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公开(公告)号:US07901555B2
公开(公告)日:2011-03-08
申请号:US10585263
申请日:2004-12-22
申请人: Li Jiang , Timothy Gareth John Jones , Richard Compton , Nathan Lawrence , Gregory George Wildgoose , Malingappagari Pandurangappa , Oliver Clinton Mullins , Andrew Meredith
发明人: Li Jiang , Timothy Gareth John Jones , Richard Compton , Nathan Lawrence , Gregory George Wildgoose , Malingappagari Pandurangappa , Oliver Clinton Mullins , Andrew Meredith
IPC分类号: G01N27/333 , E21B47/00 , E21B49/00
CPC分类号: G01N27/308 , E21B47/10 , G01N27/302 , G01N27/3335
摘要: An electro-chemical sensor is described having two molecular redox systems sensitive to the same species and having an detector to detect relative shifts in the voltammograms of the two redox systems.
摘要翻译: 描述了一种电化学传感器,其具有对相同物质敏感的两个分子氧化还原系统,并且具有检测器以检测两个氧化还原体系的伏安图的相对位移。
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公开(公告)号:US20080023328A1
公开(公告)日:2008-01-31
申请号:US11781546
申请日:2007-07-23
申请人: Li Jiang , Timothy Jones , Richard Compton , Nathan Lawrence , Gregory Wildgoose , Malingappagari Pandurangappa , Oliver Mullins , Andrew Meredith , Markus Pagels
发明人: Li Jiang , Timothy Jones , Richard Compton , Nathan Lawrence , Gregory Wildgoose , Malingappagari Pandurangappa , Oliver Mullins , Andrew Meredith , Markus Pagels
IPC分类号: G01N27/27
CPC分类号: G01N27/308 , E21B47/10 , G01N27/302 , G01N27/3335
摘要: An electro-chemical sensor is described having one or more redox species sensitive to a certain analyte and one or more redox species that are insensitive to that analyte, for the purpose of making measurements in a downhole environment in aquifers or oilfield reservoirs.
摘要翻译: 描述了一种电化学传感器,其具有对特定分析物敏感的一种或多种氧化还原物质和对该分析物不敏感的一种或多种氧化还原物质,用于在含水层或油田储层中的井下环境中进行测量。
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公开(公告)号:US20070272552A1
公开(公告)日:2007-11-29
申请号:US10585263
申请日:2004-12-22
申请人: Li Jiang , Timothy Jones , Richard Compton , Nathan Lawrence , Gregory Wildgoose , Malingappagari Pandurangappa , Oliver Mullins , Andrew Meredith
发明人: Li Jiang , Timothy Jones , Richard Compton , Nathan Lawrence , Gregory Wildgoose , Malingappagari Pandurangappa , Oliver Mullins , Andrew Meredith
IPC分类号: G01N27/416 , G01N33/28
CPC分类号: G01N27/308 , E21B47/10 , G01N27/302 , G01N27/3335
摘要: An electro-chemical sensor is described having two molecular redox systems sensitive to the same species and having an detector to detect relative shifts in the voltammograms of the two redox systems.
摘要翻译: 描述了一种电化学传感器,其具有对相同物质敏感的两个分子氧化还原系统,并且具有检测器以检测两个氧化还原体系的伏安图的相对位移。
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4.
公开(公告)号:US20100255587A1
公开(公告)日:2010-10-07
申请号:US12820363
申请日:2010-06-22
申请人: Li Jiang , Timothy Gareth John Jones , Andrew Meredith , Markus Pagels , Amilra Prasanna De Silva
发明人: Li Jiang , Timothy Gareth John Jones , Andrew Meredith , Markus Pagels , Amilra Prasanna De Silva
IPC分类号: G01N27/00
CPC分类号: E21B47/10 , G01N17/008 , G01N33/1853 , Y10T436/21 , Y10T436/25 , Y10T436/25375 , Y10T436/255
摘要: This invention relates to methods and apparatus for determination of ion concentrations, particularly in downhole water from hydrocarbon wells, aquifers etc. It is useful in a wide range of applications, including predicting the formation of scale and fingerprinting waters from different sources. More particularly, the invention relates to the use of ligands whose electronic configuration is altered by the binding of the scaling ions within a water sample. These alterations are detected electrochemically by applying varying potential to electrodes and measuring current flow as potential is varied, from which is derived the concentration of scaling ions in the fluid.
