecule during an oxidation-reduction cycle. Doubly bridged aromatic groups or their coordination compounds can be particularly suitable active materials. Flow batteries can include a first half-cell containing a first electrolyte solution, and a second half-cell containing a second electrolyte solution, in which at least one of the first electrolyte solution and the second electrolyte solution contains an active material having at least two aromatic groups doubly bridged by a carbonyl moiety and a bridging moiety containing a bridging atom selected from carbon, nitrogen, oxygen, sulfur, selenium and tellurium. Such bridged compounds can directly function as the active material, or coordination compounds containing the bridged compounds as at least one ligand can serve as the active material.
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公开(公告)号:US12074353B2
公开(公告)日:2024-08-27
申请号:US17270623
申请日:2019-10-23
发明人: Zachariah M. Norman , Alexander B. Papandrew , Steven Y. Reece , Rachel Christine Klet , Matthew Millard
IPC分类号: H01M8/06 , H01M4/86 , H01M4/90 , H01M8/08 , H01M8/18 , H01M50/414 , H01M50/497
CPC分类号: H01M8/0693 , H01M4/8605 , H01M4/9016 , H01M4/9041 , H01M8/08 , H01M8/188 , H01M50/414 , H01M50/497 , H01M4/8657 , H01M2300/0002
摘要: The present disclosure provides methods and devices for preparing electrolyte solutions containing unwanted impurities at the pg/L levels. The methods generally comprise electrochemically reducing the impurity to a precipitated, plated, or volatilized form, and removing that reduced form from electrolyte solution. This disclosure describes the methods and devices for effecting such methods, and the electrochemical solutions derived or derivable from such methods.
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公开(公告)号:US12062795B2
公开(公告)日:2024-08-13
申请号:US17147585
申请日:2021-01-13
IPC分类号: H01M4/90 , C07F7/28 , H01M8/04276 , H01M8/18 , H01M8/20
CPC分类号: H01M4/9008 , C07F7/28 , H01M8/04276 , H01M8/188 , H01M8/20 , Y02E60/50
摘要: Electrolyte solutions for flow batteries and other electrochemical systems can contain an active material that is capable of transferring one or more electrons per molecule during an oxidation-reduction cycle. Doubly bridged aromatic groups or their coordination compounds can be particularly suitable active materials. Flow batteries can include a first half-cell containing a first electrolyte solution, and a second half-cell containing a second electrolyte solution, in which at least one of the first electrolyte solution and the second electrolyte solution contains an active material having at least two aromatic groups doubly bridged by a carbonyl moiety and a bridging moiety containing a bridging atom selected from carbon, nitrogen, oxygen, sulfur, selenium and tellurium. Such bridged compounds can directly function as the active material, or coordination compounds containing the bridged compounds as at least one ligand can serve as the active material.
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公开(公告)号:US20210194032A1
公开(公告)日:2021-06-24
申请号:US17177845
申请日:2021-02-17
IPC分类号: H01M8/18 , C07D209/04 , C07D209/46 , C07D221/00 , C07D279/12 , C07F1/00 , C07F3/00 , H01M4/36 , H01M4/60
摘要: Flow batteries can include a first half-cell containing a first aqueous electrolyte solution, a second half-cell containing a second aqueous electrolyte solution, and a separator disposed between the first half-cell and the second half-cell, The first aqueous electrolyte solution contains a first redox-active material, and the second aqueous electrolyte solution contains a second redox-active material. At least one of the first redox-active material and the second redox-active material is a nitroxide compound or a salt thereof. Particular nitroxide compounds can include a doubly bonded oxygen contained in a ring bearing the nitroxide group, a doubly bonded oxygen appended to a ring bearing the nitroxide group, sulfate or phosphate groups appended to a ring bearing the nitroxide group, various heterocyclic rings bearing the nitroxide group, or acyclic nitroxide compounds.
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