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1.发明授权Oxychlorination of hydrocarbons in the presence of non-halide copper containing catalysts 失效在不含卤化物铜的催化剂存在下，烃的氧氯化
公开(公告)号：US4046821A
公开(公告)日：1977-09-06
申请号：US576589
申请日：1975-05-12
IPC分类号： B01J23/76 , C07C17/152 , C07C17/15
CPC分类号： C07C17/152 , B01J23/76
摘要： Copper chloride has been employed as a reagent for oxychlorination of hydrocarbons. It has now been found that a non-halide copper compound in combination with a rare earth compound is an excellent oxychlorination catalyst, e.g. a CuCO.sub.3 - CeO.sub.2 catalyst calcined at 900.degree. C. for 1 hour converted 99 mole % of ethylene fed at a selectivity of 100% to chlorinated products, principally vinyl chloride, ethyl chloride and dichloroethane.
摘要翻译： 已经使用氯化铜作为烃的氧氯化试剂。 现在已经发现，非卤化物铜化合物与稀土化合物的组合是优异的氧氯化催化剂，例如， 在900℃下煅烧1小时的CuCO3-CeO2催化剂，将99摩尔％的以100％选择性进料的乙烯转化成氯化产物，主要是氯乙烯，氯乙烷和二氯乙烷。
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2.发明授权Oxychlorination of hydrocarbons in the presence of non-halide copper containing catalysts 失效在不含卤化物铜的催化剂存在下，烃的氧氯化
公开(公告)号：US4025461A
公开(公告)日：1977-05-24
申请号：US576590
申请日：1975-05-12
CPC分类号： B01J23/76
摘要： Copperchloride has been employed as a reagent for oxychlorination of hydrocarbons. It has now been found that a non-halide copper compound in combination with a rare earth compound is an excellent oxychlorination catalyst, e.g. a CuCO.sub.3 -- CeO.sub.2 catalyst calcined at 900.degree. C. for 1 hour converted 99 mole % of ethylene fed at a selectivity of 100% to chlorinated products, principally vinyl chloride, ethyl chloride and dichloroethane.
摘要翻译： 已经使用氯化铜作为烃的氧氯化试剂。 现在已经发现，非卤化物铜化合物与稀土化合物的组合是优异的氧氯化催化剂，例如， 在900℃下煅烧1小时的CuCO3-CeO2催化剂，将99摩尔％的以100％选择性进料的乙烯转化成氯化产物，主要是氯乙烯，氯乙烷和二氯乙烷。
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