Polylactide resin having excellent heat resistance and preparation method thereof
    1.
    发明授权
    Polylactide resin having excellent heat resistance and preparation method thereof 有权
    具有优异耐热性的聚丙交酯树脂及其制备方法

    公开(公告)号:US08722845B2

    公开(公告)日:2014-05-13

    申请号:US13704099

    申请日:2011-06-21

    IPC分类号: C08G63/85

    摘要: The present invention relates to a polylactide resin having excellent heat resistance, a preparation method thereof, and a polylactide resin composition including the same.The polylactide resin is characterized by high polymerization activity owing to an organic coordinated metal catalyst even though it has a low catalyst content, and a molecular weight reduction due to thermal decomposition at high temperature and a rate of thermal decomposition including depolymerization are greatly suppressed by a low catalyst content and a low resin acidity, and thus provided is the polylactide resin having superior heat resistance.

    摘要翻译: 本发明涉及耐热性优异的聚丙交酯树脂及其制备方法以及包含其的聚交酯树脂组合物。 聚丙交酯树脂的特征在于由于有机配位金属催化剂而具有高聚合活性,即使其催化剂含量低,并且由于高温下的热分解和包括解聚在内的热分解速率引起的分子量降低被 低催化剂含量和低树脂酸度,因此提供了具有优异耐热性的聚丙交酯树脂。

    NOVEL ORGANOMETALLIC COMPOUND, AND ORGANIC LIGHT-EMITTING DIODE USING SAME
    2.
    发明申请
    NOVEL ORGANOMETALLIC COMPOUND, AND ORGANIC LIGHT-EMITTING DIODE USING SAME 有权
    新型有机化合物和有机发光二极管

    公开(公告)号:US20130334521A1

    公开(公告)日:2013-12-19

    申请号:US14002598

    申请日:2012-04-06

    IPC分类号: H01L51/00

    摘要: The present invention relates to a novel organometallic compound, and more particularly, to a luminescent organometallic compound in which intermolecular interaction is inhibited by means of introducing a germanium substituent, thereby improving light-emitting characteristics. The present invention also relates to an organic electronic device, specifically, to an organic light-emitting diode using the compound. According to the present invention, a germanium substituent is introduced to the parent organometallic iridium compound, thus inhibiting an intermolecular interaction in the solid state and enabling the compound of the present invention to be effectively used in solution processing. When the compound of the present invention is used as part of a light-emitting layer of an organic light-emitting diode, the light-emitting efficiency of the light-emitting diode may be significantly improved. Therefore, the compound of the present invention may be effectively used as a material for an organic light-emitting diode.

    摘要翻译: 本发明涉及新型有机金属化合物,更具体地说,涉及通过引入锗取代基来抑制分子间相互作用的发光有机金属化合物,从而提高发光特性。 本发明还涉及有机电子器件,具体涉及使用该化合物的有机发光二极管。 根据本发明,将锗取代基引入到母体有机金属铱化合物中,从而抑制固态的分子间相互作用,使得本发明的化合物能够有效地用于溶液处理。 当将本发明的化合物用作有机发光二极管的发光层的一部分时,可以显着提高发光二极管的发光效率。 因此,本发明的化合物可以有效地用作有机发光二极管的材料。

    Method for polymerizing cycloolefin polymer containing polar functional groups and electronic devices employing the polymerized cycloolefins
    9.
    发明授权
    Method for polymerizing cycloolefin polymer containing polar functional groups and electronic devices employing the polymerized cycloolefins 有权
    聚合包含极性官能团的环烯烃聚合物的方法和使用聚合环烯烃的电子器件

    公开(公告)号:US07718744B2

    公开(公告)日:2010-05-18

    申请号:US10502185

    申请日:2003-12-03

    摘要: Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising: preparing a catalyst mixture including i) a precatalyst, containing a Group 10 transition metal having a ligand containing oxygen ions bonded to the metal; ii) a first cocatalyst which is an organic compound containing a Group 15 element; and iii) a second cocatalyst which is capable of providing an anion and weakly coordinating to the metal of the precatalyst; and subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, at a temperature of 80-200° C., the total amount of the organic solvent being 50-800% by weight based on the total weight of the monomer contained in the monomer solution, and the product yield of the polymer being 50% by weight or more based on the total weight of the monomer.

    摘要翻译: 公开了一种制备含有极性官能团的环烯烃聚合物的方法,包括:制备催化剂混合物,其包括i)含有具有与金属键合的含氧离子的配体的第10族过渡金属的预催化剂; ii)第一助催化剂,其是含有第15族元素的有机化合物; 和iii)能够提供阴离子并与预催化剂的金属弱配位的第二助催化剂; 将含有极性官能团的降冰片烯系化合物的单体溶液在有机溶剂和催化剂混合物的存在下,在80〜200℃的温度下进行加成聚合反应, 溶剂为50-800重量%,基于单体溶液中所含单体的总重量,聚合物的产物收率基于单体的总重量为50重量%以上。