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    Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
    4.
    发明授权
    Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins 有权
    催化剂活化剂，其制备方法及其在催化剂和烯烃聚合中的应用

    公开(公告)号：US07928172B2

    公开(公告)日：2011-04-19

    申请号：US12519254

    申请日：2007-12-04

    申请人： Lubin Luo ,  Katherine Wu ,  Steven P. Diefenbach

    发明人： Lubin Luo ,  Katherine Wu ,  Steven P. Diefenbach

    IPC分类号： C08F4/64 ,  C08F4/6592 ,  B01J31/14

    CPC分类号： C08F10/00 ,  C08F4/65925 ,  C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F210/14

    摘要： Compositions useful for activating catalysts for olefin polymerization are-provided. The compositions are derived from at least: a) compound derived from at least (i) carrier having at least one pair of hydrogen bonded hydroxyl groups, (ii) organoaluminum compound, and (iii) Lewis base, such that each of a majority of aluminum atoms in the organoaluminum compound forms chemical bonds with at least two oxygen atoms from the at least one pair of hydrogen bonded hydroxyl groups; and b) Bronsted acid, wherein the molar ratio of the Bronsted acid to the organoaluminum compound is less than or equal to about 2:1.

    摘要翻译： 提供用于活化烯烃聚合催化剂的组合物。 所述组合物至少衍生自：a）衍生自至少（i）具有至少一对氢键合羟基的载体的化合物，（ii）有机铝化合物和（iii）路易斯碱，使得大部分 有机铝化合物中的铝原子与至少一对键合氢键的至少两个氧原子形成化学键; 和b）布朗斯台德酸，其中布朗斯台德酸与有机铝化合物的摩尔比小于或等于约2:1。

    Catalyst Activators, Processes for Making Same, and Use Thereof in Catalysts and Polymerization of Olefins
    7.
    发明申请
    Catalyst Activators, Processes for Making Same, and Use Thereof in Catalysts and Polymerization of Olefins 审中-公开
    催化剂活化剂，其制备方法及其在催化剂中的用途和烯烃的聚合

    公开(公告)号：US20080300372A1

    公开(公告)日：2008-12-04

    申请号：US12158975

    申请日：2006-12-20

    申请人： Lubin Luo ,  Steven P. Diefenbach ,  Zhike Wang

    发明人： Lubin Luo ,  Steven P. Diefenbach ,  Zhike Wang

    IPC分类号： C08F4/00 ,  B01J31/02

    CPC分类号： C08F10/00 ,  C08F4/65916 ,  C08F4/65922 ,  C08F4/65912

    摘要： A composition useful for activating catalysts for olefin polymerization is provided. The composition is derived from at least: carrier; organoaluminoxy compound; component having at least one electron withdrawing group and at least one active proton; and Lewis base. Alternatively, the composition is derived from at least: carrier; organoaluminoxy compound; component having at least one electron withdrawing group and at least one active proton; and ionic compound having at least one active proton. Alternatively, the composition is derived from at least: carrier; organoaluminoxy compound; component having at least one electron donating group and at least one active proton; and, optionally, Lewis base. Alternatively, the composition is derived from at least: carrier; organoaluminoxy compound; component having at least one electron withdrawing group and at least one active proton; and component having at least one electron donating group and at least one active proton—and optionally, the composition comprises Lewis base.

    摘要翻译： 提供了可用于活化烯烃聚合催化剂的组合物。 该组合物至少衍生自：载体; 有机铝氧化合物 组分具有至少一个吸电子基团和至少一个活性质子; 和路易斯基地。 或者，组合物至少从载体衍生; 有机铝氧化合物 组分具有至少一个吸电子基团和至少一个活性质子; 和具有至少一个活性质子的离子化合物。 或者，组合物至少从载体衍生; 有机铝氧化合物 具有至少一个给电子基团和至少一个活性质子的组分; 和任选的路易斯碱。 或者，组合物至少从载体衍生; 有机铝氧化合物 组分具有至少一个吸电子基团和至少一个活性质子; 和具有至少一个给电子基团和至少一个活性质子的组分 - 以及任选的组合物包含路易斯碱。

    Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts
    9.
    发明授权
    Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts 有权
    含环戊二烯基的低价早期过渡金属烯烃聚合催化剂

    公开(公告)号：US06670299B1

    公开(公告)日：2003-12-30

    申请号：US09608855

    申请日：2000-06-30

    申请人： Tobin J. Marks ,  Lubin Luo ,  Sung Cheol Yoon

    发明人： Tobin J. Marks ,  Lubin Luo ,  Sung Cheol Yoon

    IPC分类号： C08F464

    CPC分类号： C08F220/14 ,  B01J31/2295 ,  B01J2231/12 ,  B01J2531/46 ,  C08F4/6192 ,  C08F4/65908 ,  C08F4/6592 ,  C08F10/00 ,  C08F12/08 ,  C08F212/08 ,  Y10S526/943

    摘要： A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising {CP* MRR′n}+{A}− wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R is a C1-C20 hydrocarbyl; R′ are independently selected from hydride, C1-C20 hydrocarbyl, SiR″3, NR″2, OR″, SR″, GeR″3, SnR″3, and C═C containing groups (R″═C1-C10 hydrocarbyl); n is an integer selected to balance the oxidation state of M; and A is a suitable non-coordinating anionic cocatalyst or precursor. This catalyst system may form stereoregular olefin polymers including syndiotactic polymers of styrene and methylmethacrylate and isotactic copolymers of polar and nonpolar olefin monomers such as methylmethacrylate and styrene.

    摘要翻译： 通过用包含Cp *是环戊二烯基或取代的环戊二烯基部分的催化剂前体的还原剂进行原位还原来形成可用于聚合和共聚极性和非极性烯烃单体的催化剂体系; M是早期过渡金属; R是C1-C20烃基; R'独立地选自氢化物，C 1 -C 20烃基，SiR''3，NR''2，OR“，SR”，GeR'3，SnR'3和C =含C的基团（R' '= C1-C10烃基）; n是选择以平衡M的氧化态的整数; 而A是合适的非配位阴离子助催化剂或前体。 该催化剂体系可以形成包含苯乙烯和甲基丙烯酸甲酯的间同立构聚合物的立构规环烯烃聚合物，以及极性和非极性烯烃单体如甲基丙烯酸甲酯和苯乙烯的全同立构共聚物。