摘要翻译: 本发明涉及用于测定离子浓度的方法和装置,特别是在来自烃井,含水层等的井下水中。它在广泛的应用中是有用的,包括预测来自不同来源的水垢和指纹图谱的形成。 更具体地,本发明涉及配体的用途,其配体通过水样中的结垢离子而改变。 通过对电极施加变化的电位并且随着电位变化来测量电流而电化学地检测这些变化,从而导出流体中结垢离子的浓度。
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5.
公开(公告)号:US09034651B2
公开(公告)日:2015-05-19
申请号:US12820363
申请日:2010-06-22
申请人: Li Jiang , Timothy Gareth John Jones , Andrew Meredith , Markus Pagels , Amilra Prasanna De Silva
发明人: Li Jiang , Timothy Gareth John Jones , Andrew Meredith , Markus Pagels , Amilra Prasanna De Silva
CPC分类号: E21B47/10 , G01N17/008 , G01N33/1853 , Y10T436/21 , Y10T436/25 , Y10T436/25375 , Y10T436/255
摘要: This invention relates to methods and apparatus for determination of ion concentrations, particularly in downhole water from hydrocarbon wells, aquifers etc. It is useful in a wide range of applications, including predicting the formation of scale and fingerprinting waters from different sources. More particularly, the invention relates to the use of ligands whose electronic configuration is altered by the binding of the scaling ions within a water sample. These alterations are detected electrochemically by applying varying potential to electrodes and measuring current flow as potential is varied, from which is derived the concentration of scaling ions in the fluid.
摘要翻译: 本发明涉及用于测定离子浓度的方法和装置,特别是在来自烃井,含水层等的井下水中。它在广泛的应用中是有用的,包括预测来自不同来源的水垢和指纹图谱的形成。 更具体地,本发明涉及配体的用途,其配体通过水样中的结垢离子而改变。 通过对电极施加变化的电位并且随着电位变化来测量电流而电化学地检测这些变化,从而导出流体中结垢离子的浓度。
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6.
公开(公告)号:US07767461B2
公开(公告)日:2010-08-03
申请号:US10564939
申请日:2004-07-12
申请人: Li Jiang , Timothy Gareth John Jones , Andrew Meredith , Markus Pagels , Amilra Prasanna De Silva
发明人: Li Jiang , Timothy Gareth John Jones , Andrew Meredith , Markus Pagels , Amilra Prasanna De Silva
IPC分类号: G01N33/20
CPC分类号: E21B47/10 , G01N17/008 , G01N33/1853 , Y10T436/21 , Y10T436/25 , Y10T436/25375 , Y10T436/255
摘要: This invention relates to methods and apparatus for determination of ion concentrations, particularly in downhole water from hydrocarbon wells, aquifers etc. It is useful in a wide range of applications, including predicting the formation of scale and fingerprinting waters from different sources. More particularly, the invention relates to the use of ligands whose electronic configuration is altered by the binding of the scaling ions within a water sample. These alterations are detected, for example by electrochemical means, and are indicative of the concentration of scaling ions in the sample.
摘要翻译: 本发明涉及用于测定离子浓度的方法和装置,特别是在来自烃井,含水层等的井下水中。它在广泛的应用中是有用的,包括预测来自不同来源的水垢和指纹图谱的形成。 更具体地,本发明涉及配体的用途,其配体通过水样中的结垢离子而改变。 这些改变例如通过电化学方法检测,并且指示样品中结垢离子的浓度。
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公开(公告)号:US20120064632A1
公开(公告)日:2012-03-15
申请号:US13062788
申请日:2009-08-26
申请人: Kay Robinson , Nathan Lawrence , Andrew Meredith
发明人: Kay Robinson , Nathan Lawrence , Andrew Meredith
CPC分类号: G01N33/24
摘要: The present invention provides an electrochemical sensor having a solid electrically conductive substrate and a compound immobilized thereon which has binding affinity for an analyte species to be detected and also displays electrochemical behaviour which is modified upon binding of that analyte species, so that binding of an analyte species can be detected by measuring electrochemical properties, such as by voltammetry. Desirably the immobilised compound contains both a first moiety with binding affinity for the analyte and a separate second moiety which is a redox system whose electrochemical oxidation/reduction properties become modified when the first moiety binds the analyte. The analyte binding moiety may be a diol or polyol and preferably is a sugar. The electrochemical sensor finds use in methods of analysing reservoir and process fluids, particularly at a subterranean location. The electrochemical sensor may be a component of a downhole tool, adapted for deployment downhole.
