公开(公告)号：US5866502A

公开(公告)日：1999-02-02

申请号：US835042

申请日：1997-03-27

申请人： Larry Michael Cirjak ,  Marc Anthony Pepera

发明人： Larry Michael Cirjak ,  Marc Anthony Pepera

IPC分类号： B01J37/04 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/34 ,  B01J23/84 ,  B01J23/847 ,  B01J23/889 ,  B01J27/02 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/03 ,  C07C255/08 ,  B01J23/20

CPC分类号： B01J23/22 ,  B01J23/18 ,  B01J23/8472

摘要： A method of preparing a V.sub.a Sb.sub.b M.sub.m N.sub.n O.sub.x catalyst useful in the ammoxidation of a C.sub.2 -C.sub.5 hydrocarbon to its corresponding .alpha., .beta. unsaturated nitrile comprising heating an aqueous mixture comprising V.sub.2 O.sub.5 and Sb.sub.2 O.sub.3 at a temperature above about 100.degree. to 250.degree. C., preferably 110.degree. to 175.degree. C., most preferably 120.degree. to 160.degree. C., under autogenous pressure with agitation to form a catalyst precursor, drying the catalyst precursor and calcining the catalyst precursor to form the finished catalyst.

摘要翻译： 制备可用于将C2-C5烃氨氧化成其相应的α，β不饱和腈的VaSbbMmNnOx催化剂的方法，包括在高于约100℃至250℃，优选110℃的温度下加热包含V 2 O 5和Sb 2 O 3的含水混合物 至175℃，最优选120℃至160℃，在自生压力下搅拌以形成催化剂前体，干燥催化剂前体并煅烧催化剂前体以形成最终催化剂。

公开(公告)号：US06399813B1

公开(公告)日：2002-06-04

申请号：US09929256

申请日：2001-08-14

申请人： Patricia Rae Blum ,  Larry Michael Cirjak ,  Marc Anthony Pepera ,  Christos Paparizos ,  George Frederick Salem ,  Michael James Baker

发明人： Patricia Rae Blum ,  Larry Michael Cirjak ,  Marc Anthony Pepera ,  Christos Paparizos ,  George Frederick Salem ,  Michael James Baker

IPC分类号： C07C67055

CPC分类号： B01J37/0045 ,  B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a metal salt of Pd and M, wherein M comprises Ba, Cd, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 105 microns.

公开(公告)号：US06395676B2

公开(公告)日：2002-05-28

申请号：US09343832

申请日：1999-06-30

申请人： Patricia Rae Blum ,  Larry Michael Cirjak ,  Marc Anthony Pepera ,  Christos Paparizos ,  George Frederick Salem ,  Michael James Baker

发明人： Patricia Rae Blum ,  Larry Michael Cirjak ,  Marc Anthony Pepera ,  Christos Paparizos ,  George Frederick Salem ,  Michael James Baker

IPC分类号： B01J2304

CPC分类号： B01J37/0045 ,  B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a metal salt of Pd and M, wherein M comprises Ba, Cd, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 105 microns.