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公开(公告)号：US20150148560A1
公开(公告)日：2015-05-28
申请号：US14404384
申请日：2013-05-31
Applicant: MICROMIDAS, INC.
Inventor： Ryan L. Smith , John Bissell , Makoto N. Masuno , Douglas Cannon , Alex B. Wood , Marc Foster
CPC classification number: C07C67/31 , C07C1/24 , C07C29/095 , C07C29/149 , C07C51/16 , C07C67/03 , C07C67/30 , C07C2527/167 , C07C69/675 , C07C69/533 , C07C11/167 , C07C57/15 , C07C69/56 , C07C31/207
Abstract: Provided herein are methods that utilize polyhydroxyalkanoates (PHAs) as a substrate for further conversion to C4 and C5 compounds. Polyhydroxyalkanoates can undergo esterification to yield alkyl hydroxyalkanoates and alkyl alkenoates, which may serve as useful precursors in the production of alkadienes and alkenedioic acids, including for example butadiene and butenedioic acid.
Abstract translation: 本文提供了利用聚羟基链烷酸酯（PHA）作为底物进一步转化成C4和C5化合物的方法。 聚羟基链烷酸酯可以进行酯化以得到烷基羟基链烷酸酯和烷基链烯酸酯，其可用作生产烷二烯和烯二酸的有用前体，包括例如丁二烯和丁烯二酸。
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公开(公告)号：US09688603B2
公开(公告)日：2017-06-27
申请号：US15154804
申请日：2016-05-13
Applicant: MICROMIDAS, INC.
Inventor： Ryan L. Smith , John Bissell , Makoto N. Masuno , Douglas Cannon , Alex B. Wood
CPC classification number: C07C67/31 , C07C1/24 , C07C29/095 , C07C29/149 , C07C51/16 , C07C67/03 , C07C67/30 , C07C2527/167 , C07C69/675 , C07C69/533 , C07C11/167 , C07C57/15 , C07C69/56 , C07C31/207
Abstract: Provided herein are methods that utilize polyhydroxyalkanoates (PHAs) as a substrate for further conversion to C4 and C5 compounds. Polyhydroxyalkanoates can undergo esterification to yield alkyl hydroxyalkanoates and alkyl alkenoates, which may serve as useful precursors in the production of alkadienes and alkenedioic acids, including for example butadiene and butenedioic acid.
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公开(公告)号：US09359283B2
公开(公告)日：2016-06-07
申请号：US14404384
申请日：2013-05-31
Applicant: MICROMIDAS, INC.
Inventor： Ryan L. Smith , John Bissell , Makoto N. Masuno , Douglas Cannon , Alex B. Wood
CPC classification number: C07C67/31 , C07C1/24 , C07C29/095 , C07C29/149 , C07C51/16 , C07C67/03 , C07C67/30 , C07C2527/167 , C07C69/675 , C07C69/533 , C07C11/167 , C07C57/15 , C07C69/56 , C07C31/207
Abstract: Provided herein are methods that utilize polyhydroxyalkanoates (PHAs) as a substrate for further conversion to C4 and C5 compounds. Polyhydroxyalkanoates can undergo esterification to yield alkyl hydroxyalkanoates and alkyl alkenoates, which may serve as useful precursors in the production of alkadienes and alkenedioic acids, including for example butadiene and butenedioic acid.
Abstract translation: 本文提供了利用聚羟基链烷酸酯（PHA）作为底物进一步转化成C4和C5化合物的方法。 聚羟基链烷酸酯可以进行酯化以得到烷基羟基链烷酸酯和烷基链烯酸酯，其可用作生产烷二烯和烯二酸的有用前体，包括例如丁二烯和丁烯二酸。
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公开(公告)号：US09890101B2
公开(公告)日：2018-02-13
申请号：US14993833
申请日：2016-01-12
Applicant: MICROMIDAS, INC.
Inventor： Makoto N. Masuno , Douglas Cannon , John Bissell, II , Ryan L. Smith , Alex B. Wood , Patrick B. Smith , Dennis A. Hucul , Katherine Brune
CPC classification number: C07C51/16 , C07C2/52 , C07C2/862 , C07C2/865 , C07C15/08 , C07C2521/18 , C07C2527/02 , C07C2527/053 , C07C2527/08 , C07C2527/10 , C07C2527/122 , C07C2527/126 , C07C2527/128 , C07C2527/132 , C07C2527/133 , C07C2527/135 , C07C2527/138 , C07C2527/14 , C07C2527/16 , C07C2529/08 , C07C2529/14 , C07C2529/24 , C07C2531/02 , C07C2531/04 , C07C2531/12 , C07C15/06
Abstract: The present disclosure provides methods to produce para-xylene, toluene, and other compounds from renewable sources (e.g., cellulose, hemicellulose) and ethylene in the presence of an acid, such as a Lewis acid. For example, cellulose and/or hemicellulose may be converted into 2,5-dimethylfuran (DMF) and 2-methylfuran, which may be converted into para-xylene and toluene, respectively. In particular, para-xylene can then be oxidized to form terephthalic acid.
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