摘要翻译: 本发明提供一种电化学传感器,其具有固体导电基质和固定在其上的化合物,其对待检测的分析物种具有结合亲和力,并且还显示在该分析物种结合时修饰的电化学行为,使得分析物 可以通过测量电化学性质例如通过伏安法来检测物种。 理想地,固定化的化合物含有对分析物具有结合亲和力的第一部分和分开的第二部分,其是当第一部分结合分析物时其电化学氧化/还原性质变得改变的氧化还原体系。 分析物结合部分可以是二醇或多元醇,优选是糖。 电化学传感器用于分析储层和工艺流体的方法,特别是在地下位置。 电化学传感器可以是井下工具的组件,适用于井下部署。
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公开(公告)号:US07710000B2
公开(公告)日:2010-05-04
申请号:US11499332
申请日:2006-08-04
申请人: Clive E. Hall , Li Jiang , Timothy G. J. Jones , Andrew Meredith , Nathan S. Lawrence , Markus Pagels
发明人: Clive E. Hall , Li Jiang , Timothy G. J. Jones , Andrew Meredith , Nathan S. Lawrence , Markus Pagels
IPC分类号: H01L41/083 , H01L41/047
CPC分类号: G01N27/308 , G01N27/26 , G01N27/38
摘要: The present invention, in one set of embodiments, provides methods and systems for integrating conducting diamond electrodes into a high power acoustic resonator. More specifically, but not by way of limitation, in certain embodiments of the present invention, diamond electrodes may be integrated into a high power acoustic resonator to provide a robust sensing device that may provide for acoustic cleaning of the electrodes and increasing the rate of mass transport to the diamond electrodes. The diamond electrodes may be used as working, reference or counter electrodes or a combination of two or more of such electrodes. In certain aspects, the high power acoustic resonator may include an acoustic horn for focusing acoustic energy and the diamond electrodes may be coupled with the acoustic horn.
摘要翻译: 本发明在一组实施例中提供了用于将导电金刚石电极集成到高功率声谐振器中的方法和系统。 更具体地但不是限制,在本发明的某些实施例中,金刚石电极可以被集成到高功率声谐振器中,以提供鲁棒的感测装置,其可以提供电极的声学清洁并且提高质量 运输到金刚石电极。 金刚石电极可以用作工作电极,参考电极或对电极,或两个或多个这样的电极的组合。 在某些方面,高功率声谐振器可以包括用于聚焦声能的声喇叭,并且金刚石电极可以与声喇叭耦合。
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9.
公开(公告)号:US20070065337A1
公开(公告)日:2007-03-22
申请号:US10564939
申请日:2004-07-12
申请人: Li Jiang , Timothy Jones , Andrew Meredith , Markus Pagels , Amilra De Silva
发明人: Li Jiang , Timothy Jones , Andrew Meredith , Markus Pagels , Amilra De Silva
IPC分类号: G01N17/00
CPC分类号: E21B47/10 , G01N17/008 , G01N33/1853 , Y10T436/21 , Y10T436/25 , Y10T436/25375 , Y10T436/255
摘要: This invention relates to methods and apparatus for determination of ion concentrations, particularly in downhole water from hydrocarbon wells, aquifers etc. It is useful in a wide range of applications, including predicting the formation of scale and fingerprinting waters from different sources. More particularly, the invention relates to the use of ligands whose electronic configuration is altered by the binding of the scaling ions within a water sample. These alterations are detected, for example by electrochemical means, and are indicative of the concentration of scaling ions in the sample.
摘要翻译: 本发明涉及用于测定离子浓度的方法和装置,特别是在来自烃井,含水层等的井下水中。它在广泛的应用中是有用的,包括预测来自不同来源的水垢和指纹图谱的形成。 更具体地,本发明涉及配体的用途,其配体通过水样中的结垢离子而改变。 这些改变例如通过电化学方法检测,并且指示样品中结垢离子的浓度。
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公开(公告)号:US08596354B2
公开(公告)日:2013-12-03
申请号:US12753229
申请日:2010-04-02
IPC分类号: E21B47/00
CPC分类号: E21B47/1015
摘要: In an arrangement for monitoring of flow within a hydrocarbon well or reservoir by means of one or more tracers which are placed at subterranean locations such that they may be present in flow produced from the well, the analysis of the flow produced from the well is carried out using an electrochemical method, preferably voltammetry, to detect tracer chosen to undergo a detectable electrochemical reaction. The tracer may be provided as nanoparticles in the well fluid.
摘要翻译: 在用于通过放置在地下位置的一个或多个示踪剂来监测烃井或储层内的流动的装置,使得它们可以以从井产生的流动存在,从井中产生的流动的分析被携带 使用电化学方法(优选伏安法)检测被选择进行可检测的电化学反应的示踪剂。 示踪剂可以作为阱流体中的纳米颗粒提供。
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